Electrohydrodynamics (EHD), also known as electro-fluid-dynamics (EFD) or electrokinetics, is the study of the
dynamics of
electrically charged fluids.
Electrohydrodynamics (EHD) is a joint domain of electrodynamics and fluid dynamics mainly focused on the fluid motion induced by electric fields. EHD, in its simplest form, involves the application of an electric field to a fluid medium, resulting in fluid flow, form, or properties manipulation. These mechanisms arise from the interaction between the electric fields and charged particles or polarization effects within the fluid.
The generation and movement of charge carriers (ions) in a fluid subjected to an electric field are the underlying physics of all EHD-based technologies.
The electric forces acting on particles consist of electrostatic (Coulomb) and electrophoresis force (first term in the following equation)., dielectrophoretic force (second term in the following equation), and electrostrictive force (third term in the following equation):
This electrical force is then inserted in
Navier-Stokes equation, as a body (volumetric) force.EHD covers the following types of particle and fluid transport mechanisms:
electrophoresis
Electrophoresis is the motion of charged dispersed particles or dissolved charged molecules relative to a fluid under the influence of a spatially uniform electric field. As a rule, these are zwitterions with a positive or negative net ch ...
,
electrokinesis,
dielectrophoresis
Dielectrophoresis (DEP) is a phenomenon in which a force is exerted on a dielectric particle when it is subjected to a non-uniform electric field.
This force does not require the particle to be charged. All particles exhibit dielectrophoretic a ...
,
electro-osmosis, and
electrorotation. In general, the phenomena relate to the direct conversion of
electrical energy
Electrical energy is the energy transferred as electric charges move between points with different electric potential, that is, as they move across a voltage, potential difference. As electric potential is lost or gained, work is done changing the ...
into
kinetic energy
In physics, the kinetic energy of an object is the form of energy that it possesses due to its motion.
In classical mechanics, the kinetic energy of a non-rotating object of mass ''m'' traveling at a speed ''v'' is \fracmv^2.Resnick, Rober ...
, and ''vice versa''.
In the first instance, shaped
electrostatic field
An electric field (sometimes called E-field) is a physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) describes their capac ...
s (ESF's) create
hydrostatic pressure
Hydrostatics is the branch of fluid mechanics that studies fluids at hydrostatic equilibrium and "the pressure in a fluid or exerted by a fluid on an immersed body". The word "hydrostatics" is sometimes used to refer specifically to water and o ...
(HSP, or motion) in
dielectric media. When such media are
fluid
In physics, a fluid is a liquid, gas, or other material that may continuously motion, move and Deformation (physics), deform (''flow'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are M ...
s, a
flow is produced. If the dielectric is a
vacuum
A vacuum (: vacuums or vacua) is space devoid of matter. The word is derived from the Latin adjective (neuter ) meaning "vacant" or "void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressur ...
or a
solid
Solid is a state of matter where molecules are closely packed and can not slide past each other. Solids resist compression, expansion, or external forces that would alter its shape, with the degree to which they are resisted dependent upon the ...
, no flow is produced. Such flow can be directed against the
electrode
An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or a gas). In electrochemical cells, electrodes are essential parts that can consist of a varie ...
s, generally to move the electrodes. In such case, the moving structure acts as an
electric motor
An electric motor is a machine that converts electrical energy into mechanical energy. Most electric motors operate through the interaction between the motor's magnetic field and electric current in a electromagnetic coil, wire winding to gene ...
. Practical fields of interest of EHD are the common
air ioniser
An air ioniser (or negative ion generator or Chizhevsky's chandelier) is a device that uses high voltage to ionization, ionise (electrically charge) Atmosphere of Earth, air molecules. Negative ions, or anions, are particles with one or more e ...
,
electrohydrodynamic thruster
An ion-propelled aircraft or ionocraft is an aircraft that uses electrohydrodynamics (EHD) to provide lift (force), lift or thrust in the air without requiring combustion or moving parts. Current designs do not produce sufficient thrust for crew ...
s and EHD cooling systems.
In the second instance, the converse takes place. A powered flow of medium within a shaped electrostatic field adds energy to the system which is picked up as a
potential difference
Voltage, also known as (electrical) potential difference, electric pressure, or electric tension, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge ...
by electrodes. In such case, the structure acts as an
electrical generator
In electricity generation, a generator, also called an ''electric generator'', ''electrical generator'', and ''electromagnetic generator'' is an electromechanical device that converts mechanical energy to electrical energy for use in an extern ...
.
Electrokinesis
Electrokinesis is the particle or
fluid
In physics, a fluid is a liquid, gas, or other material that may continuously motion, move and Deformation (physics), deform (''flow'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are M ...
transport produced by an electric field acting on a fluid having a net mobile charge. (See -kinesis for explanation and further uses of the -kinesis suffix.) ''Electrokinesis'' was first observed by Ferdinand Frederic Reuss during 1808, in the
electrophoresis
Electrophoresis is the motion of charged dispersed particles or dissolved charged molecules relative to a fluid under the influence of a spatially uniform electric field. As a rule, these are zwitterions with a positive or negative net ch ...
of clay particles The effect was also noticed and publicized in the 1920s by
Thomas Townsend Brown
Thomas Townsend Brown (March 18, 1905 – October 27, 1985) was an American inventor whose research into odd electrical effects led him to believe he had discovered a type of anti-gravity caused by strong electric fields. Instead of being an anti- ...
which he called the
Biefeld–Brown effect
The Biefeld–Brown effect is an electrical phenomenon, first noticed by inventor Thomas Townsend Brown in the 1920s, where high voltage applied to the electrodes of an asymmetric capacitor causes a net propulsive force toward the smaller electr ...
, although he seems to have misidentified it as an electric field acting on gravity.
The flow rate in such a mechanism is linear in the
electric field
An electric field (sometimes called E-field) is a field (physics), physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) descri ...
. Electrokinesis is of considerable practical importance in
microfluidics
Microfluidics refers to a system that manipulates a small amount of fluids (10−9 to 10−18 liters) using small channels with sizes of ten to hundreds of micrometres. It is a multidisciplinary field that involves molecular analysis, molecular bi ...
,
because it offers a way to manipulate and convey fluids in microsystems using only electric fields, with no moving parts.
The force acting on the fluid, is given by the equation
where,
is the resulting force, measured in
newtons
The newton (symbol: N) is the unit of force in the International System of Units (SI). Expressed in terms of SI base units, it is 1 kg⋅m/s2, the force that accelerates a mass of one kilogram at one metre per second squared.
The unit i ...
,
is the current, measured in
ampere
The ampere ( , ; symbol: A), often shortened to amp,SI supports only the use of symbols and deprecates the use of abbreviations for units. is the unit of electric current in the International System of Units (SI). One ampere is equal to 1 c ...
s,
is the distance between electrodes, measured in metres, and
is the ion mobility coefficient of the dielectric fluid, measured in m
2/(V·s).
If the electrodes are free to move within the fluid, while keeping their distance fixed from each other, then such a force will actually propel the electrodes with respect to the fluid.
''Electrokinesis'' has also been observed in biology, where it was found to cause physical damage to neurons by inciting movement in their membranes.
It is discussed in R. J. Elul's "Fixed charge in the cell membrane" (1967).
Water electrokinetics
In October 2003, Dr. Daniel Kwok, Dr. Larry Kostiuk and two graduate students from the
University of Alberta
The University of Alberta (also known as U of A or UAlberta, ) is a public research university located in Edmonton, Alberta, Canada. It was founded in 1908 by Alexander Cameron Rutherford, the first premier of Alberta, and Henry Marshall Tory, t ...
discussed a method to convert hydrodynamic to
electrical energy
Electrical energy is the energy transferred as electric charges move between points with different electric potential, that is, as they move across a voltage, potential difference. As electric potential is lost or gained, work is done changing the ...
by exploiting the natural electrokinetic properties of a liquid such as ordinary
tap water
Tap water (also known as running water, piped water or municipal water) is water supplied through a Tap (valve), tap, a water dispenser valve. In many countries, tap water usually has the quality of drinking water. Tap water is commonly used f ...
, by pumping fluid through tiny micro-channels with a pressure difference. This technology could lead to a practical and clean energy storage device, replacing batteries for devices such as mobile phones or calculators which would be charged up by simply compressing water to high
pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
. Pressure would then be released on demand, for the fluid to flow through micro-channels. When water travels, or streams over a surface, the ions in the water "rub" against the solid, leaving the surface slightly charged. Kinetic energy from the moving ions would thus be converted to electrical energy. Although the power generated from a single channel is extremely small, millions of parallel micro-channels can be used to increase the power output.
This
streaming potential
Streaming media refers to multimedia delivered through a network for playback using a media player. Media is transferred in a ''stream'' of packets from a server to a client and is rendered in real-time; this contrasts with file downl ...
, water-flow phenomenon was discovered in 1859 by German physicist
Georg Hermann Quincke.
Electrokinetic instabilities
The fluid flows in microfluidic
Microfluidics refers to a system that manipulates a small amount of fluids (10−9 to 10−18 liters) using small channels with sizes of ten to hundreds of micrometres. It is a multidisciplinary field that involves molecular analysis, molecular bi ...
and nanofluidic devices are often stable and strongly damped by viscous forces (with Reynolds number
In fluid dynamics, the Reynolds number () is a dimensionless quantity that helps predict fluid flow patterns in different situations by measuring the ratio between Inertia, inertial and viscous forces. At low Reynolds numbers, flows tend to ...
s of order unity or smaller). However, heterogeneous ionic conductivity fields in the presence of applied electric field
An electric field (sometimes called E-field) is a field (physics), physical field that surrounds electrically charged particles such as electrons. In classical electromagnetism, the electric field of a single charge (or group of charges) descri ...
s can, under certain conditions, generate an unstable flow field owing to electrokinetic instabilities (EKI). Conductivity gradients are prevalent in on-chip electrokinetic processes such as preconcentration methods (e.g. field amplified sample stacking and isoelectric focusing), multidimensional assays, and systems with poorly specified sample chemistry. The dynamics and periodic morphology of ''electrokinetic instabilities'' are similar to other systems with Rayleigh–Taylor instabilities. The particular case of a flat plane geometry with homogeneous ions injection in the bottom side leads to a mathematical frame identical to the Rayleigh–Bénard convection.
EKI's can be leveraged for rapid mixing or can cause undesirable dispersion in sample injection, separation and stacking. These instabilities are caused by a coupling of electric fields and ionic conductivity gradients that results in an electric body force. This coupling results in an electric body force in the bulk liquid, outside the electric double layer, that can generate temporal, convective, and absolute flow instabilities. Electrokinetic flows with conductivity gradients become unstable when the electroviscous stretching and folding of conductivity interfaces grows faster than the dissipative effect of molecular diffusion.
Since these flows are characterized by low velocities and small length scales, the Reynolds number is below 0.01 and the flow is ''laminar''. The onset of instability in these flows is best described as an electric "Rayleigh number".
Misc
Liquids can be printed at nanoscale by pyro-EHD.
See also
* Magnetohydrodynamic drive
* Magnetohydrodynamics
In physics and engineering, magnetohydrodynamics (MHD; also called magneto-fluid dynamics or hydromagnetics) is a model of electrically conducting fluids that treats all interpenetrating particle species together as a single Continuum ...
* Electrodynamic droplet deformation
* Electrospray
* Electrokinetic phenomena Electrokinetic phenomena are a family of several different effects that occur in heterogeneous fluids, or in porous bodies filled with fluid, or in a fast flow over a flat surface. The term heterogeneous here means a fluid containing particles. Part ...
* Optoelectrofluidics
* Electrostatic precipitator
An electrostatic precipitator (ESP) is a filterless device that removes fine particles, such as dust and smoke, from a flowing gas using the force of an induced electrostatic charge minimally impeding the flow of gases through the unit.
In c ...
* List of textbooks in electromagnetism
References
External links
Dr. Larry Kostiuk's website
BBC article with graphics
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Electrodynamics
Energy conversion
Fluid dynamics