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Copper alloys are metal alloys that have
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish ...
as their principal component. They have high resistance against
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engi ...
. The best known traditional types are bronze, where tin is a significant addition, and
brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other wit ...
, using
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic t ...
instead. Both of these are imprecise terms, having both been commonly referred to as lattens in the past. Today the term ''copper alloy'' tends to be substituted, especially by museums.British Museum, "Scope Note" for "copper alloy"
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Composition

The similarity in external appearance of the various alloys, along with the different combinations of elements used when making each alloy, can lead to confusion when categorizing the different compositions. There are as many as 400 different
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish ...
and copper alloy compositions loosely grouped into the categories: copper, high copper alloy,
brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other wit ...
es, bronzes, copper nickels, copper–nickel–zinc (nickel silver), leaded copper, and special alloys. The following table lists the principal alloying element for four of the more common types used in modern industry, along with the name for each type. Historical types, such as those that characterize the
Bronze Age The Bronze Age is a historic period, lasting approximately from 3300 BC to 1200 BC, characterized by the use of bronze, the presence of writing in some areas, and other early features of urban civilization. The Bronze Age is the second pri ...
, are vaguer as the mixtures were generally variable. The following table outlines the chemical composition of various grades of copper alloys.


Brasses

A brass is an alloy of copper with zinc. Brasses are usually yellow in colour. The zinc content can vary between few % to about 40%; as long as it is kept under 15%, it does not markedly decrease corrosion resistance of copper. Brasses can be sensitive to selective leaching corrosion under certain conditions, when zinc is leached from the alloy (''dezincification''), leaving behind a spongy copper structure. * Nordic Gold


Bronzes

A bronze is an alloy of copper and other metals, most often tin, but also aluminium and silicon. * Aluminium bronzes are alloys of copper and aluminium. The content of aluminium ranges mostly between 5% and 11%. Iron, nickel, manganese and silicon are sometimes added. They have higher strength and corrosion resistance than other bronzes, especially in marine environment, and have low reactivity to sulphur compounds. Aluminium forms a thin passivation layer on the surface of the metal. *
Bell metal Bell metal or bell bronze is an alloy used for making bells and related instruments, such as cymbals. It is a form of bronze with a higher tin content, usually in approximately a 4:1 ratio of copper to tin (typically, 78% copper, 22% tin by mas ...
* Phosphor bronze * Nickel bronzes, e.g. nickel silver and cupronickel * Speculum metal * UNS C69100


Precious metal alloys

Copper is often alloyed with precious metals like
gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile ...
(Au) and
silver Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, whi ...
(Ag). † amount unspecified


See also

* Copper-clad steel * Copper alloys in aquaculture * Antimicrobial copper-alloy touch surfaces * Lubaloy C41100


References


Bibliography

* {{cite book , first1=Erik , last1=Oberg , first2=Franklin D. , last2=Jones , first3=Holbrook L. , last3=Horton , year=1992 , title=Machinery's Handbook , edition=24 , page=501 , publisher=Industrial Press Inc , location=New York , isbn=0-8311-2492-X


External links


Corrosion tests and standards: application and interpretationCopper Development Association
*Copper Binary Phase Diagrams generation code (batch file - http://www.gotrawama.eu/copperNIMS/ramefabio.txt ) using open thermodynamic databases available at NIMS https://cpddb.nims.go.jp/cpddb/periodic.htm and a commercial software, Computherm Pandat, available for free at https://computherm.com/ ( help for use https://computherm.com/docs/pandat_manual.pdf. Images of the 34 binary phase diagrams are available at http://www.gotrawama.eu/copperNIMS/PNG/ Copper alloys, Sculpture materials