Copper(II) cyanurate (
C3 H Cu N3 O3) is an
organic compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The ...
. It has very few uses, and is more often encountered accidentally, rather than actually synthesised.
It is often found when the copper concentration in an outdoor
swimming pool
A swimming pool, swimming bath, wading pool, paddling pool, or simply pool, is a structure designed to hold water to enable Human swimming, swimming or other leisure activities. Pools can be built into the ground (in-ground pools) or built ...
is too high. It also occurs with heatpumps due to acid in the insulation, and it reacts with
cyanuric acid
Cyanuric acid or 1,3,5-triazine-2,4,6-triol is a chemical compound with the formula (CNOH)3. Like many industrially useful chemicals, this triazine has many synonyms. This white, odorless solid finds use as a precursor or a component of bleaches ...
(which is added as a chlorine stabilizer) to produce copper cyanurate. This
phenomenon
A phenomenon ( : phenomena) is an observable event. The term came into its modern philosophical usage through Immanuel Kant, who contrasted it with the noumenon, which ''cannot'' be directly observed. Kant was heavily influenced by Gottfried W ...
is called 'Purple Cyanurate', as it discolours the surfaces and the
water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
of the pool to a purple shade.
Synthesis
Copper cyanurate can be created by reacting cyanuric acid with copper oxide.
CuO + 2C
3H
3N
3O
3 → C
3HCuN
3O
3 + H
2O.
Joanneumite is a rare natural mineral found in bat guano with formula Cu(C
3N
3O
3H
2)
2(NH
3)
2 which is an ammine.
By heating copper compounds, such as the nitrate or carbonate with molten urea up to 190°C, they are largely converted to the lavender coloured joanneumite compound.
This is dissolved and then recrystallised from a hot strong ammonia solution. If instead a weak (2%) cold ammonia solution is used, the dark purple compound CuC
3N
3O
3H•2NH
3 is formed instead.
[
A green coloured copper cyanurate containing no extra water or ammonia ligands also exists: Cu3(C3N3O3)2.][
]
Applications
Copper cyanurate has no known practical uses. The only place it commonly occurs is as an adverse effect
An adverse effect is an undesired harmful effect resulting from a Pharmaceutical drug, medication or other Surgery#Definitions, intervention, such as surgery. An adverse effect may be termed a "side effect", when judged to be secondary to a main ...
of high levels of copper in swimming pools, and is more commonly seen as a nuisance.
References
{{Reflist
Copper(II) compounds
Triazines