Duftite is a relatively common

arsenate mineral Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or ...

with the formula CuPb(AsO₄)(OH), related to

conichalcite Conichalcite, Ca Cu( As O4)(O H), is a relatively common arsenate mineral related to duftite ( PbCu(AsO4)(OH)). It is green, often botryoidal, and occurs in the oxidation zone of some metal deposits. It occurs with limonite, malachite, beudant ...

. It is green and often forms

botryoidal A botryoidal ( ) texture or mineral habit, is one in which the mineral has an external form composed of many rounded segments, named for the Ancient Greek (), meaning "a bunch of grapes".Adjective form: ''botruoeidēs'' This is a common form f ...

aggregates. It is a member of the adelite-

descloizite Descloizite is a rare mineral species consisting of basic lead and zinc vanadium, vanadate, , crystallizing in the orthorhombic crystal system and isomorphous with olivenite. Appreciable gallium and germanium may also be incorporated into the cr ...

Group, Conichalcite-Duftite Series. Duftite and conichalcite specimens from Tsumeb are commonly zoned in color and composition. Microprobe analyses and X-ray powder-diffraction studies indicate extensive substitution of Zn for Cu, and Ca for Pb in the duftite structure. This indicates a solid solution among conichalcite, CaCu(AsO₄ )(OH),

austinite Austinite is a member of the adelite-descloizite group, adelite subgroup, the zinc (Zn) end member of the copper-Zn series with conichalcite. It is the zinc analogue of cobaltaustinite and nickelaustinite. At one time “brickerite” was thoug ...

, CaZn(AsO₄)(OH) and duftite PbCu(AsO₄)(OH), all of them belonging to the adelite group of arsenates. It was named after Mining Councilor G Duft, Director of the Otavi Mine and Railroad Company, Tsumeb, Namibia. The type locality is the Tsumeb Mine,

Tsumeb Tsumeb (; ) is a city of around 35,000 inhabitants and the largest town in the Oshikoto Region, Oshikoto region in northern Namibia. Tsumeb, since its founding in 1905, has been primarily a mining town. The town is the site of a deep mine (the ...

, Otjikoto Region, Namibia.

Structure

The structure is composed of chains of edge-sharing CuO₆ distorted octahedra parallel to the c axis. The chains are linked by AsO₄ tetrahedra and Pb atoms.

Environment

Duftite is an uncommon product of weathered

sulfide ore Sulfide (also sulphide in British English) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to large families of ...

deposits. It is associated with

azurite Azurite or '' Azure spar'Krivovichev V. G.'' Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0. ''(in Russian)'' is a soft, deep-blue copp ...

at the type locality, and with bayldonite, segnitite,

agardite Agardite is a mineral group consisting of agardite-(Y), agardite-(Ce), agardite-(Nd), and agardite-(La). They comprise a group of minerals that are hydrous hydrated arsenates of rare-earth elements (REE) and copper, with the general chemical for ...

and gartrellite at the Central Cobar Mines, New South Wales, Australia, where some pseudomorphs of duftite after

mimetite Mimetite is a lead arsenate chloride mineral () which forms as a secondary mineral in lead deposits, usually by the Redox, oxidation of galena and arsenopyrite. The name derives from the Greek ''mimetes'', meaning "imitator" and refers to mimeti ...

have also found. It occurs in association with

olivenite Olivenite is a copper arsenate mineral, formula Cu2 As O4O H. It crystallizes in the monoclinic system (pseudo-orthorhombic), and is sometimes found in small brilliant crystals of simple prismatic habit terminated by domal faces. More commonly ...

mottramite Mottramite is an orthorhombic anhydrous vanadate hydroxide mineral, lead, Pbcopper, Cu(vanadium, Voxygen, O4)(Ohydrogen, H), at the copper end of the descloizite subgroup. It was formerly called cuprodescloizite or psittacinite (this mineral cha ...

malachite Malachite () is a copper Carbonate mineral, carbonate hydroxide mineral, with the chemical formula, formula Basic copper carbonate, Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often for ...

wulfenite Wulfenite is a lead molybdate mineral with the formula Pb Mo O4. It often occurs as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form it is some ...

and

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

in the Tsumeb, Namibia deposit. It occurs with

bayldonite Bayldonite (BAIL-done-ite) is a rare secondary mineral with the chemical formula PbCu3(AsO4)2(OH)2. Its provenance has been attributed to Penberthy Croft Mine, Cornwall, England, United Kingdom but there is no substantiating evidence for this and ...

beudantite Beudandite is a secondary mineral occurring in the Oxidation, oxidized zones of Polymetal, polymetallic deposits. It is a lead, iron, Arsenate mineral, arsenate, sulfate mineral, sulfate with Chemical formula, endmember formula: PbFe3(OH)6SO4AsO4 ...

and

cerussite Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate with the chemical formula PbCO3, and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was ...

in the Cap Garonne mine,

France France, officially the French Republic, is a country located primarily in Western Europe. Overseas France, Its overseas regions and territories include French Guiana in South America, Saint Pierre and Miquelon in the Atlantic Ocean#North Atlan ...

Distribution

Reported from Argentina, Australia, Austria, Chile, the Czech Republic, France, Germany, Greece, Italy, Japan, Mexico, Namibia, Poland, Portugal, Russia, South Africa, Spain, Switzerland, the UK, the US and Zimbabwe.

References

Bibliography

*Palache, P.; Berman H.; Frondel, C. (1960). "''Dana's System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. (Seventh Edition)"'' John Wiley and Sons, Inc., New York, pp. 810-811. {{Commons category, Duftite, position=left Arsenate minerals Copper(II) minerals Lead minerals Orthorhombic minerals Minerals in space group 19