Cyclosiloxanes are a class of
silicone
In Organosilicon chemistry, organosilicon and polymer chemistry, a silicone or polysiloxane is a polymer composed of repeating units of siloxane (, where R = Organyl group, organic group). They are typically colorless oils or elastomer, rubber ...
material. They are volatile and often used as a
solvent
A solvent (from the Latin language, Latin ''wikt:solvo#Latin, solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a Solution (chemistry), solution. A solvent is usually a liquid but can also be a solid, a gas ...
. The three main commercial varies are
octamethylcyclotetrasiloxane
Octamethylcyclotetrasiloxane, also called D4, is an organosilicon compound and one of a number of cyclic siloxanes (cyclomethicones). It is a colorless viscous liquid with a high boiling point. It has historically been used on a large scale in pe ...
(D4),
decamethylcyclopentasiloxane
Decamethylcyclopentasiloxane, also known as D5 and D5, is an organosilicon compound with the formula . It is a colorless and odorless liquid that is slightly volatile. It is used in various cosmetic products. It also is used as a dry cleaning so ...
(D5) and
dodecamethylcyclohexasiloxane (D6). They evaporate and degrade in air under sunlight.
Octamethylcyclotetrasiloxane (D4)

The octamethylcyclotetrasiloxane silicone liquid has no odor and consists of four repeating units of silicon (Si) and oxygen (O) atoms in a closed loop giving it a circular structure. Each silicon atom has two
methyl groups attached (CH
3).
Decamethylcyclopentasiloxane (D5)

Decamethylcyclopentasiloxane silicone liquid has no odor and consists of five repeating units of silicon (Si) and oxygen (O) atoms in a closed loop giving it a circular structure. Each silicon atom has two methyl groups attached (CH
3). Typically it is used as an ingredient in
antiperspirant
A deodorant is a substance applied to the body to prevent or mask body odor caused by bacterial breakdown of perspiration, for example in the armpits, groin, or feet. A subclass of deodorants, called antiperspirants, prevents sweating itself, t ...
,
skin cream,
sun protection lotion and make-up. With a low surface tension of 18 mN/m this material has good spreading properties.
Dodecamethylcyclohexasiloxane (D6)
The dodecamethylcyclohexasiloxane silicone liquid has no odor and consists of six repeating units of silicon (Si) and oxygen (O) atoms in a closed loop giving it a circular structure. Each silicon atom has two methyl groups attached (CH
3).
CASRN: 540-97-6. D6 is also contained under the CAS No. (69430-24-6 ) which is associated with the names ''cyclopolydimethylsiloxane, cyclopolydimethylsiloxane (DX), cyclosiloxanes di-Me, dimethylcyclopolysiloxane, polydimethyl siloxy cyclics, polydimethylcyclosiloxane, cyclomethicone'' and ''mixed cyclosiloxane''.
Existing Substances Evaluation
Substance Profile for The Challenge. Decamethylcyclopentasiloxane (D5). CAS No. 541-02-6. Environment Canada. 2007
See also
* Polydimethylsiloxane
Polydimethylsiloxane (PDMS), also known as dimethylpolysiloxane or dimethicone, is a silicone polymer with a wide variety of uses, from cosmetics to industrial lubrication and passive daytime radiative cooling.
PDMS is particularly known for its ...
* Cyclomethicone
* Siloxane
In organosilicon chemistry, a siloxane is an organic compound containing a functional group of two silicon atoms bound to an oxygen atom: . The parent siloxanes include the oligomeric and polymeric hydrides with the formulae and . Siloxanes ...
and other organosilicon
Organosilicon chemistry is the study of organometallic compounds containing carbon–silicon bonds, to which they are called organosilicon compounds. Most organosilicon compounds are similar to the ordinary organic compounds, being colourless, f ...
compounds
Literature
* ''Cyclosiloxanes''
pdf-file
, Materials for the December 4-5, 2008 Meeting of the California Environmental Contaminant Biomonitoring Program (CECBP) Scientific Guidance Panel (SGP)
References
{{Reflist
Silicones
Chemistry
Solvents
Materials