DMDEE
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DMDEE is an acronym for dimorpholinodiethyl ether but is almost always referred to as DMDEE (pronounced dumdee) in the
polyurethane Polyurethane (; often abbreviated PUR and PU) is a class of polymers composed of organic chemistry, organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethane term ...
industry. It is an organic chemical, specifically a nitrogen-oxygen
heterocycle A heterocyclic compound or ring structure is a cyclic compound that has atoms of at least two different elements as members of its ring(s). Heterocyclic organic chemistry is the branch of organic chemistry dealing with the synthesis, proper ...
with tertiary amine functionality. It is a catalyst used mainly to produce
polyurethane foam Polyurethane foam is a solid polymeric foam based on polyurethane chemistry. As a specialist synthetic fibre, synthetic material with highly diverse applications, polyurethane foams are primarily used for thermal insulation and as a cushioning mat ...
. It has the CAS number 6425-39-4 and is
TSCA The Toxic Substances Control Act (TSCA) is a United States law, passed by the Congress in 1976 and administered by the United States Environmental Protection Agency (EPA), that regulates chemicals not regulated by other U.S. federal statutes, i ...
and REACH registered and on EINECS with the number 229-194-7. The IUPAC name is 4- -(2-morpholin-4-ylethoxy)ethylorpholine and the chemical formula C12H24N2O3.


Other names

Main section reference. * Morpholine, 4,4'-(oxydi-2,1-ethanediyl)bis- * Bis(2-morpholinoethyl) Ether * 4,4'-(Oxybis(ethane-2,1-diyl))dimorpholine * 2,2-Dimorpholinodiethylether * 2,2'-Dimorpholinodiethyl ether * 4,4'-(Oxydiethylene)bis(morpholine) * 4- -(2-morpholin-4-ylethoxy)ethylorpholine * 2,2'-Dimorpholinyldiethyl ether


Use as a polyurethane catalyst

DMDEE tends to be used in one-component rather than 2-component polyurethane systems. Its use has been investigated in polyurethanes for controlled drug release and also adhesives for medical applications. Its use as a catalyst including the kinetics and thermodynamics have been studied and reported on extensively. It is a popular catalyst along with
DABCO DABCO (1,4-diazabicyclo .2.2ctane), also known as triethylenediamine or TEDA, is a bicyclic organic compound with the formula N2(C2H4)3. This colorless solid is a highly nucleophilic tertiary amine base, which is used as a catalyst and reagent in ...
.


Toxicity

The material has been in use for some time and so the toxicity is generally well understood. However, some sources say toxicity data is limited and work continues to acquire the necessary data and publish to ensure it is in the public domain.


References

{{reflist Tertiary amines Catalysis 4-Morpholinyl compounds Ethers