Donald Mastick
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Donald Francis Mastick (September 1, 1920 – September 8, 2007) was an American chemist who worked at the
Manhattan Project The Manhattan Project was a research and development program undertaken during World War II to produce the first nuclear weapons. It was led by the United States in collaboration with the United Kingdom and Canada. From 1942 to 1946, the ...
's
Los Alamos Laboratory The Los Alamos Laboratory, also known as Project Y, was a secret scientific laboratory established by the Manhattan Project and overseen by the University of California during World War II. It was operated in partnership with the United State ...
. As part of
Project Alberta Project Alberta, also known as Project A, was a section of the Manhattan Project which assisted in delivering the first nuclear weapons in the atomic bombing of Hiroshima and Nagasaki during World War II. Project Alberta was formed in March 1 ...
, he was part of the planning and preparation for the
atomic bombing of Hiroshima and Nagasaki On 6 and 9 August 1945, the United States detonated two atomic bombs over the Japanese cities of Hiroshima and Nagasaki, respectively, during World War II. The aerial bombings killed between 150,000 and 246,000 people, most of whom were civil ...
, for which he was awarded the
Bronze Star Medal The Bronze Star Medal (BSM) is a Awards and decorations of the United States Armed Forces, United States Armed Forces decoration awarded to members of the United States Armed Forces for either heroic achievement, heroic service, meritorious a ...
. Mastick is known for a lab incident in 1944 when he accidentally ingested a small amount of
plutonium Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...
, traces of which remained detectable in his body decades later. After the incident, he worked for the Naval Radiological Defense Laboratory and the Atomic Energy Commission.


Early life

Donald Francis Mastick was born in
St. Helena, California St. Helena ( ) is a city in Napa County, California, United States. Located in the North Bay region of the San Francisco Bay Area, the population was 5,430 at the 2020 census.US Census Bureau, 2020 report Quick Facts, St. Helena city, Califor ...
, the son of Spencer Mastick and his wife Frankie Hite. He grew up in the
Napa Valley Napa Valley is an American Viticultural Area (AVA) in Napa County, California. The area was established by the Bureau of Alcohol, Tobacco, Firearms and Explosives (ATF) on February 27, 1981, after a 1978 petition submitted by the Napa Valley Vin ...
. He entered the
University of California, Berkeley The University of California, Berkeley (UC Berkeley, Berkeley, Cal, or California), is a Public university, public Land-grant university, land-grant research university in Berkeley, California, United States. Founded in 1868 and named after t ...
, where he studied
chemistry Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules a ...
, graduating with his
Bachelor of Science A Bachelor of Science (BS, BSc, B.S., B.Sc., SB, or ScB; from the Latin ') is a bachelor's degree that is awarded for programs that generally last three to five years. The first university to admit a student to the degree of Bachelor of Scienc ...
degree in 1942. He was a member of the
Phi Beta Kappa The Phi Beta Kappa Society () is the oldest academic honor society in the United States. It was founded in 1776 at the College of William & Mary in Virginia. Phi Beta Kappa aims to promote and advocate excellence in the liberal arts and sciences, ...
and
Sigma Xi Sigma Xi, The Scientific Research Honor Society () is an international non-profit honor society for scientists and engineers. Sigma Xi was founded at Cornell University by a faculty member and graduate students in 1886 and is one of the oldest ...
honor societies In the United States, an honor society is an organization that recognizes individuals who rank above a set standard in various domains such as academics, leadership, and other personal achievements, not all of which are based on ranking systems. ...
.


Manhattan Project

By the time Mastick graduated, the United States had entered
World War II World War II or the Second World War (1 September 1939 – 2 September 1945) was a World war, global conflict between two coalitions: the Allies of World War II, Allies and the Axis powers. World War II by country, Nearly all of the wo ...
. Mastick was studying radioactive carbon. He told Professor Wendell Latimer that he could not stand by while there was a war on, and that he was leaving. Latimer suggested that he instead join a secret project, which would lead to a commission in the
United States Navy The United States Navy (USN) is the naval warfare, maritime military branch, service branch of the United States Department of Defense. It is the world's most powerful navy with the largest Displacement (ship), displacement, at 4.5 millio ...
. He introduced him to
Robert Oppenheimer J. Robert Oppenheimer (born Julius Robert Oppenheimer ; April 22, 1904 – February 18, 1967) was an American theoretical physicist who served as the director of the Manhattan Project's Los Alamos Laboratory during World War II. He is often ...
, who recruited him for the
Manhattan Project The Manhattan Project was a research and development program undertaken during World War II to produce the first nuclear weapons. It was led by the United States in collaboration with the United Kingdom and Canada. From 1942 to 1946, the ...
. Initially, Mastick's job was to draw up lists of equipment required by the chemistry laboratories at the
Los Alamos Laboratory The Los Alamos Laboratory, also known as Project Y, was a secret scientific laboratory established by the Manhattan Project and overseen by the University of California during World War II. It was operated in partnership with the United State ...
, which were then under construction. Mastick moved to Los Alamos early in 1943, where he worked in the Chemistry Division and studied the mysterious chemical properties of
plutonium Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four ...
, a synthetic element then available only in microscopic quantities. Although young, he was a member of the group that planned the laboratory's scientific program, along with Robert Wilson,
Robert Serber Robert Serber (March 14, 1909 – June 1, 1997) was an American physicist who participated in the Manhattan Project. Serber's lectures explaining the basic principles and goals of the project were printed and supplied to all incoming scientific st ...
,
John Williams John Towner Williams (born February 8, 1932)Nylund, Rob (November 15, 2022)Classic Connection review, ''WBOI'' ("For the second time this year, the Fort Wayne Philharmonic honored American composer, conductor, and arranger John Williams, who w ...
and
Edwin McMillan Edwin Mattison McMillan (September 18, 1907 – September 7, 1991) was an American physicist credited with being the first to produce a transuranium element, neptunium. For this, he shared the 1951 Nobel Prize in Chemistry with Glenn Seaborg. ...
. On August 1, 1944, Mastick and his laboratory partner,
Arthur Wahl Arthur Charles Wahl (September 8, 1917 – March 6, 2006) was an American chemist who, as a doctoral student of Glenn T. Seaborg at the University of California, Berkeley, first isolated plutonium (94) in February 1941 shortly after the elem ...
, were working with a vial containing 10 milligrams of
plutonium chloride Plutonium(III) chloride is a chemical compound with the formula PuCl3. This ionic plutonium salt can be prepared by reacting the metal with hydrochloric acid. Structure Plutonium atoms in crystalline PuCl3 are 9 coordinate, and the structure is ...
dissolved in an acid solution when the vial exploded. Gases had built up in the vial overnight, most likely through the dissociation of water molecules due to
alpha radiation Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an atom ...
from the plutonium. Mastick tasted some of the acid in his mouth, so he knew that he had ingested some plutonium. Mastick replaced the vial in its wooden container, and went to see Dr. Louis Hempelmann, the director of the Health Group at Los Alamos. Hempelmann phoned Colonel Stafford L. Warren, the Manhattan Project's medical director, at the
Clinton Engineer Works The Clinton Engineer Works (CEW) was the production installation of the Manhattan Project that during World War II produced the enriched uranium used in the 1945 bombing of Hiroshima, as well as the first examples of reactor-produced pluton ...
in
Oak Ridge, Tennessee Oak Ridge is a city in Anderson County, Tennessee, Anderson and Roane County, Tennessee, Roane counties in the East Tennessee, eastern part of the U.S. state of Tennessee, about west of downtown Knoxville, Tennessee, Knoxville. Oak Ridge's po ...
. Mastick's face was scrubbed, but his skin remained contaminated with a microgram of plutonium. Hempelmann gave him a mouthwash of
trisodium citrate Trisodium citrate is a chemical compound with the molecular formula Na3C6H5O7. It is sometimes referred to simply as " sodium citrate", though sodium citrate can refer to any of the three sodium salts of citric acid. It possesses a saline, mild ...
, which would combine with the plutonium to form a soluble liquid, and
sodium bicarbonate Sodium bicarbonate ( IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda (or simply “bicarb” especially in the UK) is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cat ...
, which would make it solid again. This removed most of the plutonium. Nonetheless, for days afterwards his breath could make the needle on an
ionization chamber The ionization chamber is the simplest type of gaseous ionisation detector, and is widely used for the detection and measurement of many types of ionizing radiation, including X-rays, gamma rays, alpha particles and beta particles. Conventionall ...
go off the scale, even from away. Hempelmann used a
stomach pump Gastric lavage, also commonly called stomach pumping or gastric irrigation or gastric suction, is the process of cleaning out the contents of the stomach using a tube. Since its first recorded use in the early 19th century, it has become one of the ...
to retrieve plutonium that had been swallowed, which recovered about 60 nanograms of plutonium.
Urine Urine is a liquid by-product of metabolism in humans and many other animals. In placental mammals, urine flows from the Kidney (vertebrates), kidneys through the ureters to the urinary bladder and exits the urethra through the penile meatus (mal ...
assays indicated that less than 1 microgram remained in his body. Some was still detectable 30 years later. Unable to work in the Chemistry Division any more because of the accident, Mastick suggested to Oppenheimer that he become an assistant to
Commander Commander (commonly abbreviated as Cmdr.) is a common naval officer rank as well as a job title in many army, armies. Commander is also used as a rank or title in other formal organizations, including several police forces. In several countri ...
Frederick Ashworth. Mastick initially served as Ashworth's administrative assistant, but soon became involved in the drop-testing of
pumpkin bomb Pumpkin bombs were conventional aerial bombs developed by the Manhattan Project and used by the United States Army Air Forces against Japan during World War II. Its physical characteristics closely replicated those of the Fat Man plutonium b ...
s in the
Salton Sea The Salton Sea is a shallow, landlocked, highly salinity, saline endorheic lake in Riverside County, California, Riverside and Imperial County, California, Imperial counties in Southern California. It lies on the San Andreas Fault within the S ...
,
Silverplate Silverplate was the code reference for the United States Army Air Forces' participation in the Manhattan Project during World War II. Originally the name for the aircraft modification project which enabled a B-29 Superfortress bomber to drop ...
modifications to the
Boeing B-29 Superfortress The Boeing B-29 Superfortress is a retired American four-engined propeller-driven heavy bomber, designed by Boeing and flown primarily by the United States during World War II and the Korean War. Named in allusion to its predecessor, the Bo ...
to carry nuclear weapons, and modifications to the casing and tail configurations of the bombs themselves. He also investigated the inadvertent dropping of
Little Boy Little Boy was a type of atomic bomb created by the Manhattan Project during World War II. The name is also often used to describe the specific bomb (L-11) used in the bombing of the Japanese city of Hiroshima by the Boeing B-29 Superfortress ...
due to a faulty electrical circuit. Mastick was commissioned as an
ensign Ensign most often refers to: * Ensign (flag), a flag flown on a vessel to indicate nationality * Ensign (rank), a navy (and former army) officer rank Ensign or The Ensign may also refer to: Places * Ensign, Alberta, Alberta, Canada * Ensign, Ka ...
in the
United States Navy Reserve The United States Navy Reserve (USNR), known as the United States Naval Reserve from 1915 to 2004, is the Reserve Component (RC) of the United States Navy. Members of the Navy Reserve, called reservists, are categorized as being in either the S ...
in June 1945. Five days later he headed to
Tinian Tinian () is one of the three principal islands of the Commonwealth of the Northern Mariana Islands (CNMI). Together with uninhabited neighboring Aguiguan, it forms Tinian Municipality, one of the four constituent municipalities of the Northern ...
as part of
Project Alberta Project Alberta, also known as Project A, was a section of the Manhattan Project which assisted in delivering the first nuclear weapons in the atomic bombing of Hiroshima and Nagasaki during World War II. Project Alberta was formed in March 1 ...
. For his part in the
atomic bombing of Hiroshima and Nagasaki On 6 and 9 August 1945, the United States detonated two atomic bombs over the Japanese cities of Hiroshima and Nagasaki, respectively, during World War II. The aerial bombings killed between 150,000 and 246,000 people, most of whom were civil ...
, he was awarded the
Bronze Star Medal The Bronze Star Medal (BSM) is a Awards and decorations of the United States Armed Forces, United States Armed Forces decoration awarded to members of the United States Armed Forces for either heroic achievement, heroic service, meritorious a ...
. After the war ended he participated in the
Operation Crossroads Operation Crossroads was a pair of nuclear weapon tests conducted by the United States at Bikini Atoll in mid-1946. They were the first nuclear weapon tests since Trinity on July 16, 1945, and the first detonations of nuclear devices sinc ...
nuclear tests at
Bikini Atoll Bikini Atoll ( or ; Marshallese language, Marshallese: , , ), known as Eschscholtz Atoll between the 19th century and 1946, is a coral reef in the Marshall Islands consisting of 23 islands surrounding a central lagoon. The atoll is at the no ...
. He left the Navy with the rank of
lieutenant (junior grade) Lieutenant junior grade is a junior commissioned officer rank used in a number of navies. United States Lieutenant (junior grade), commonly abbreviated as LTJG or, historically, Lt. (j.g.) (as well as variants of both abbreviations), i ...
.


Post-war

Mastick returned to the University of California, where he earned his
PhD A Doctor of Philosophy (PhD, DPhil; or ) is a terminal degree that usually denotes the highest level of academic achievement in a given discipline and is awarded following a course of graduate study and original research. The name of the deg ...
in 1950, writing his thesis on ''A study of gaseous oxides at high temperatures''. He became the head of the Radiochemical Research section at the Naval Radiological Defense Laboratory San Francisco. In 1951 he joined the Atomic Energy Commission, as a scientific advisor and the manager of the Division of Military Applications. He then became vice president and Director of Precision Technology at General Precision Equipment. In 1957, he joined
Stauffer Chemical Stauffer Chemical Company was an American chemical company which manufactured herbicides and pesticides for various agricultural crops. It was acquired by Imperial Chemical Industries from Chesebrough-Pond's Inc. in 1987. In 1987, Stauffer's he ...
as its director of research. He married Irene Pietrusiak, and they had a daughter, Patricia. In 1971, they started an interior landscape company, Foliage Plant Systems. Initially located in
Saddle River, New Jersey Saddle River is a borough in Bergen County, in the U.S. state of New Jersey. It is a suburb of New York City, located just over northwest of Manhattan. The town is known for its natural fields, farmland, horse farms, forests, and rivers, and ...
, the business subsequently expanded into seven states, and earned accolades including one presented by
Nancy Reagan Nancy Davis Reagan (; born Anne Frances Robbins; July 6, 1921 – March 6, 2016) was an American film actress who was the first lady of the United States from 1981 to 1989, as the second wife of President Ronald Reagan. Reagan was born in ...
at the
White House The White House is the official residence and workplace of the president of the United States. Located at 1600 Pennsylvania Avenue Northwest (Washington, D.C.), NW in Washington, D.C., it has served as the residence of every U.S. president ...
in
Washington, D.C. Washington, D.C., formally the District of Columbia and commonly known as Washington or D.C., is the capital city and federal district of the United States. The city is on the Potomac River, across from Virginia, and shares land borders with ...
Mastick died in
Santa Barbara, California Santa Barbara (, meaning ) is a coastal city in Santa Barbara County, California, of which it is also the county seat. Situated on a south-facing section of coastline, the longest such section on the West Coast of the United States excepting A ...
, on September 8, 2007.


Notes


References

* * * * * {{DEFAULTSORT:Mastick, Donald F. 1920 births 2007 deaths Manhattan Project people American chemists University of California, Berkeley alumni People associated with the atomic bombings of Hiroshima and Nagasaki United States Navy personnel of World War II