Don Juan Pond
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Don Juan Pond is a small and very shallow hypersaline lake in the western end of Wright Valley (South Fork),
Victoria Land Victoria Land is a region in eastern Antarctica which fronts the western side of the Ross Sea and the Ross Ice Shelf, extending southward from about 70°30'S to 78th parallel south, 78°00'S, and westward from the Ross Sea to the edge of the Ant ...
,
Antarctica Antarctica () is Earth's southernmost and least-populated continent. Situated almost entirely south of the Antarctic Circle and surrounded by the Southern Ocean (also known as the Antarctic Ocean), it contains the geographic South Pole. ...
, west from Lake Vanda. It is wedged between the Asgard Range to the south and the Dais Range to the north. On the west end is a small tributary and a rock glacier. With a salinity level of 45.8%, Don Juan Pond is the saltiest of the Antarctic lakes. This salinity causes significant
freezing-point depression Freezing-point depression is a drop in the maximum temperature at which a substance freezing, freezes, caused when a smaller amount of another, non-Volatility (chemistry), volatile substance is added. Examples include adding salt into water (u ...
, allowing the pond to remain liquid even at temperatures as low as . Don Juan Pond was discovered in 1961. It was named for two helicopter pilots, Lt. Don Roe and Lt. John Hickey, who piloted the helicopter involved with the first field party investigating the pond.


Salinity

Don Juan Pond is a shallow, flat-bottom, hyper-saline pond. It has the second-highest total dissolved solids on record, 1.3 times greater
salinity Salinity () is the saltiness or amount of salt (chemistry), salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensio ...
than the
Dead Sea The Dead Sea (; or ; ), also known by #Names, other names, is a landlocked salt lake bordered by Jordan to the east, the Israeli-occupied West Bank to the west and Israel to the southwest. It lies in the endorheic basin of the Jordan Rift Valle ...
. Salinity varies over time from 200 to 474 g/L, dominated by calcium chloride. It is the only Antarctic hypersaline lake that almost never freezes. The area around Don Juan Pond is covered with
sodium chloride Sodium chloride , commonly known as Salt#Edible salt, edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. It is transparent or translucent, brittle, hygroscopic, and occurs a ...
and
calcium chloride Calcium chloride is an inorganic compound, a Salt (chemistry), salt with the chemical formula . It is a white crystalline solid at room temperature, and it is highly soluble in water. It can be created by neutralising hydrochloric acid with cal ...
salts that have precipitated as the water evaporated. The area and volume of Don Juan Pond vary over time. According to the
United States Geological Survey The United States Geological Survey (USGS), founded as the Geological Survey, is an agency of the U.S. Department of the Interior whose work spans the disciplines of biology, geography, geology, and hydrology. The agency was founded on Mar ...
topographical map published in 1977, the area was approximately . However, in recent years the pond has shrunk considerably. The maximum depth in 1993–1994 was described as "a foot deep" (). In January 1997, it was approximately deep;Salty Antarctic pond could be a replica of Mars' water
''Astrobiology Magazine''. 23 November 2017.
in December 1998, the pond was almost dry everywhere except for an area of a few tens of square metres. Most of the remaining water was in depressions around large boulders in the pond.


Origin of Water and Salts

The extreme salinity of Don Juan Pond (DJP) has been the subject of extensive research, with multiple competing or complementary mechanisms proposed regarding the sources of its water and high salt content.


Water

One prominent hypothesis suggests that DJP is primarily fed by near-surface processes. Studies have observed that calcium chloride-rich brines form through the deliquescence of
hygroscopic Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption (chemistry), absorption or adsorption from the surrounding Natural environment, environment, which is usually at normal or room temperature. If water mol ...
salts in the surrounding soils, absorbing atmospheric moisture. These brines then flow downslope along shallow subsurface pathways, known as water tracks, into the pond. This mechanism is supported by time-lapse imagery and soil moisture measurements indicating active brine transport during warmer periods. Alternatively, other research points to a deep
groundwater Groundwater is the water present beneath Earth's surface in rock and Pore space in soil, soil pore spaces and in the fractures of stratum, rock formations. About 30 percent of all readily available fresh water in the world is groundwater. A unit ...
source as the primary contributor to DJP's salinity.
Geochemical Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the ...
analyses and modeling have demonstrated that the pond's unique calcium chloride-dominated composition is consistent with upwelling from a regional deep groundwater system. This groundwater is believed to interact with subsurface minerals, enriching the water with calcium chloride before it reaches the pond.


Salt

The precise origin of the salts remains a topic of ongoing investigation. Some studies suggest that the calcium chloride may result from interactions between percolating water and the surrounding geological formations, particularly the weathered dolerite bedrock. This process could leach calcium ions into the water, contributing to the pond's high salinity. Both near-surface brine flows and deeper groundwater sources are thought to contribute to Don Juan Pond's hydrology, though the relative importance of each mechanism remains uncertain. Continued research into these processes may also inform studies of similar saline environments on other planetary bodies, such as Mars.


Life

Studies of lifeforms in the hypersaline (and/or brine) water of Don Juan Pond have found a "sparse microflora of four species of heterotrophic bacteria and a yeast".


Literature

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References


External links


Great Zoom into Don Juan Pond, Antarctica
* {{gnis, 3975, type=antarid
Don Juan Pond GigaPan picture
Lakes of Victoria Land Saline lakes of Antarctica Endorheic lakes of Antarctica McMurdo Dry Valleys