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Earth's outer core is a fluid layer about thick, composed of mostly
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
and nickel that lies above Earth's solid inner core and below its mantle. The outer core begins approximately beneath Earth's surface at the core-mantle boundary and ends beneath Earth's surface at the inner core boundary.


Properties

The outer core of Earth is liquid, unlike its inner core, which is solid. Evidence for a fluid outer core includes
seismology Seismology (; from Ancient Greek σεισμός (''seismós'') meaning "earthquake" and -λογία (''-logía'') meaning "study of") is the scientific study of earthquakes (or generally, quakes) and the generation and propagation of elastic ...
which shows that seismic shear-waves are not transmitted through the outer core. Although having a composition similar to Earth's solid inner core, the outer core remains liquid as there is not enough pressure to keep it in a solid state. Seismic inversions of body waves and normal modes constrain the radius of the outer core to be 3483 km with an uncertainty of 5 km, while that of the inner core is 1220±10 km. Estimates for the
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
of the outer core are about in its outer region and near the inner core. Modeling has shown that the outer core, because of its high temperature, is a low-
viscosity Viscosity is a measure of a fluid's rate-dependent drag (physics), resistance to a change in shape or to movement of its neighboring portions relative to one another. For liquids, it corresponds to the informal concept of ''thickness''; for e ...
fluid that convects turbulently. The dynamo theory sees eddy currents in the nickel-iron fluid of the outer core as the principal source of
Earth's magnetic field Earth's magnetic field, also known as the geomagnetic field, is the magnetic field that extends from structure of Earth, Earth's interior out into space, where it interacts with the solar wind, a stream of charged particles emanating from ...
. The average
magnetic field A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular ...
strength in Earth's outer core is estimated to be 2.5 millitesla, 50 times stronger than the magnetic field at the surface. As Earth's core cools, the liquid at the inner core boundary freezes, causing the solid inner core to grow at the expense of the outer core, at an estimated rate of 1 mm per year. This is approximately 80,000 tonnes of iron per second.


Light elements of Earth's outer core


Composition

Earth's outer core cannot be entirely constituted of iron or iron-nickel
alloy An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
because their densities are higher than geophysical measurements of the
density Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...
of Earth's outer core. In fact, Earth's outer core is approximately 5 to 10 percent lower density than
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
at Earth's core
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
s and
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
s. Hence it has been proposed that light elements with low
atomic number The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons, this is equal to the proton number (''n''p) or the number of pro ...
s compose part of Earth's outer core, as the only feasible way to lower its density. Although Earth's outer core is inaccessible to direct sampling, the composition of light elements can be meaningfully constrained by high-
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
experiments, calculations based on
seismic Seismology (; from Ancient Greek σεισμός (''seismós'') meaning "earthquake" and -λογία (''-logía'') meaning "study of") is the scientific study of earthquakes (or generally, quakes) and the generation and propagation of elastic ...
measurements, models of Earth's accretion, and carbonaceous chondrite meteorite comparisons with bulk silicate Earth (BSE). Recent estimates are that Earth's outer core is composed of
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
along with 0 to 0.26 percent
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
, 0.2 percent
carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
, 0.8 to 5.3 percent
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, 0 to 4.0 percent
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
, 1.7 percent
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
, and 5 percent nickel by weight, and the
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
of the core-mantle boundary and the inner core boundary ranges from 4,137 to 4,300 K and from 5,400 to 6,300 K respectively.


Constraints


= Accretion

= The variety of light elements present in Earth's outer core is constrained in part by Earth's accretion. Namely, the light elements contained must have been abundant during Earth's formation, must be able to partition into
liquid Liquid is a state of matter with a definite volume but no fixed shape. Liquids adapt to the shape of their container and are nearly incompressible, maintaining their volume even under pressure. The density of a liquid is usually close to th ...
iron at low
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
s, and must not volatilize and escape during Earth's accretionary process.


= CI chondrites

= CI chondritic meteorites are believed to contain the same planet-forming elements in the same proportions as in the early
Solar System The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Sola ...
, so differences between CI meteorites and BSE can provide insights into the light element composition of Earth's outer core. For instance, the depletion of
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
in Earth's
primitive mantle In geochemistry, the primitive mantle (also known as the ''bulk silicate Earth'') is the chemical composition of the Earth's mantle during the developmental stage between core-mantle differentiation and the formation of early continental crust. ...
compared to CI meteorites may indicate that silicon was absorbed into Earth's core; however, a wide range of silicon concentrations in Earth's outer and inner core is still possible.


Implications for Earth's accretion and core formation history

Tighter constraints on the concentrations of light elements in Earth's outer core would provide a better understanding of Earth's accretion and core formation history.


Consequences for Earth's accretion

Models of Earth's accretion could be better tested if we had better constraints on light element
concentration In chemistry, concentration is the abundance of a constituent divided by the total volume of a mixture. Several types of mathematical description can be distinguished: '' mass concentration'', '' molar concentration'', '' number concentration'', ...
s in Earth's outer core. For example, accretionary models based on core-mantle element partitioning tend to support proto-Earths constructed from reduced, condensed, and volatile-free material, despite the possibility that
oxidized Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
material from the outer
Solar System The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Sola ...
was accreted towards the conclusion of Earth's accretion. If we could better constrain the concentrations of
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
,
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, and
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
in Earth's outer core, models of Earth's accretion that match these concentrations would presumably better constrain Earth’s formation.


Consequences for Earth's core formation

The depletion of siderophile elements in
Earth's mantle Earth's mantle is a layer of silicate mineral, silicate rock between the Earth's crust, crust and the Earth's outer core, outer core. It has a mass of and makes up 67% of the mass of Earth. It has a thickness of making up about 46% of Earth's ...
compared to chondritic meteorites is attributed to metal-silicate reactions during formation of Earth's core. These reactions are dependent on
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
,
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
, and
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
, so better constraints on
concentrations In chemistry, concentration is the Abundance (chemistry), abundance of a constituent divided by the total volume of a mixture. Several types of mathematical description can be distinguished: ''mass concentration (chemistry), mass concentration'', ...
of these elements in Earth's outer core will help elucidate the conditions of formation of
Earth's core The internal structure of Earth are the layers of the Earth, excluding its atmosphere and hydrosphere. The structure consists of an outer silicate solid crust, a highly viscous asthenosphere, and solid mantle, a liquid outer core whose flow g ...
. In another example, the possible presence of
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
in Earth's outer core suggests that the accretion of Earth’s
water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
was not limited to the final stages of Earth's accretion and that
water Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known liv ...
may have been absorbed into core-forming metals through a hydrous
magma ocean Magma oceans are vast fields of surface magma that exist during periods of a planet's or some natural satellite's accretion when the celestial body is completely or partly molten. In the early Solar System, magma oceans were formed by the melt ...
.


Implications for Earth's magnetic field

Earth's magnetic field Earth's magnetic field, also known as the geomagnetic field, is the magnetic field that extends from structure of Earth, Earth's interior out into space, where it interacts with the solar wind, a stream of charged particles emanating from ...
is driven by thermal convection and also by chemical convection, the exclusion of light elements from the inner core, which float upward within the fluid outer core while denser elements sink. This chemical convection releases
gravitational energy Gravitational energy or gravitational potential energy is the potential energy an object with mass has due to the gravitational potential of its position in a gravitational field. Mathematically, it is the minimum mechanical work that has to be do ...
that is then available to power the
geodynamo In physics, the dynamo theory proposes a mechanism by which a celestial body such as Earth or a star generates a magnetic field. The dynamo theory describes the process through which a rotating, convecting, and electrically conducting fluid can ...
that produces Earth's magnetic field. Carnot efficiencies with large uncertainties suggest that compositional and thermal convection contribute about 80 percent and 20 percent respectively to the power of Earth's geodynamo. Traditionally it was thought that prior to the formation of
Earth's inner core Earth's inner core is the innermost geologic layer of the planet Earth. It is primarily a solid ball with a radius of about , which is about 20% of Earth's radius or 70% of the Moon's radius. There are no samples of the core accessible for d ...
, Earth's geodynamo was mainly driven by thermal convection. However, recent claims that the
thermal conductivity The thermal conductivity of a material is a measure of its ability to heat conduction, conduct heat. It is commonly denoted by k, \lambda, or \kappa and is measured in W·m−1·K−1. Heat transfer occurs at a lower rate in materials of low ...
of
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
at core
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
s and pressures is much higher than previously thought imply that core cooling was largely by conduction not convection, limiting the ability of thermal convection to drive the geodynamo. This conundrum is known as the new "core paradox." An alternative process that could have sustained Earth's geodynamo requires Earth's core to have initially been hot enough to dissolve
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
,
magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
,
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
, and other light elements. As the Earth's core began to cool, it would become
supersaturated In physical chemistry, supersaturation occurs with a solution when the concentration of a solute exceeds the concentration specified by the value of solubility at equilibrium. Most commonly the term is applied to a solution of a solid in a ...
in these light elements that would then
precipitate In an aqueous solution, precipitation is the "sedimentation of a solid material (a precipitate) from a liquid solution". The solid formed is called the precipitate. In case of an inorganic chemical reaction leading to precipitation, the chemic ...
into the lower mantle forming
oxide An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation st ...
s leading to a different variant of chemical convection. The magnetic field generated by core flow is essential to protect life from interplanetary radiation and prevent the atmosphere from dissipating in the
solar wind The solar wind is a stream of charged particles released from the Sun's outermost atmospheric layer, the Stellar corona, corona. This Plasma (physics), plasma mostly consists of electrons, protons and alpha particles with kinetic energy betwee ...
. The rate of cooling by conduction and convection is uncertain, but one estimate is that the core would not be expected to freeze up for approximately 91 billion years, which is well after the Sun is expected to expand, sterilize the surface of the planet, and then burn out.


See also

*
Hollow Earth The Hollow Earth is a concept proposing that the planet Earth is entirely hollow or contains a substantial interior space. Notably suggested by Edmond Halley in the late 17th century, the notion was disproven, first tentatively by Pierre Bougue ...
* Geological history of Earth *
Large low-shear-velocity provinces Large low-shear-velocity provinces (LLSVPs), also called large low-velocity provinces (LLVPs) or superplumes, are characteristic structures of parts of the lowermost mantle, the region surrounding the outer core deep inside the Earth. These provi ...
* Lehmann discontinuity * Rain-out model * Seismic tomography – technique for imaging the subsurface of Earth using seismic waves *
Travel to the Earth's center Travelling to the Earth's center is a popular List of science fiction themes, theme in science fiction. Some subterranean fiction involves traveling to the Earth's center and finding either a hollow Earth or Inner core, Earth's molten core. pla ...
*
Solid earth Solid earth refers to "the earth beneath our feet" or '' terra firma'', the planet's solid surface and its interior. It excludes the Earth's fluid envelopes, the atmosphere and hydrosphere (but includes the ocean basin), as well as the biosphere ...


References


External links

{{Authority control Structure of the Earth Geomagnetism