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The Dufour effect is the
energy flux Energy flux is the rate of transfer of energy through a surface. The quantity is defined in two different ways, depending on the context: # Total rate of energy transfer (not per unit area); SI units: W = J⋅s−1. # Specific rate of energy tran ...
due to a mass
concentration gradient Fick's laws of diffusion describe diffusion and were first posited by Adolf Fick in 1855 on the basis of largely experimental results. They can be used to solve for the diffusion coefficient, . Fick's first law can be used to derive his second ...
occurring as a coupled effect of
irreversible process In thermodynamics, an irreversible process is a thermodynamic processes, process that cannot be undone. All complex natural processes are irreversible, although a phase transition at the coexistence temperature (e.g. melting of ice cubes in wate ...
es, named after L. Dufour. It is the reciprocal phenomenon to the Soret effect. The concentration gradient results in a temperature change. For binary liquid mixtures, the Dufour effect is usually considered negligible, whereas in binary gas mixtures the effect can be significant.


References

Thermodynamics {{thermodynamics-stub