The Edeleanu process is a type of
extraction process in the petroleum
refining
Refining is the process of purification of a (1) substance or a (2) form. The term is usually used of a natural resource that is almost in a usable form, but which is more useful in its pure form. For instance, most types of natural petroleum w ...
industry, whereby liquid
sulfur dioxide
Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a colorless gas with a pungent smell that is responsible for the odor of burnt matches. It is r ...
is used to extract
aromatic
In organic chemistry, aromaticity is a chemical property describing the way in which a conjugated system, conjugated ring of unsaturated bonds, lone pairs, or empty orbitals exhibits a stabilization stronger than would be expected from conjugati ...
s from
kerosene
Kerosene, or paraffin, is a combustibility, combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in Aviation fuel, aviation as well as households. Its name derives from the Greek (''kērós'') meaning " ...
. Liquid SO
2 selectively dissolves the aromatics leaving behind the low aromatic content kerosene as the finished product. It is named after the
Romania
Romania is a country located at the crossroads of Central Europe, Central, Eastern Europe, Eastern and Southeast Europe. It borders Ukraine to the north and east, Hungary to the west, Serbia to the southwest, Bulgaria to the south, Moldova to ...
n chemist
Lazăr Edeleanu
Lazăr Edeleanu (; 1 September 1861, Bucharest – 7 April 1941, Bucharest) was a Romanian chemist of Jewish origin. at www.romanianjewish.org He is known for being the first chemist to synthesize amphetamine at the University of Berlin and for ...
. The aromatic extract is then separated from SO
2 through
rectification and SO
2 recirculation. Temperature is maintained at -20°C.
[Robert L. Brandt (1930)]
The Edeleanu Process for Refining Petroleum
''Industrial & Engineering Chemistry'', 22 (3), pag. 218-223,
By using a blend of sulfur dioxide and
benzene
Benzene is an Organic compound, organic chemical compound with the Chemical formula#Molecular formula, molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar hexagonal Ring (chemistry), ring with one hyd ...
, some improvement can be effected, more suitable solvents such as
furfural
Furfural is an organic compound with the formula C4H3OCHO. It is a colorless liquid, although commercial samples are often brown. It has an aldehyde group attached to the 2-position of furan. It is a product of the dehydration of sugars, as occu ...
,
phenol
Phenol (also known as carbolic acid, phenolic acid, or benzenol) is an aromatic organic compound with the molecular formula . It is a white crystalline solid that is volatile and can catch fire.
The molecule consists of a phenyl group () ...
and N-methyl-2-pyrrolidone are used.
References
Oil refining
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