Copper(I) oxide or cuprous oxide is the

inorganic compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...

with the formula . It is one of the principal

oxide An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation st ...

s of

copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...

, the other being

copper(II) oxide Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite, or so ...

or cupric oxide (CuO). The compound can appear either yellow or red, depending on the size of the particles. Cuprous oxide is found as the

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...

cuprite Cuprite is an oxide mineral composed of copper(I) oxide Cu2O, and is a minor ore of copper. Its dark crystals with red internal reflections are in the isometric system hexoctahedral class, appearing as cubic, octahedral, or dodecahedral forms, ...

. It is a component of some

antifouling Biofouling or biological fouling is the accumulation of microorganisms, plants, algae, or small animals where it is not wanted on surfaces such as ship and submarine hulls, devices such as water inlets, pipework, grates, ponds, and rivers that ...

paints, and has other applications including some that exploit its property as a

semiconductor A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping level ...

Preparation

Copper(I) oxide may be produced by several methods. Most straightforwardly, it arises via the

oxidation Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...

of copper metal: : Additives such as water and acids affect the rate as well as the further oxidation to copper(II) oxides. It is also produced commercially by reduction of copper(II) solutions with

sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a colorless gas with a pungent smell that is responsible for the odor of burnt matches. It is r ...

. Alternatively, it may be prepared via the reduction of

copper(II) acetate Copper(II) acetate, also referred to as cupric acetate, is the chemical compound with the formula where is acetate (). The hydrated derivative, , which contains one molecule of water for each copper atom, is available commercially. Anhydrous co ...

with

hydrazine Hydrazine is an inorganic compound with the chemical formula . It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour. Hydrazine is highly hazardous unless handled in solution as, for example, hydraz ...

: : Copper(I) chloride solutions react with base to give the same material. In all cases, the color of the cuprous oxide is highly sensitive to the procedural details. degrades to copper(II) oxide in moist air. Cu-pourbaix-diagram

Formation of copper(I) oxide is the basis of the

Fehling's test In organic chemistry, Fehling's solution is a chemical reagent used to differentiate between water-soluble carbohydrate and ketone () functional groups, and as a test for reducing sugars and non-reducing sugars, supplementary to the Tollens' rea ...

and

Benedict's test Benedict's reagent (often called Benedict's qualitative solution or Benedict's solution) is a chemical reagent and complex mixture of sodium carbonate, sodium citrate, and copper(II) sulfate pentahydrate. It is often used in place of Fehli ...

for reducing

sugar Sugar is the generic name for sweet-tasting, soluble carbohydrates, many of which are used in food. Simple sugars, also called monosaccharides, include glucose Glucose is a sugar with the Chemical formula#Molecular formula, molecul ...

s. These sugars reduce an

alkaline In chemistry, an alkali (; from the Arabic word , ) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The ...

solution of a copper(II) salt, giving a bright red

precipitate In an aqueous solution, precipitation is the "sedimentation of a solid material (a precipitate) from a liquid solution". The solid formed is called the precipitate. In case of an inorganic chemical reaction leading to precipitation, the chemic ...

of . It forms on

silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...

-plated copper parts exposed to moisture when the silver layer is porous or damaged. This kind of

corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...

is known as

red plague "Red Plague" () is a Polish poem, written in 1944 by Józef Szczepański, a World War II–era poet, who died during the Warsaw Uprising. "Red Plague" inspired Polish Oscar-winning film director Andrzej Wajda to create the movie ''Kanał''. The p ...

Properties

Like all copper(I) compounds, cuprous oxide is

diamagnetic Diamagnetism is the property of materials that are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagn ...

. It does not readily hydrate to

cuprous hydroxide Copper(I) hydroxide is the inorganic compound with the chemical formula of CuOH. Little evidence exists for its existence. A similar situation applies to the monohydroxides of gold(I) and silver(I). Solid CuOH has been claimed however as an unst ...

. Copper(I) oxide dissolves in concentrated

ammonia Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pu ...

solution to form the colourless

complex Complex commonly refers to: * Complexity, the behaviour of a system whose components interact in multiple ways so possible interactions are difficult to describe ** Complex system, a system composed of many components which may interact with each ...

, which is easily

oxidized Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...

in air to the blue . Cuprous oxide is attacked by acids.

Hydrochloric acid Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ...

gives the

chloride complex In chemistry, a transition metal chloride complex is a coordination complex that consists of a transition metal coordinated to one or more chloride ligand. The class of complexes is extensive. Bonding Halides are X-type ligands in coordination ch ...

Sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...

and

nitric acid Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most com ...

produce

copper(II) sulfate Copper(II) sulfate is an inorganic compound with the chemical formula . It forms hydrates , where ''n'' can range from 1 to 7. The pentahydrate (''n'' = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate, whi ...

and

copper(II) nitrate Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu( NO3)2(H2O)x. The hydrates are hygroscopic blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 ° ...

, respectively.

Structure

In terms of their coordination spheres, copper centres are 2-coordinated and the oxides are

tetrahedral In geometry, a tetrahedron (: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular Face (geometry), faces, six straight Edge (geometry), edges, and four vertex (geometry), vertices. The tet ...

. The structure thus resembles in some sense the main polymorphs of , but cuprous oxide's lattices interpenetrate. crystallizes in a

cubic Cubic may refer to: Science and mathematics * Cube (algebra), "cubic" measurement * Cube, a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex ** Cubic crystal system, a crystal system w ...

structure with a lattice constant ''a''_l = . The copper atoms arrange in a

Bravais lattice In geometry and crystallography, a Bravais lattice, named after , is an infinite array of discrete points generated by a set of discrete translation operations described in three dimensional space by : \mathbf = n_1 \mathbf_1 + n_2 \mathbf_2 ...

fcc sublattice, the oxygen atoms in a bcc sublattice. One sublattice is shifted by a quarter of the body diagonal. The

space group In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that ...

is Pnm, which includes the

point group In geometry, a point group is a group (mathematics), mathematical group of symmetry operations (isometry, isometries in a Euclidean space) that have a Fixed point (mathematics), fixed point in common. The Origin (mathematics), coordinate origin o ...

with full octahedral symmetry.

Applications

The dominant use of cuprous oxide is as a component of

paints. Cuprous oxide is also commonly used as a

pigment A pigment is a powder used to add or alter color or change visual appearance. Pigments are completely or nearly solubility, insoluble and reactivity (chemistry), chemically unreactive in water or another medium; in contrast, dyes are colored sub ...

and a

fungicide Fungicides are pesticides used to kill parasitic fungi or their spores. Fungi can cause serious damage in agriculture, resulting in losses of yield and quality. Fungicides are used both in agriculture and to fight fungal infections in animals, ...

Semiconductor and related uses

Rectifier diodes based on this material have been used industrially as early as 1924, long before

silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...

became the standard. Copper(I) oxide is also responsible for the pink color in a positive

. In the history of

physics, Cu₂O is one of the most studied materials. Many applications have been demonstrated first in this material: *Semiconductor

diode A diode is a two-Terminal (electronics), terminal electronic component that conducts electric current primarily in One-way traffic, one direction (asymmetric electrical conductance, conductance). It has low (ideally zero) Electrical resistance ...

s *Phonoritons ("a coherent superposition of

exciton An exciton is a bound state of an electron and an electron hole which are attracted to each other by the electrostatic Coulomb's law, Coulomb force resulting from their opposite charges. It is an electrically neutral quasiparticle regarded as ...

photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless particles that can ...

, and

phonon A phonon is a collective excitation in a periodic, elastic arrangement of atoms or molecules in condensed matter, specifically in solids and some liquids. In the context of optically trapped objects, the quantized vibration mode can be defined a ...

") The lowest excitons in Cu₂O are extremely long lived; absorption lineshapes have been demonstrated with neV linewidths, which is the narrowest bulk exciton resonance ever observed. The associated quadrupole

polariton In physics, polaritons are bosonic quasiparticles resulting from strong coupling of electromagnetic waves (photon) with an electric or magnetic dipole-carrying excitation (state) of solid or liquid matter (such as a phonon, plasmon, or an exc ...

s have low

group velocity The group velocity of a wave is the velocity with which the overall envelope shape of the wave's amplitudes—known as the ''modulation'' or ''envelope (waves), envelope'' of the wave—propagates through space. For example, if a stone is thro ...

approaching the speed of sound. Thus, light moves almost as slowly as sound in this medium, which results in high polariton densities. Another unusual feature of the

ground state The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state ...

excitons is that all primary scattering mechanisms are known quantitatively. was the first substance where an entirely parameter-free model of

absorption Absorption may refer to: Chemistry and biology *Absorption (biology), digestion **Absorption (small intestine) *Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials *Absorption (skin), a route by which su ...

linewidth A spectral line is a weaker or stronger region in an otherwise uniform and continuous spectrum. It may result from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used ...

broadening by

temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...

could be established, allowing the corresponding

absorption coefficient The linear attenuation coefficient, attenuation coefficient, or narrow-beam attenuation coefficient characterizes how easily a volume of material can be penetrated by a beam of light, sound, particles, or other energy or matter. A coefficient val ...

to be deduced. It can be shown using that the Kramers–Kronig relations do not apply to polaritons. In December 2021,

Toshiba is a Japanese multinational electronics company headquartered in Minato, Tokyo. Its diversified products and services include power, industrial and social infrastructure systems, elevators and escalators, electronic components, semiconductors ...

disclosed a transparent thin-film

solar cell A solar cell, also known as a photovoltaic cell (PV cell), is an electronic device that converts the energy of light directly into electricity by means of the photovoltaic effect.

. The cell achieved an 8.4%

energy conversion efficiency Energy conversion efficiency (''η'') is the ratio between the useful output of an energy conversion machine and the input, in energy terms. The input, as well as the useful output may be chemical, electric power, mechanical work, light (radi ...

, the highest efficiency ever reported for any cell of this type as of 2021. The cells could be used for

high-altitude platform station A high-altitude platform station (HAPS, which can also mean high-altitude pseudo-satellite or high-altitude platform systems), also known as atmospheric satellite, is a long endurance (aeronautics), endurance, high altitude aircraft able to off ...

applications and

electric vehicles An electric vehicle (EV) is a motor vehicle whose propulsion is powered fully or mostly by electricity. EVs encompass a wide range of transportation modes, including road vehicle, road and rail vehicles, electric boats and Submersible, submer ...

Similar compounds

An example of natural copper(I,II) oxide is the mineral

paramelaconite Paramelaconite is a rare, black-colored copper(I,II) oxide mineral with formula CuCuO3 (or Cu4O3). It was discovered in the Copper Queen Mine in Bisbee, Arizona, about 1890. It was described in 1892 and more fully in 1941. Its name is derived fr ...

, or .

References

External links

National Pollutant Inventory: Copper and compounds fact sheet

Copper oxides project page
{{DEFAULTSORT:Copper(I) Oxide Copper(I) compounds Semiconductor materials Solar cells Transition metal oxides