Edmond Frémy
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Edmond Frémy (; 28 February 1814 – 3 February 1894) was a French
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a graduated scientist trained in the study of chemistry, or an officially enrolled student in the field. Chemists study the composition of ...
. He is perhaps best known today for Frémy's salt, a strong oxidizing agent which he discovered in 1845. Fremy's salt is a long-lived
free radical A daughter category of ''Ageing'', this category deals only with the biological aspects of ageing. Ageing Biogerontology Biological processes Causes of death Cellular processes Gerontology Life extension Metabolic disorders Metabolism ...
that finds use as a standard in
electron paramagnetic resonance Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spin ...
spectroscopy.


Life

Frémy was born at
Versailles The Palace of Versailles ( ; ) is a former royal residence commissioned by King Louis XIV located in Versailles, Yvelines, Versailles, about west of Paris, in the Yvelines, Yvelines Department of ÃŽle-de-France, ÃŽle-de-France region in Franc ...
, entered
Joseph Louis Gay-Lussac Joseph Louis Gay-Lussac ( , ; ; 6 December 1778 â€“ 9 May 1850) was a French chemist and physicist. He is known mostly for his discovery that water is made of two parts hydrogen and one part oxygen by volume (with Alexander von Humboldt), f ...
's laboratory in 1831, and was employed at the
École Polytechnique (, ; also known as Polytechnique or l'X ) is a ''grande école'' located in Palaiseau, France. It specializes in science and engineering and is a founding member of the Polytechnic Institute of Paris. The school was founded in 1794 by mat ...
in 1834 and at the
Collège de France The (), formerly known as the or as the ''Collège impérial'' founded in 1530 by François I, is a higher education and research establishment () in France. It is located in Paris near La Sorbonne. The has been considered to be France's most ...
in 1837. His next post was that of repetiteur at the École Polytechnique, where in 1846 he was appointed professor, and in 1850 he succeeded
Gay-Lussac Joseph Louis Gay-Lussac ( , ; ; 6 December 1778 â€“ 9 May 1850) was a French chemist and physicist. He is known mostly for his discovery that water is made of two parts hydrogen and one part oxygen by volume (with Alexander von Humboldt), f ...
in the chair of chemistry at the
Muséum national d'histoire naturelle The French National Museum of Natural History ( ; abbr. MNHN) is the national natural history museum of France and a of higher education part of Sorbonne University. The main museum, with four galleries, is located in Paris, France, within the Ja ...
, of which he later became director (1879–1891) after
Michel Eugène Chevreul Michel Eugène Chevreul (; 31 August 1786 – 9 April 1889) was a French chemist whose work contributed to significant developments in science, medicine, and art. Chevreul's early work with animal fats revolutionized soap and candle manufacturing ...
. He died in Paris.


Work

Frémy's work included investigations of osmic acid, the ferrates,
stannate In chemistry, the term stannate or tinnate refers to compounds of tin (Sn). Stannic acid (Sn(OH)4), the formal precursor to stannates, does not exist and is actually a hydrate of SnO2. The term is also used in naming conventions as a suffix; for ...
s,
plumbate In chemistry, a plumbate often refers to compounds that can be viewed as derivatives of the hypothetical anion. Examples Halides Salts of , , , etc. are labeled as iodoplumbates. Lead perovskite semiconductors are often described as plumbates. ...
s, and other oxometallates, as well as
ozone Ozone () (or trioxygen) is an Inorganic compound, inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , break ...
; attempts to obtain free
fluorine Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
by the electrolysis of fused fluorides; and the discovery of anhydrous
hydrofluoric acid Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48–52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling p ...
and a series of ''acides sulphazotés'', the precise nature of which long remained a matter of discussion. He also studied the coloring of leaves and flowers, the composition of
bone A bone is a rigid organ that constitutes part of the skeleton in most vertebrate animals. Bones protect the various other organs of the body, produce red and white blood cells, store minerals, provide structure and support for the body, ...
, cerebral matter, and other animal substances, and the processes of
fermentation Fermentation is a type of anaerobic metabolism which harnesses the redox potential of the reactants to make adenosine triphosphate (ATP) and organic end products. Organic molecules, such as glucose or other sugars, are catabolized and reduce ...
, in which he was an opponent of
Pasteur Louis Pasteur (, ; 27 December 1822 – 28 September 1895) was a French chemist, pharmacist, and microbiologist renowned for his discoveries of the principles of vaccination, microbial fermentation, and pasteurization, the last of which wa ...
's views. Keenly alive to the importance of the technical applications of chemistry, Frémy devoted special attention as a teacher to the training of industrial chemists. In this field he contributed to our knowledge of the manufacture of iron and steel,
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
, glass, and paper, and in particular worked at the saponification of fats with sulfuric acid and the utilization of
palmitic acid Palmitic acid (hexadecanoic acid in IUPAC nomenclature) is a fatty acid with a 16-carbon chain. It is the most common saturated fatty acid found in animals, plants and microorganisms.Gunstone, F. D., John L. Harwood, and Albert J. Dijkstra. The ...
for
candle A candle is an ignitable candle wick, wick embedded in wax, or another flammable solid substance such as tallow, that provides light, and in some cases, a Aroma compound, fragrance. A candle can also provide heat or a method of keeping time. ...
-making. In the later years of his life he applied himself to the problem of obtaining
alumina Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly ...
in the I crystalline form, and succeeded in making
rubies Ruby is a pinkish-red-to-blood-red-colored gemstone, a variety of the mineral corundum (aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sapphi ...
identical with the natural gem not merely in chemical composition but also in physical properties.


Publications

In addition to numerous treatises in the ''Annales de Chimie et de Physique'', he published ''Traité de chimie générale'' (7 vols., 3rd ed. 1862-65). The ''Encyclopédie Chimique'', a work in 10 volumes, upon which he was engaged for thirteen years, was prepared by him in collaboration with several other scientists, and was completed in 1894.


Notes


References

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Further reading

* * {{DEFAULTSORT:Fremy, Edmond 1814 births 1894 deaths 19th-century French chemists Inorganic chemists Members of the French Academy of Sciences