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The Efimov effect is an effect in the
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
of few-body systems predicted by the Russian
theoretical physicist Theoretical physics is a branch of physics that employs mathematical models and abstractions of physical objects and systems to rationalize, explain, and predict natural phenomena. This is in contrast to experimental physics, which uses experi ...
V. N. Efimov in 1970. Efimov's effect is where three identical
boson In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0, 1, 2, ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have half odd-intege ...
s interact, with the prediction of an infinite series of excited three-body energy levels when a two-body state is exactly at the dissociation threshold. One corollary is that there exist bound states (called Efimov states) of three bosons even if the two-particle attraction is too weak to allow two bosons to form a pair. A (three-particle) Efimov state, where the (two-body) sub-systems are unbound, is often depicted symbolically by the
Borromean rings In mathematics, the Borromean rings are three simple closed curves in three-dimensional space that are link (knot theory), topologically linked and cannot be separated from each other, but that break apart into two unknotted and unlinked loops wh ...
. This means that if one of the particles is removed, the remaining two fall apart. In this case, the Efimov state is also called a Borromean state.


Theory

Pair interactions among three identical bosons will approach "Resonance (particle physics)" as the
binding energy In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a system of particles into individual parts. In the former meaning the term is predominantly use ...
of some two-body bound state approaches zero, or equivalently, the s-wave
scattering length The scattering length in quantum mechanics describes low-energy scattering. For potentials that decay faster than 1/r^3 as r\to \infty, it is defined as the following low-energy limit: : \lim_ k\cot\delta(k) =- \frac\;, where a is the scatterin ...
of the state becomes infinite. In this limit, Efimov predicted that the three-body
spectrum A spectrum (: spectra or spectrums) is a set of related ideas, objects, or properties whose features overlap such that they blend to form a continuum. The word ''spectrum'' was first used scientifically in optics to describe the rainbow of co ...
exhibits an infinite sequence of bound states N=0,1,2,\ldots whose scattering lengths a_ and binding energies E_N each form a
geometric progression A geometric progression, also known as a geometric sequence, is a mathematical sequence of non-zero numbers where each term after the first is found by multiplying the previous one by a fixed number called the ''common ratio''. For example, the s ...
\begin a_&=a_0\lambda^N\\ E_&=E_0\lambda^ \end where the common ratio \lambda=\mathrm^=22.69438\ldots is a universal constant (). Here s_0=1.0062378\ldots is the order of the imaginary-order modified Bessel function of the second kind \tilde_(r/a) that describes the radial dependence of the wavefunction. By virtue of the resonance-determined boundary conditions, this is the unique positive value of s satisfying the transcendental equation -s\cosh\left.\tfrac\right.+\tfrac\sinh\left.\tfrac\right.=0. The geometric progression of the energy levels of Efimov states is an example of a emergent discrete scaling symmetry. This phenomenon, exhibiting a
renormalization group In theoretical physics, the renormalization group (RG) is a formal apparatus that allows systematic investigation of the changes of a physical system as viewed at different scales. In particle physics, it reflects the changes in the underlying p ...
limit cycle, is closely related to the scale invariance of the 1/r^2 form of the quantum mechanical potential of the system.


Experimental results

In 2005, the research group of Rudolf Grimm and Hanns-Christoph Nägerl at the Institute for Experimental Physics at the
University of Innsbruck The University of Innsbruck (; ) is a public research university in Innsbruck, the capital of the Austrian federal state of Tyrol (state), Tyrol, founded on October 15, 1669. It is the largest education facility in the Austrian States of Austria, ...
experimentally confirmed the existence of such a state for the first time in an ultracold gas of
caesium Caesium (IUPAC spelling; also spelled cesium in American English) is a chemical element; it has Symbol (chemistry), symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only f ...
atoms. In 2006, they published their findings in the scientific journal Nature. Further experimental support for the existence of the Efimov state has been given recently by independent groups. Almost 40 years after Efimov's purely theoretical prediction, the characteristic periodic behavior of the states has been confirmed. The most accurate experimental value of the scaling factor of the states has been determined by the experimental group of Rudolf Grimm at Innsbruck University as \lambda=21.0\pm1.3 Interest in the "universal phenomena" of cold atomic gases is still growing. The discipline of universality in cold atomic gases near the Efimov states is sometimes referred to as "Efimov physics". The experimental groups of Cheng Chin of the
University of Chicago The University of Chicago (UChicago, Chicago, or UChi) is a Private university, private research university in Chicago, Illinois, United States. Its main campus is in the Hyde Park, Chicago, Hyde Park neighborhood on Chicago's South Side, Chic ...
and Matthias Weidemüller of the
University of Heidelberg Heidelberg University, officially the Ruprecht Karl University of Heidelberg (; ), is a public university, public research university in Heidelberg, Baden-Württemberg, Germany. Founded in 1386 on instruction of Pope Urban VI, Heidelberg is List ...
have observed Efimov states in an ultracold mixture of
lithium Lithium (from , , ) is a chemical element; it has chemical symbol, symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard temperature and pressure, standard conditions, it is the least dense metal and the ...
and
caesium Caesium (IUPAC spelling; also spelled cesium in American English) is a chemical element; it has Symbol (chemistry), symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only f ...
atoms, extending Efimov's original picture of three identical bosons. An Efimov state existing as an excited state of a helium trimer was observed in an experiment in 2015.{{cite journal, last1=Kunitski, first1=Maksim, last2=Zeller, first2=Stefan, last3=Voigtsberger, first3=Jörg, last4=Kalinin, first4=Anton, last5= Schmidt, first5=Lothar Ph. H., last6=Schöffler, first6=Markus, last7=Czasch, first7=Achim, last8=Schöllkopf, first8=Wieland, last9=Grisenti, first9=Robert E., last10=Jahnke, first10=Till, last11=Blume, first11=Dörte, last12=Dörner, first12=Reinhard, title=Observation of the Efimov state of the helium trimer , journal=Science, date=May 2015, volume=348, issue=6234, pages=551–555, doi=10.1126/science.aaa5601, pmid=25931554, arxiv=1512.02036, bibcode=2015Sci...348..551K, s2cid=206635093


Usage

The Efimov states are independent of the underlying physical interaction and can in principle be observed in all quantum mechanical systems (i.e. molecular, atomic, and nuclear). The states are very special because of their "non-classical" nature: The size of each three-particle Efimov state is much larger than the force-range between the individual particle pairs. This means that the state is purely quantum mechanical. Similar phenomena are observed in two-neutron halo-nuclei, such as lithium-11; these are called Borromean nuclei. (Halo nuclei could be seen as special Efimov states, depending on the subtle definitions.)


See also

* Three-body force


References


External links


Press release about the experimental confirmation (2006.03.16)


* ttp://journals.aps.org/prl/abstract/10.1103/PhysRevLett.112.190401 Observation of the Second Triatomic Resonance in Efimov’s Scenario (2014.05.15) Quantum mechanics