Dacitic
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Dacite () is a
volcanic rock Volcanic rocks (often shortened to volcanics in scientific contexts) are rocks formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and me ...
formed by rapid solidification of
lava Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a Natural satellite, moon onto its surface. Lava may be erupted at a volcano or through a Fissure vent, fractu ...
that is high in
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
and low in alkali metal oxides. It has a fine-grained (
aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This geo ...
) to
porphyritic Porphyritic is an adjective used in geology to describe igneous rocks with a distinct difference in the size of mineral crystals, with the larger crystals known as phenocrysts. Both extrusive and intrusive rocks can be porphyritic, meaning ...
texture and is intermediate in composition between
andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predomina ...
and
rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture (geology), texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained matri ...
. It is composed predominantly of
plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
and
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
. Dacite is relatively common, occurring in many tectonic settings. It is associated with andesite and rhyolite as part of the subalkaline tholeiitic and calc-alkaline magma series.


Etymology

The word ''dacite'' comes from
Dacia Dacia (, ; ) was the land inhabited by the Dacians, its core in Transylvania, stretching to the Danube in the south, the Black Sea in the east, and the Tisza in the west. The Carpathian Mountains were located in the middle of Dacia. It thus ro ...
, a province of the
Roman Empire The Roman Empire ruled the Mediterranean and much of Europe, Western Asia and North Africa. The Roman people, Romans conquered most of this during the Roman Republic, Republic, and it was ruled by emperors following Octavian's assumption of ...
which lay between the
Danube River The Danube ( ; see also other names) is the second-longest river in Europe, after the Volga in Russia. It flows through Central and Southeastern Europe, from the Black Forest south into the Black Sea. A large and historically important riv ...
and
Carpathian Mountains The Carpathian Mountains or Carpathians () are a range of mountains forming an arc across Central Europe and Southeast Europe. Roughly long, it is the third-longest European mountain range after the Ural Mountains, Urals at and the Scandinav ...
(now modern
Romania Romania is a country located at the crossroads of Central Europe, Central, Eastern Europe, Eastern and Southeast Europe. It borders Ukraine to the north and east, Hungary to the west, Serbia to the southwest, Bulgaria to the south, Moldova to ...
and
Moldova Moldova, officially the Republic of Moldova, is a Landlocked country, landlocked country in Eastern Europe, with an area of and population of 2.42 million. Moldova is bordered by Romania to the west and Ukraine to the north, east, and south. ...
) where the rock was first described. The term ''dacite'' was used for the first time in the scientific literature in the book ''Geologie Siebenbürgens'' (''The Geology of Transylvania'') by Austrian geologists Franz Ritter von Hauer and Guido Stache. Dacite was originally defined as a new rock type to separate calc-alkaline rocks with oligoclase phenocrysts (dacites) from rocks with orthoclase phenocrysts (rhyolites).


Composition

Dacite consists mostly of
plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
feldspar and
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
with
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more al ...
,
hornblende Hornblende is a complex silicate minerals#Inosilicates, inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common ...
, and
pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
(
augite Augite, also known as Augurite, is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid soluti ...
or enstatite). The quartz appears as rounded, corroded
phenocryst image:montblanc granite phenocrysts.JPG, 300px, Granites often have large feldspar, feldspathic phenocrysts. This granite, from the Switzerland, Swiss side of the Mont Blanc massif, has large white phenocrysts of plagioclase (that have trapezoid sh ...
s, or as an element of the ground-mass. The plagioclase in dacite ranges from
oligoclase Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite ( Na Al Si3 O8) and anorthite ( CaAl2Si2O8). The albite:ano ...
to andesine and
labradorite Labradorite (( Ca, Na)( Al, Si)4 O8) is a calcium-enriched feldspar mineral first identified in Labrador, Canada, which can display an iridescent effect ( schiller). Labradorite is an intermediate to calcic member of the plagioclase series. It ...
.
Sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal sys ...
occurs, although in small proportions, in some dacites, and when abundant gives rise to rocks that form transitions to the rhyolites. The relative proportions of
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
s and
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
in dacite, and in many other volcanic rocks, are illustrated in the
QAPF diagram A QAPF diagram is a doubled-triangle plot diagram used to classify igneous rocks based on their mineralogy. The acronym QAPF stands for "quartz, alkali feldspar, plagioclase, feldspathoid (foid)", which are the four mineral groups used for clas ...
. This defines dacite as having a content of 20% to 60% quartz, with plagioclase making up 65% or more of its feldspar content. However, while the
IUGS The International Union of Geological Sciences (IUGS) is an international non-governmental organization devoted to global cooperation in the field of geology. As of 2023, it represents more than 1 million geoscientists around the world. About Fo ...
recommends classifying volcanic rocks on the basis of their mineral composition whenever possible, dacites are often so fine-grained that mineral identification is impractical. The rock must then be classified chemically based on its content of silica and alkali metal oxides ( K2O plus Na2O). The
TAS classification TAS stands for Total Alkali Silica. The TAS classification can be used to assign names to many common types of volcanic rocks based upon the relationships between the combined alkali and silica contents. These chemical parameters are useful because ...
puts dacite in the O3 sector.


Texture

In hand specimen, many of the hornblende and biotite dacites are grey or pale brown and yellow rocks with white feldspars, and black crystals of biotite and hornblende. Other dacites, especially pyroxene-bearing dacites, are darker colored. In thin section, dacites may have an
aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This geo ...
to
porphyritic Porphyritic is an adjective used in geology to describe igneous rocks with a distinct difference in the size of mineral crystals, with the larger crystals known as phenocrysts. Both extrusive and intrusive rocks can be porphyritic, meaning ...
texture. Porphyritic dacites contain blocky highly zoned
plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...
phenocrysts and/or rounded corroded
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
phenocrysts. Subhedral
hornblende Hornblende is a complex silicate minerals#Inosilicates, inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common ...
and elongated
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more al ...
grains are present.
Sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal sys ...
phenocrysts and
augite Augite, also known as Augurite, is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid soluti ...
(or enstatite) are found in some samples. The groundmass of these rocks is often
aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This geo ...
microcrystalline A microcrystalline material is a crystallized substance or rock that contains small crystals visible only through microscopic examination. There is little agreement on the range of crystal sizes that should be regarded as microcrystalline, but ...
, with a web of minute feldspars mixed with interstitial grains of quartz or tridymite; but in many dacites it is largely vitreous, while in others it is felsitic or cryptocrystalline.


Geological context and formation

Dacite usually forms as an intrusive rock such as a dike or sill. Examples of this type of dacite outcrop are found in northwestern
Montana Montana ( ) is a landlocked U.S. state, state in the Mountain states, Mountain West subregion of the Western United States. It is bordered by Idaho to the west, North Dakota to the east, South Dakota to the southeast, Wyoming to the south, an ...
and northeastern
Bulgaria Bulgaria, officially the Republic of Bulgaria, is a country in Southeast Europe. It is situated on the eastern portion of the Balkans directly south of the Danube river and west of the Black Sea. Bulgaria is bordered by Greece and Turkey t ...
. Nevertheless, because of the moderately high silica content, dacitic
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as ''lava'') is found beneath the surface of the Earth, and evidence of magmatism has also ...
is quite viscous and therefore prone to explosive eruption. A notorious example of this is Mount St. Helens in which dacite domes formed from previous eruptions. Pyroclastic flows may also be of dacitic composition as is the case with the Fish Canyon Tuff of La Garita Caldera. Dacitic magma is formed by the subduction of young oceanic crust under a thick
felsic In geology, felsic is a grammatical modifier, modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted ...
continental plate. Oceanic crust is hydrothermally altered causing addition of quartz and sodium. As the young, hot oceanic plate is subducted under continental crust, the subducted slab partially melts and interacts with the
upper mantle The upper mantle of Earth is a very thick layer of rock inside the planet, which begins just beneath the crust (geology), crust (at about under the oceans and about under the continents) and ends at the top of the lower mantle (Earth), lower man ...
through convection and dehydration reactions. The process of subduction creates metamorphism in the subducting slab. When this slab reaches the mantle and initiates the dehydration reactions, minerals such as
talc Talc, or talcum, is a clay mineral composed of hydrated magnesium silicate, with the chemical formula . Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant ...
, serpentine,
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into fragile elastic plates. This characteristic is described as ''perfect basal cleavage''. Mica is co ...
and
amphibole Amphibole ( ) is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
s break down generating a more sodic melt. The magma then continues to migrate upwards causing differentiation and becomes even more sodic and silicic as it rises. Once at the cold surface, the sodium rich magma crystallizes plagioclase, quartz and hornblende. Accessory minerals like pyroxenes provide insight to the history of the magma. The formation of dacite provides a great deal of information about the connection between oceanic crust and continental crust. It provides a model for the generation of felsic, buoyant, perennial rock from a mafic, dense, short-lived one.


Dacite's role in the formation of Archean continental crust

The process by which dacite forms has been used to explain the generation of continental crust during the Archean eon. At that time, the production of dacitic magma was more ubiquitous, due to the availability of young, hot oceanic crust. Today, the colder oceanic crust that subducts under most plates is not able to melt prior to the dehydration reactions, thus inhibiting the process.


Molten dacite magma at Kīlauea

Dacitic magma was encountered in a drillhole during geothermal exploration on
Kīlauea Kīlauea ( , ) is an active shield volcano in the Hawaiian Islands. It is located along the southeastern shore of Hawaii (island), Hawaii Island. The volcano is between 210,000 and 280,000 years old and grew above sea level about 100,000 years ...
in 2005. At a depth of 2488 m, the magma flowed up the wellbore. This produced several kilograms of clear, colorless vitric (glassy, non-crystalline) cuttings at the surface. The dacite magma is a residual melt of the typical
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
magma of Kīlauea.Puna Dacite Magma at Kilauea: Unexpected Drilling Into an Active Magma Posters, 2008 Eos Trans. AGU, 89(53), Fall Meeting
/ref>


Distribution

Dacite is relatively common and occurs in various tectonic and magmatic contexts: * In oceanic volcanic series. Examples:
Iceland Iceland is a Nordic countries, Nordic island country between the Atlantic Ocean, North Atlantic and Arctic Oceans, on the Mid-Atlantic Ridge between North America and Europe. It is culturally and politically linked with Europe and is the regi ...
(Heiðarsporður ridge),
Juan de Fuca Ridge The Juan de Fuca Ridge is a Mid-ocean ridge, mid-ocean spreading center and divergent plate boundary located off the coast of the Pacific Northwest region of North America, named after Juan de Fuca. The ridge separates the Pacific Plate to the we ...
. * In
calc-alkaline The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic ...
and tholeiitic volcanic series of the subduction zones of
island arc Island arcs are long archipelago, chains of active volcanoes with intense earthquake, seismic activity found along convergent boundary, convergent plate tectonics, tectonic plate boundaries. Most island arcs originate on oceanic crust and have re ...
s and active
continental margin A continental margin is the outer edge of continental crust abutting oceanic crust under coastal waters. It is one of the three major zones of the ocean floor, the other two being deep-ocean basins and mid-ocean ridges. The continental marg ...
s. Examples of dacitic magmatism in island arcs are
Japan Japan is an island country in East Asia. Located in the Pacific Ocean off the northeast coast of the Asia, Asian mainland, it is bordered on the west by the Sea of Japan and extends from the Sea of Okhotsk in the north to the East China Sea ...
, the
Philippines The Philippines, officially the Republic of the Philippines, is an Archipelagic state, archipelagic country in Southeast Asia. Located in the western Pacific Ocean, it consists of List of islands of the Philippines, 7,641 islands, with a tot ...
, the Aleutians, the
Antilles The Antilles is an archipelago bordered by the Caribbean Sea to the south and west, the Gulf of Mexico to the northwest, and the Atlantic Ocean to the north and east. The Antillean islands are divided into two smaller groupings: the Greater An ...
, the Sunda Arc ( Mount Batur),
Tonga Tonga, officially the Kingdom of Tonga, is an island country in Polynesia, part of Oceania. The country has 171 islands, of which 45 are inhabited. Its total surface area is about , scattered over in the southern Pacific Ocean. accordin ...
and the
South Sandwich Islands The South Sandwich Islands () are a chain of uninhabited volcanic islands in the South Atlantic Ocean. They are administered as part of the British Overseas Territory of South Georgia and the South Sandwich Islands. The chain lies in the sub-A ...
. Examples of dacitic magmatism in active continental margins are the
Cascade Range The Cascade Range or Cascades is a major mountain range of western North America, extending from southern British Columbia through Washington (state), Washington and Oregon to Northern California. It includes both non-volcanic mountains, such as m ...
,
Guatemala Guatemala, officially the Republic of Guatemala, is a country in Central America. It is bordered to the north and west by Mexico, to the northeast by Belize, to the east by Honduras, and to the southeast by El Salvador. It is hydrologically b ...
and the
Andes The Andes ( ), Andes Mountains or Andean Mountain Range (; ) are the List of longest mountain chains on Earth, longest continental mountain range in the world, forming a continuous highland along the western edge of South America. The range ...
(
Ecuador Ecuador, officially the Republic of Ecuador, is a country in northwestern South America, bordered by Colombia on the north, Peru on the east and south, and the Pacific Ocean on the west. It also includes the Galápagos Province which contain ...
,
Peru Peru, officially the Republic of Peru, is a country in western South America. It is bordered in the north by Ecuador and Colombia, in the east by Brazil, in the southeast by Bolivia, in the south by Chile, and in the south and west by the Pac ...
and
Chile Chile, officially the Republic of Chile, is a country in western South America. It is the southernmost country in the world and the closest to Antarctica, stretching along a narrow strip of land between the Andes, Andes Mountains and the Paci ...
). * In continental volcanic series, often in association with tholeiitic basalts and intermediary rocks * The type locality of dacite is Gizella quarry near Poieni, Cluj in
Romania Romania is a country located at the crossroads of Central Europe, Central, Eastern Europe, Eastern and Southeast Europe. It borders Ukraine to the north and east, Hungary to the west, Serbia to the southwest, Bulgaria to the south, Moldova to ...
. Other occurrences of dacite in Europe are Germany ( Weiselberg), Greece ( Nisyros and
Thera Santorini (, ), officially Thira (, ) or Thera, is a Greek island in the southern Aegean Sea, about southeast from the mainland. It is the largest island of a small, circular archipelago formed by the Santorini caldera. It is the southernmos ...
), Italy (in Bozen quartz porphyry, and
Sardinia Sardinia ( ; ; ) is the Mediterranean islands#By area, second-largest island in the Mediterranean Sea, after Sicily, and one of the Regions of Italy, twenty regions of Italy. It is located west of the Italian Peninsula, north of Tunisia an ...
),
Austria Austria, formally the Republic of Austria, is a landlocked country in Central Europe, lying in the Eastern Alps. It is a federation of nine Federal states of Austria, states, of which the capital Vienna is the List of largest cities in Aust ...
(Styrian Volcano Arc), Scotland (
Argyll Argyll (; archaically Argyle; , ), sometimes called Argyllshire, is a Shires of Scotland, historic county and registration county of western Scotland. The county ceased to be used for local government purposes in 1975 and most of the area ...
),
Slovakia Slovakia, officially the Slovak Republic, is a landlocked country in Central Europe. It is bordered by Poland to the north, Ukraine to the east, Hungary to the south, Austria to the west, and the Czech Republic to the northwest. Slovakia's m ...
, Spain (El Hoyazo near
Almería Almería (, , ) is a city and municipalities in Spain, municipality of Spain, located in Andalusia. It is the capital of the province of Almería, province of the same name. It lies in southeastern Iberian Peninsula, Iberia on the Mediterranean S ...
), France ( Massif de l'Esterel) and
Hungary Hungary is a landlocked country in Central Europe. Spanning much of the Pannonian Basin, Carpathian Basin, it is bordered by Slovakia to the north, Ukraine to the northeast, Romania to the east and southeast, Serbia to the south, Croatia and ...
(Csódi Hill). Sites outside Europe include
Iran Iran, officially the Islamic Republic of Iran (IRI) and also known as Persia, is a country in West Asia. It borders Iraq to the west, Turkey, Azerbaijan, and Armenia to the northwest, the Caspian Sea to the north, Turkmenistan to the nort ...
,
Morocco Morocco, officially the Kingdom of Morocco, is a country in the Maghreb region of North Africa. It has coastlines on the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to Algeria–Morocc ...
,
New Zealand New Zealand () is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and List of islands of New Zealand, over 600 smaller islands. It is the List of isla ...
(volcanic region of Taupo),
Turkey Turkey, officially the Republic of Türkiye, is a country mainly located in Anatolia in West Asia, with a relatively small part called East Thrace in Southeast Europe. It borders the Black Sea to the north; Georgia (country), Georgia, Armen ...
,
United States The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
and
Zambia Zambia, officially the Republic of Zambia, is a landlocked country at the crossroads of Central Africa, Central, Southern Africa, Southern and East Africa. It is typically referred to being in South-Central Africa or Southern Africa. It is bor ...
. Dacite is found extraterrestrially at Nili Patera
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcanic eruption. An eruption that ejects large volumes of magma over a short period of time can cause significant detriment to the str ...
of Syrtis Major Planum on
Mars Mars is the fourth planet from the Sun. It is also known as the "Red Planet", because of its orange-red appearance. Mars is a desert-like rocky planet with a tenuous carbon dioxide () atmosphere. At the average surface level the atmosph ...
.


See also

*
Lassen Volcanic National Park Lassen Volcanic National Park is a List of national parks of the United States, national park of the United States in northeastern California. The dominant feature of the park is Lassen Peak, the largest lava dome, plug dome volcano in the wo ...
*
Potosí Potosí, known as Villa Imperial de Potosí in the colonial period, is the capital city and a municipality of the Potosí Department, Department of Potosí in Bolivia. It is one of the list of highest cities in the world, highest cities in the wo ...
, Bolivia


References

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