Copper(I) ''t''-butoxide is an
alkoxide of copper(I). It is a white sublimable solid. It is a
reagent in the synthesis of other copper compounds.
The compound was originally obtained by salt metathesis from
lithium tert-butoxide
Lithium ''tert''-butoxide is the metalloorganic compound with the formula LiOC(CH3)3. A white solid, it is used as a strong base in organic synthesis. The compound is often depicted as a salt, and it often behaves as such, but it is not ionized ...
and
copper(I) chloride
Copper(I) chloride, commonly called cuprous chloride, is the lower chloride of copper, with the formula CuCl. The substance is a white solid sparingly soluble in water, but very soluble in concentrated hydrochloric acid. Impure samples appear gre ...
. An octameric form was obtained by alcoholysis of mesitylcopper:
[{{cite journal, title=Copper(I) alkoxides: preparation and structural characterisation of triphenylmethoxocopper(I) and of an octanuclear form of t-butoxocopper(I) , authors=Håkansson, M.; Lopes, C.; Jagner, S., journal=Inorganica Chimica Acta, year=2000, volume=304, issue=2 , pages=178–183, doi=10.1016/S0020-1693(00)00081-5]
:8 CuC
6H
2Me
3 + 8 HOBu-t → 8 HC
6H
2Me
3 +
uOBu-tsub>8
References
Copper(I) compounds
Tert-butyl compounds
Alkoxides