A desalter is a process unit in an
oil refinery
An oil refinery or petroleum refinery is an industrial processes, industrial process Factory, plant where petroleum (crude oil) is transformed and refining, refined into products such as gasoline (petrol), diesel fuel, Bitumen, asphalt base, ...
that removes salt from the
crude oil
Petroleum, also known as crude oil or simply oil, is a naturally occurring, yellowish-black liquid chemical mixture found in geological formations, consisting mainly of hydrocarbons. The term ''petroleum'' refers both to naturally occurring u ...
. The salt is dissolved in the water in the crude oil, not in the crude oil itself. The desalting is usually the first process in crude oil refining. The salt content after the desalter is usually measured in PTB – pounds of salt per thousand
barrel
A barrel or cask is a hollow cylindrical container with a bulging center, longer than it is wide. They are traditionally made of wooden stave (wood), staves and bound by wooden or metal hoops. The word vat is often used for large containers ...
s of crude oil. Another specification is
Basic sediment and water.
The term desalter may also refer to a
water desalination
Desalination is a process that removes mineral components from saline water. More generally, desalination is the removal of salts and minerals from a substance. One example is soil desalination. This is important for agriculture. It is possible ...
facility used to treat
brackish water
Brackish water, sometimes termed brack water, is water occurring in a natural environment that has more salinity than freshwater, but not as much as seawater. It may result from mixing seawater (salt water) and fresh water together, as in estuary ...
from
agricultural runoff. This may be done either to produce
potable water
Drinking water or potable water is water that is safe for ingestion, either when drunk directly in liquid form or consumed indirectly through food preparation. It is often (but not always) supplied through taps, in which case it is also calle ...
for human or animal consumption, or to reduce the salinity of river water prior to its crossing an international border, usually to comply with the terms of a
treaty
A treaty is a formal, legally binding written agreement between sovereign states and/or international organizations that is governed by international law. A treaty may also be known as an international agreement, protocol, covenant, convention ...
. Desalters are also used to treat
groundwater
Groundwater is the water present beneath Earth's surface in rock and Pore space in soil, soil pore spaces and in the fractures of stratum, rock formations. About 30 percent of all readily available fresh water in the world is groundwater. A unit ...
reservoirs in areas impacted by cattle
feedlot
A feedlot or feed yard is a type of animal feeding operation (AFO) which is used in intensive animal farming, notably beef cattle, but also swine, horses, sheep, turkeys, chickens or ducks, prior to slaughter. Large beef feedlots are called conc ...
s and
dairies
A dairy is a place where milk is stored and where butter, cheese, and other dairy products are made, or a place where those products are sold. It may be a room, a building, or a larger establishment. In the United States, the word may also des ...
.
Desalting crude oil
The salts that are most frequently present in crude oil are calcium, sodium and magnesium chlorides. If these compounds are not removed from the oil several problems arise in the refining process. The high temperatures that occur downstream in the process could cause water
hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution reaction, substitution, elimination reaction, elimination, and solvation reactions in which water ...
, which in turn allows the formation of corrosive
hydrochloric acid
Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ...
. Sand, silts and salt cause deposits and foul heat exchangers or result in plugging. The need to supply heat to vaporize water reduces crude pre-heat capacity. Sodium, arsenic and other metals can poison catalysts. By removing the suspended solids, they are not carried into the burner and eventually flue gas, where they would cause problems with environmental compliance such as flue gas opacity norms.
Crude oil to be desalted is heated to a temperature of 100-150 °C and mixed with 4-10% fresh water, which dilutes the salt. The mixture is then pumped into a settling tank where the salt water separates from the oil and is drawn off. An electrostatic field is applied by electrodes in the settling tank, inducing polarization of the water droplets floating in the larger volume of oil. This results in the water droplets clumping together and settling to the bottom of the tank.
[https://m.tau.ac.il/~tsirel/dump/Static/knowino.org/wiki/Crude_oil_desalter.html Crude oil desalter]
See also
*
Brackish water
Brackish water, sometimes termed brack water, is water occurring in a natural environment that has more salinity than freshwater, but not as much as seawater. It may result from mixing seawater (salt water) and fresh water together, as in estuary ...
*
Water desalination
Desalination is a process that removes mineral components from saline water. More generally, desalination is the removal of salts and minerals from a substance. One example is soil desalination. This is important for agriculture. It is possible ...
References
External links
Desalting in refinery
{{Petroleum refining
Industrial equipment
Chemical equipment
Oil refineries