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An electrolytic detector, or liquid barretter, is a type of detector (
demodulator Demodulation is the process of extracting the original information-bearing signal from a carrier wave. A demodulator is an electronic circuit (or computer program in a software-defined radio) that is used to recover the information content from ...
) used in early
radio receiver In radio communications, a radio receiver, also known as a receiver, a wireless, or simply a radio, is an electronic device that receives radio waves and converts the information carried by them to a usable form. It is used with an antenna. ...
s. It was first used by Canadian radio researcher
Reginald Fessenden Reginald Aubrey Fessenden (October 6, 1866 – July 22, 1932) was a Canadian-American electrical engineer and inventor who received hundreds of List of Reginald Fessenden patents, patents in fields related to radio and sonar between 1891 and 1936 ...
in 1903, and used until about 1913, after which it was superseded by
crystal detector A crystal detector is an obsolete electronic component used in some early 20th century radio receivers. It consists of a piece of crystalline mineral that rectifies an alternating current radio signal. It was employed as a detector ( demod ...
s and vacuum tube detectors such as the
Fleming valve The Fleming valve, also called the Fleming oscillation valve, was a thermionic valve or vacuum tube invented in 1904 by English physicist John Ambrose Fleming as a detector for early radio receivers used in electromagnetic wireless telegrap ...
and
Audion The Audion was an electronic detecting or amplifying vacuum tube invented by American electrical engineer Lee de Forest as a diode in 1906.De Forest patented a number of variations of his detector tubes starting in 1906. The patent that most cle ...
(
triode A triode is an electronic amplifier, amplifying vacuum tube (or ''thermionic valve'' in British English) consisting of three electrodes inside an evacuated glass envelope: a heated Electrical filament, filament or cathode, a control grid, grid ...
). It was considered very sensitive and reliable compared to other detectors available at the time such as the
magnetic detector The magnetic detector or Marconi magnetic detector, sometimes called the "Maggie", was an early radio wave detector used in some of the first radio receivers to receive Morse code messages during the wireless telegraphy era around the turn of th ...
and the
coherer The coherer was a primitive form of radio signal detector used in the first radio receivers during the wireless telegraphy era at the beginning of the 20th century. Its use in radio was based on the 1890 findings of French physicist Édouard Bra ...
. It was one of the first rectifying detectors, able to receive AM (sound) transmissions. On December 24, 1906, US Naval ships with radio receivers equipped with Fessenden's electrolytic detectors received the first AM radio broadcast from Fessenden's Brant Rock, Massachusetts transmitter, consisting of a program of Christmas music.


History

Fessenden, more than any other person, is responsible for developing
amplitude modulation Amplitude modulation (AM) is a signal modulation technique used in electronic communication, most commonly for transmitting messages with a radio wave. In amplitude modulation, the instantaneous amplitude of the wave is varied in proportion t ...
(AM) radio transmission around 1900. While working to develop AM transmitters, he realized that the radio wave detectors used in existing radio receivers were not suitable to receive AM signals. The radio transmitters of the time transmitted information by
radiotelegraphy Wireless telegraphy or radiotelegraphy is the transmission of text messages by radio waves, analogous to electrical telegraphy using cables. Before about 1910, the term ''wireless telegraphy'' was also used for other experimental technologies f ...
; the transmitter was turned on and off by the operator using a switch called a
telegraph key A telegraph key, clacker, tapper or morse key is a specialized electrical switch used by a trained operator to transmit text messages in Morse code in a telegraphy system. Keys are used in all forms of electrical telegraph systems, includ ...
producing pulses of radio waves, to transmit text data using
Morse code Morse code is a telecommunications method which Character encoding, encodes Written language, text characters as standardized sequences of two different signal durations, called ''dots'' and ''dashes'', or ''dits'' and ''dahs''. Morse code i ...
. Thus, receivers didn't have to extract an audio signal from the radio signal, but only detected the presence or absence of the radio frequency to produce "clicks" in the earphone representing the pulses of Morse code. The device that did this was called a "detector". The detector used in receivers of that day, called a
coherer The coherer was a primitive form of radio signal detector used in the first radio receivers during the wireless telegraphy era at the beginning of the 20th century. Its use in radio was based on the 1890 findings of French physicist Édouard Bra ...
, simply acted as a switch, that conducted current in the presence of radio waves, and thus did not have the capability to
demodulate Demodulation is the process of extracting the original information-bearing signal from a carrier wave. A demodulator is an electronic circuit (or computer program in a software-defined radio) that is used to recover the information content from ...
, or extract the audio signal from, an amplitude-modulated radio wave. The simplest way to extract the sound waveform from an AM signal is to rectify it; remove the oscillations on one side of the wave, converting it from an
alternating current Alternating current (AC) is an electric current that periodically reverses direction and changes its magnitude continuously with time, in contrast to direct current (DC), which flows only in one direction. Alternating current is the form in w ...
to a varying
direct current Direct current (DC) is one-directional electric current, flow of electric charge. An electrochemical cell is a prime example of DC power. Direct current may flow through a conductor (material), conductor such as a wire, but can also flow throug ...
. The variations in the amplitude of the radio wave that represent the sound waveform will cause variations in the current, and thus can be converted to sound by an earphone. To do this a
rectifier A rectifier is an electrical device that converts alternating current (AC), which periodically reverses direction, to direct current (DC), which flows in only one direction. The process is known as ''rectification'', since it "straightens" t ...
is required, an electrical component that conducts electric current in only one direction and blocks current in the opposite direction. It was known at the time that passing current through solutions of
electrolyte An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble Salt (chemistry), salts, acids, and Base (chemistry), bases, dissolved in a polar solven ...
s such as acids could have this unilateral conduction property. In 1902 Fessenden developed what he called a " barretter" detector that would rectify an AM signal, but it was not very sensitive. The barretter used a fine platinum wire, called Wollaston wire, manufactured as a platinum core in a silver sheath that had to be stripped off with acid. In the process of stripping some Wollaston wire, Fessenden left it immersed in acid too long, eating away most of the wire until only a tip remained in contact with the solution; he noted that it responded well to radio signals being generated nearby, and could be used as new type of detector. This story was disputed at the time, with credit for the discovery also given to Michael I. Pupin, W. Schloemilch,
Hugo Gernsback Hugo Gernsback (; born Hugo Gernsbacher, August 16, 1884 – August 19, 1967) was a Luxembourgish American editor and magazine publisher whose publications included the first science fiction magazine, ''Amazing Stories''. His contributions to ...
and others. However, it is apparent that Fessenden was the first to put the device to practical use.


Description

The action of this detector is based upon the fact that only the tip of a
platinum Platinum is a chemical element; it has Symbol (chemistry), symbol Pt and atomic number 78. It is a density, dense, malleable, ductility, ductile, highly unreactive, precious metal, precious, silverish-white transition metal. Its name origina ...
wire a few hundred-thousandths of an inch in diameter is immersed in an
electrolyte An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble Salt (chemistry), salts, acids, and Base (chemistry), bases, dissolved in a polar solven ...
solution, and a small D.C.
voltage Voltage, also known as (electrical) potential difference, electric pressure, or electric tension, is the difference in electric potential between two points. In a Electrostatics, static electric field, it corresponds to the Work (electrical), ...
bias is applied to the cell thus formed. Platinum is used because other metals are too quickly dissolved in the acid. The applied bias current decomposes the solution by
electrolysis In chemistry and manufacturing, electrolysis is a technique that uses Direct current, direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of c ...
into tiny gas bubbles that cling to the metal point insulating the metal tip from the solution thus reducing the bias current. An incoming R.F. current can flow better in the direction across the point that makes the point more negative. That recombines the gases and increases point exposure to the liquid. RF current flow in the direction that makes the point more positive only reinforces the resistance from the gaseous blocking of the point. Detection results from this asymmetrical flow. In practical use, a
series circuit Terminal (electronics), Two-terminal components and electrical networks can be connected in series or parallel. The resulting electrical network will have two terminals, and itself can participate in a series or parallel Topology (electrical ci ...
is made of the detector,
headphone Headphones are a pair of small loudspeaker drivers worn on or around the head over a user's ears. They are electroacoustic transducers, which convert an electrical signal to a corresponding sound. Headphones let a single user listen to an ...
s, and a battery with a
potentiometer A potentiometer is a three- terminal resistor with a sliding or rotating contact that forms an adjustable voltage divider. If only two terminals are used, one end and the wiper, it acts as a variable resistor or rheostat. The measuring instrum ...
. The wire is made positive, and the signal to be demodulated is applied directly to it; a small (about 5 ml) platinum cup filled with either sulfuric or
nitric acid Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most com ...
completes the headphone circuit, and is also connected to ground to complete the signal circuit. To adjust the cell, the point of the wire electrode is dipped into the electrolyte and the potentiometer adjusted until a hissing noise is heard in the headphones. The potentiometer setting is then moved to reduce the current until the noise just ceases, at which point the detector is in its most sensitive state. It was found that strong
atmospheric noise Atmospheric noise is radio noise, or "static", caused by natural atmospheric processes, primarily lightning discharges in thunderstorms. On a worldwide scale, there are about 40 lightning flashes per second, or lightning discharges per day ...
would render it insensitive, requiring that the device be rebiased after each strong burst of static interference.


Sealed-point detector

Another form of electrolytic detector, the sealed-point electrolytic detector, which could stand considerable rough usage, was commercially known as the Radioson Detector; it had the cell sealed in a glass envelope. The operation was the same as in the bare-point electrolytic detector, the advantage being that the acid was sealed in, and consequently could not spill or evaporate.


See also

* Hot-wire barretter *
Coherer The coherer was a primitive form of radio signal detector used in the first radio receivers during the wireless telegraphy era at the beginning of the 20th century. Its use in radio was based on the 1890 findings of French physicist Édouard Bra ...
* Crystal Radio *
Spark-gap transmitter A spark-gap transmitter is an obsolete type of transmitter, radio transmitter which generates radio waves by means of an electric spark."Radio Transmitters, Early" in Spark-gap transmitters were the first type of radio transmitter, and were the m ...
*
Radio receiver In radio communications, a radio receiver, also known as a receiver, a wireless, or simply a radio, is an electronic device that receives radio waves and converts the information carried by them to a usable form. It is used with an antenna. ...
*
Antique radio An antique radio is a radio receiving set that is collectible because of its age and rarity. Types of antique radio Morse receivers The first radio receivers used a coherer and sounding board, and were only able to receive continuous wave (CW) ...
* Camille Papin Tissot


Notes


External links


United States Early Radio History
{{Telecommunications History of radio Radio electronics Detectors