Cummingtonite ( ) is a metamorphic
amphibole
Amphibole ( ) is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
with the
chemical composition
A chemical composition specifies the identity, arrangement, and ratio of the chemical elements making up a compound by way of chemical and atomic bonds.
Chemical formulas can be used to describe the relative amounts of elements present in a com ...
, magnesium iron silicate hydroxide.
Monoclinic cummingtonite is compositionally similar and polymorphic with orthorhombic
anthophyllite, which is a much more common form of
magnesium
Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
-rich amphibole, the latter being
metastable
In chemistry and physics, metastability is an intermediate energetic state within a dynamical system other than the system's state of least energy.
A ball resting in a hollow on a slope is a simple example of metastability. If the ball is onl ...
.
Cummingtonite shares few compositional similarities with
alkali
In chemistry, an alkali (; from the Arabic word , ) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The a ...
amphiboles such as
arfvedsonite
Arfvedsonite () or ''soda hornblende'' (partiellement obsolète) is a sodium amphibole mineral with composition: aNa2] Fe2+)4Fe3+(OH)2, Si8O22]. It crystallizes in the monoclinic prismatic crystal system and typically occurs as greenish black t ...
,
glaucophane-
riebeckite
Riebeckite is a sodium-rich member of the amphibole group of silicate minerals, chemical formula Na2(Fe2+3Fe3+2)Si8O22(OH)2. It forms a solid solution series with magnesioriebeckite. It crystallizes in the monoclinic system, usually as long ...
. There is little solubility between these minerals due to different
crystal habit
In mineralogy, crystal habit is the characteristic external shape of an individual crystal or aggregate of crystals. The habit of a crystal is dependent on its crystallographic form and growth conditions, which generally creates irregularities d ...
and inability of substitution between alkali elements and ferro-magnesian elements within the amphibole structure.
Name and discovery
Cummingtonite was named after the town of
Cummington, Massachusetts, where it was discovered in 1824.
[ Chester Dewey, "A Sketch of the Geology and Mineralogy of the Western Part of Massachusetts, and a Small Part of Adjoining States", in ''American Journal of Science'', first series, vol. 8, part 2, 1824, p. 1-60][ It is also found in ]Sweden
Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...
, South Africa
South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. Its Provinces of South Africa, nine provinces are bounded to the south by of coastline that stretches along the Atlantic O ...
, Scotland
Scotland is a Countries of the United Kingdom, country that is part of the United Kingdom. It contains nearly one-third of the United Kingdom's land area, consisting of the northern part of the island of Great Britain and more than 790 adjac ...
, and New Zealand
New Zealand () is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and List of islands of New Zealand, over 600 smaller islands. It is the List of isla ...
.[
]
Chemistry
Cummingtonite is a member of the cummingtonite- grunerite solid solution
A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solutio ...
series which ranges from for magnesiocummingtonite to the iron rich grunerite endmember . Cummingtonite is used to describe minerals of this formula with between 30 and 70 per cent . Thus, cummingtonite is the series intermediate.
Manganese
Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
also substitutes for ) within cummingtonite amphibole, replacing B site atoms. These minerals are found in high-grade metamorphic banded iron formation
Banded iron formations (BIFs; also called banded ironstone formations) are distinctive units of sedimentary rock consisting of alternating layers of iron oxides and iron-poor chert. They can be up to several hundred meters in thickness and e ...
and form a compositional series between (tirodite) and (dannemorite).
Calcium
Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
, sodium
Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
and potassium
Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...
concentrations in cummingtonite are low. Cummingtonite tends toward more calcium
Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
substitution than related anthophyllite. Similarly, cummingtonite has lower ferric
In chemistry, iron(III) or ''ferric'' refers to the chemical element, element iron in its +3 oxidation number, oxidation state. ''Ferric chloride'' is an alternative name for iron(III) chloride (). The adjective ''ferrous'' is used instead for i ...
iron and aluminium
Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
than anthophyllite.
Amosite is a rare asbestiform variety of grunerite that was mined as asbestos only in the eastern part of the Transvaal Province
The Province of Transvaal (), commonly referred to as the Transvaal (; ), was a province of South Africa from 1910 until 1994, when a new constitution subdivided it following the end of apartheid. The name "Transvaal" refers to the province's ...
of South Africa
South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. Its Provinces of South Africa, nine provinces are bounded to the south by of coastline that stretches along the Atlantic O ...
. The origin of the name is ''Amosa'', the acronym for the mining company "Asbestos Mines of South Africa".
Occurrence
Cummingtonite is commonly found in metamorphosed magnesium-rich rocks and occurs in amphibolites. Usually it coexists with hornblende
Hornblende is a complex silicate minerals#Inosilicates, inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common ...
or actinolite, magnesium clinochlore chlorite
The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
, talc
Talc, or talcum, is a clay mineral composed of hydrated magnesium silicate, with the chemical formula . Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant ...
, serpentine- antigorite minerals or metamorphic pyroxene
The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
. Magnesium-rich cummingtonite can also coexist with anthophyllite.
Cummingtonite has also been found in some felsic
In geology, felsic is a grammatical modifier, modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted ...
volcanic rocks such as dacite
Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite. ...
s. Manganese
Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
rich species can be found in metamorphosed Mn-rich rock units. The grunerite end member is characteristic of the metamorphosed iron formations of the Lake Superior
Lake Superior is the largest freshwater lake in the world by surface areaThe Caspian Sea is the largest lake, but is saline, not freshwater. Lake Michigan–Huron has a larger combined surface area than Superior, but is normally considered tw ...
region and the Labrador Trough. With prograde metamorphism cummingtonite and grunerite morph to members of the olivine
The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...
and pyroxene series.
References
Further reading
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{{refend
Amphibole group
Magnesium minerals
Iron(II) minerals
Asbestos