Dichroism
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In
optics Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of optical instruments, instruments that use or Photodetector, detect it. Optics usually describes t ...
, a dichroic material is either one which causes
visible light Light, visible light, or visible radiation is electromagnetic radiation that can be perceived by the human eye. Visible light spans the visible spectrum and is usually defined as having wavelengths in the range of 400–700 nanometres (nm ...
to be split up into distinct beams of different
wavelength In physics and mathematics, wavelength or spatial period of a wave or periodic function is the distance over which the wave's shape repeats. In other words, it is the distance between consecutive corresponding points of the same ''phase (waves ...
s (
colour Color (or colour in Commonwealth English; see spelling differences) is the visual perception based on the electromagnetic spectrum. Though color is not an inherent property of matter, color perception is related to an object's light absorp ...
s) (not to be confused with dispersion), or one in which light rays having different polarizations are absorbed by different amounts.


In beam splitters

The original meaning of ''dichroic'', from the
Greek Greek may refer to: Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group *Greek language, a branch of the Indo-European language family **Proto-Greek language, the assumed last common ancestor of all kno ...
''dikhroos'', two-coloured, refers to any optical device which can split a beam of light into two beams with differing wavelengths. Such devices include
mirror A mirror, also known as a looking glass, is an object that Reflection (physics), reflects an image. Light that bounces off a mirror forms an image of whatever is in front of it, which is then focused through the lens of the eye or a camera ...
s and filters, usually treated with
optical coating An optical coating is one or more thin-film optics, thin layers of material deposited on an optical component such as a lens (optics), lens, prism (optics), prism or mirror, which alters the way in which the optic reflection (physics), reflects a ...
s, which are designed to reflect light over a certain range of wavelengths and transmit light which is outside that range. An example is the
dichroic prism A dichroic prism is a prism (optics), prism that splits light into two beams of differing wavelength, wavelengths (colour). A trichroic prism assembly combines two dichroic prisms to split an image into 3 colours, typically as red, green and blue ...
, used in some
camcorder A camcorder is a self-contained portable electronic device with video and recording as its primary function. It is typically equipped with an articulating screen mounted on the left side, a belt to facilitate holding on the right side, hot-sw ...
s, which uses several coatings to split light into red, green and blue components for recording on separate CCD arrays, however it is now more common to have a
Bayer filter A Bayer filter mosaic is a color filter array (CFA) for arranging RGB color model, RGB color filters on a square grid of photosensors. Its particular arrangement of color filters is used in most single-chip digital image sensors used in digit ...
to filter individual pixels on a single CCD array. This kind of dichroic device does not usually depend on the polarization of the light. The term ''dichromatic'' is also used in this sense.


With polarized light

The second meaning of ''dichroic'' refers to the property of a material, in which light in different polarization states traveling through it experiences a different absorption coefficient; this is also known as diattenuation. When the polarization states in question are right and left-handed
circular polarization In electrodynamics, circular polarization of an electromagnetic wave is a polarization state in which, at each point, the electromagnetic field of the wave has a constant magnitude and is rotating at a constant rate in a plane perpendicular to ...
, it is then known as circular dichroism (CD). Most materials exhibiting CD are
chiral Chirality () is a property of asymmetry important in several branches of science. The word ''chirality'' is derived from the Greek language, Greek (''kheir''), "hand", a familiar chiral object. An object or a system is ''chiral'' if it is dist ...
, although non-chiral materials showing CD have been recently observed. Since the left- and right-handed circular polarizations represent two spin angular momentum (SAM) states, in this case for a photon, this dichroism can also be thought of as spin angular momentum dichroism and could be modelled using
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
. In some
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
s,, such as
tourmaline Tourmaline ( ) is a crystalline silicate mineral, silicate mineral group in which boron is chemical compound, compounded with chemical element, elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a ...
, the strength of the dichroic effect varies strongly with the wavelength of the light, making them appear to have different colours when viewed with light having differing polarizations. This is more generally referred to as
pleochroism Pleochroism is an optical phenomenon in which a substance has different colors when observed at different angles, especially with Polarization (waves), polarized light. Etymology The roots of the word are from Greek (). It was first made compou ...
, and the technique can be used in
mineralogy Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical mineralogy, optical) properties of minerals and mineralized artifact (archaeology), artifacts. Specific s ...
to identify
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
s. In some materials, such as
herapathite Herapathite, or iodoquinine sulfate, is a chemical compound whose crystals are dichroic and thus can be used for polarizing light. Its formation was investigated by 1852 by William Bird Herapath, a Bristol surgeon and chemist, after his pupil (M ...
(iodoquinine sulfate) or Polaroid sheets, the effect is not strongly dependent on wavelength.


In liquid crystals

Dichroism, in the second meaning above, occurs in
liquid crystals Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal can flow like a liquid, but its molecules may be oriented in a common direction as i ...
due to either the optical anisotropy of the molecular structure or the presence of impurities or the presence of dichroic dyes. The latter is also called a '' guest–host effect''.


See also

*
Birefringence Birefringence, also called double refraction, is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are described as birefrin ...
* Dichromatism * Lycurgus Cup *
Pleochroism Pleochroism is an optical phenomenon in which a substance has different colors when observed at different angles, especially with Polarization (waves), polarized light. Etymology The roots of the word are from Greek (). It was first made compou ...


References

{{Authority control Polarization (waves)