delay charge

Delay composition, also called delay charge or delay train, is a

pyrotechnic composition A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic reaction, exothermic chemical reac ...

, a sort of pyrotechnic initiator, a mixture of

oxidizer An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ''electron donor''). In ot ...

and

fuel A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work (physics), work. The concept was originally applied solely to those materials capable of releasing chem ...

that burns in a slow, constant rate that should not be significantly dependent on temperature and pressure. Delay compositions are used to introduce a delay into the

firing train Firing may refer to: * Dismissal (employment), sudden loss of employment by termination * Firemaking, the act of starting a fire * Burning; see combustion * Shooting, specifically the discharge of firearms * Execution by firing squad, a method of ...

, e.g. to properly sequence firing of

fireworks Fireworks are Explosive, low explosive Pyrotechnics, pyrotechnic devices used for aesthetic and entertainment purposes. They are most commonly used in fireworks displays (also called a fireworks show or pyrotechnics), combining a large numbe ...

, to delay firing of ejection charges in e.g. model rockets, or to introduce a few seconds of time between triggering a

hand grenade A grenade is a small explosive weapon typically thrown by hand (also called hand grenade), but can also refer to a Shell (projectile), shell (explosive projectile) shot from the muzzle of a rifle (as a rifle grenade) or a grenade launcher. A mod ...

and its

explosion An explosion is a rapid expansion in volume of a given amount of matter associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Explosions may also be generated ...

. Typical delay times range between several milliseconds and several seconds. A popular delay charge is a tube of pressed

black powder Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, charcoal (which is mostly carbon), and potassium nitrate, potassium ni ...

. The mechanical assembly prevents the outright detonation of the charge. While delay compositions are principally similar to other fuel-oxidizer compositions, larger grain sizes and less aggressively reacting chemicals are used. Many of the compositions generate little or no gas during burning. Typical materials used are: * Fuels:

silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...

boron Boron is a chemical element; it has symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the boron group it has three ...

manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...

tungsten Tungsten (also called wolfram) is a chemical element; it has symbol W and atomic number 74. It is a metal found naturally on Earth almost exclusively in compounds with other elements. It was identified as a distinct element in 1781 and first ...

antimony Antimony is a chemical element; it has chemical symbol, symbol Sb () and atomic number 51. A lustrous grey metal or metalloid, it is found in nature mainly as the sulfide mineral stibnite (). Antimony compounds have been known since ancient t ...

antimony trisulfide Antimony trisulfide () is found in nature as the crystalline mineral stibnite and the amorphous red mineral (actually a mineraloid) metastibnite. It is manufactured for use in safety matches, military ammunition, explosives and fireworks. It is ...

zirconium Zirconium is a chemical element; it has Symbol (chemistry), symbol Zr and atomic number 40. First identified in 1789, isolated in impure form in 1824, and manufactured at scale by 1925, pure zirconium is a lustrous transition metal with a greyis ...

–

nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...

alloy,

zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...

magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...

, etc. * Oxidizers:

lead dioxide Lead(IV) oxide, commonly known as lead dioxide, is an inorganic compound with the chemical formula . It is an oxide where lead is in an oxidation state of +4. It is a dark-brown solid which is insoluble in water. It exists in two crystalline forms ...

iron oxide An iron oxide is a chemical compound composed of iron and oxygen. Several iron oxides are recognized. Often they are non-stoichiometric. Ferric oxyhydroxides are a related class of compounds, perhaps the best known of which is rust. Iron ...

s, barium chromate, lead chromate,

tin(IV) oxide Tin(IV) oxide, also known as stannic oxide, is the inorganic compound with the formula SnO2. The mineral form of SnO2 is called cassiterite, and this is the main ore of tin. With many other names, this oxide of tin is an important material in ti ...

bismuth(III) oxide Bismuth(III) oxide is a compound of bismuth, and a common starting point for bismuth chemistry. It is found naturally as the mineral bismite (monoclinic) and sphaerobismoite (tetragonal, much more rare), but it is usually obtained as a by-produc ...

barium sulfate Barium sulfate (or sulphate) is the inorganic compound with the chemical formula Ba SO4. It is a white crystalline solid that is odorless and insoluble in water. It occurs in nature as the mineral barite, which is the main commercial source of ...

(for high-temperature compositions),

potassium perchlorate Potassium perchlorate is the inorganic salt with the chemical formula K Cl O4. Like other perchlorates, this salt is a strong oxidizer when the solid is heated at high temperature, although it usually reacts very slowly in solution with reducin ...

(usually used in small amount together with other oxidizers), etc. * Additives to cool down the flame and slow down the reaction can be employed; inert materials or coolants like

titanium dioxide Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound derived from titanium with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or Colour Index Internationa ...

, ground glass,

chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Ch ...

sodium bicarbonate Sodium bicarbonate ( IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda (or simply “bicarb” especially in the UK) is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cat ...

, etc. are common. The burn rates are dependent on

* nature of fuel - fuels that release more heat burn faster * nature of oxidizer - oxidizers that require less heat to decompose burn faster * the composition ratio - stoichiometric mixtures burn the fastest, also slight excess of metallic fuel also increases burn rate, probably due to heat transfer * particle sizes - smaller particles burn faster, but too small particles may lead to incomplete or interrupted burn due to too narrow heating zone * mechanical assembly and housing - charge diameter and thermal conductivity of housing influence lateral heat losses * ambient temperature - ideally this dependence is very low but extremely low or extremely high temperatures may have influence Examples of some compositions are

*

with addition of inert material, e.g.

lead(II) oxide Lead(II) oxide, also called lead monoxide, is the inorganic compound with the molecular formula Pb O. It occurs in two polymorphs: litharge having a tetragonal crystal structure, and massicot having an orthorhombic crystal structure. Modern ...

with

, burning at 1.5–2 cm/s *

red lead Red is the color at the long wavelength end of the visible spectrum of light, next to orange and opposite violet. It has a dominant wavelength of approximately 625–750 nanometres. It is a primary color in the RGB color model and a secondar ...

with silicon, burning at intermediate rate *

lead(IV) oxide Lead(IV) oxide, commonly known as lead dioxide, is an inorganic compound with the chemical formula . It is an oxide where lead is in an oxidation state of +4. It is a dark-brown solid which is insoluble in water. It exists in two crystalline forms. ...

with silicon, burning at 5–6 cm/s *

potassium permanganate Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, which dissolves in water as K+ and ions to give an intensely pink to purple solution. Potassium permanganate is widely us ...

with

, very slow * Manganese Delay Composition:

with lead chromate and barium chromate (lead chromate is the principal oxidizer, barium chromate acts as burning rate modifier, the more of it the slower the reaction

* Tungsten Delay Composition:

with barium chromate and

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*Zirconium Nickel Alloy Delay Composition:

alloy with barium chromate and

. *

with barium chromatebr>
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References

Pyrotechnic compositions Pyrotechnic initiators {{chem-stub