Copper peroxide is an
inorganic compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemi ...
with the formula CuO
2. It is an
oxide of
copper(II), with the two oxygen atoms as a
peroxide
In chemistry, peroxides are a group of compounds with the structure , where R = any element. The group in a peroxide is called the peroxide group or peroxo group. The nomenclature is somewhat variable.
The most common peroxide is hydrogen ...
unit. It appears as a dark
olive green
Olive is a dark yellowish-green color, like that of unripe or green olives.
As a color word in the English language, it appears in late Middle English. Shaded toward gray, it becomes olive drab.
Variations
Olivine
Olivine is the typical ...
solid or similarly colored suspension and is unstable, decomposing to
dioxygen
There are several known allotropes of oxygen. The most familiar is molecular oxygen (O2), present at significant levels in Earth's atmosphere and also known as dioxygen or triplet oxygen. Another is the highly reactive ozone (O3). Others are: ...
and other
copper oxide Copper oxide is a compound from the two elements copper and oxygen.
Copper oxide may refer to:
* Copper(I) oxide (cuprous oxide, Cu2O)
* Copper(II) oxide
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black so ...
s.
Preparation
Copper peroxide is prepared by the reaction of cold solutions of
Schweizer's reagent
Schweizer's reagent is the metal ammine complex with the formula u(NH3)4(H2O)2OH)2. This deep-blue compound is used in purifying cellulose.
It is prepared by precipitating copper(II) hydroxide from an aqueous solution of copper sulfate using ...
—a source of copper(II)—and
hydrogen peroxide
Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3% ...
, the former prepared from
copper(II) hydroxide
Copper(II) hydroxide is the hydroxide of copper with the chemical formula of Cu(OH)2. It is a pale greenish blue or bluish green solid. Some forms of copper(II) hydroxide are sold as "stabilized" copper(II) hydroxide, although they likely consist ...
and dilute
ammonia solution
Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH3(aq). Although ...
.
The Schweizer's reagent used must not contain excess ammonia.
Copper peroxide may also be produced by the reaction of an ice-cold solution of
hydrogen peroxide
Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3% ...
with a suspension of
copper hydroxide. It may also form from the very slow reaction of finely divided
cupric oxide
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It ...
with cold hydrogen peroxide.
Properties
When wet, copper peroxide decomposes
at temperatures above 6 °C; it "is far more stable when dry."
References
{{Copper compounds
Peroxides
Copper(II) compounds