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Cobalt borides are
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
s with the general formula CoxBy. The two main cobalt borides are CoB and Co2B. These are refractory materials.


Applications


Materials science

Cobalt borides are known to be exceptionally resistant to oxidation, a chemical property which makes them useful in the field of materials science. For instance, studies suggest cobalt boride can increase the lifespan of metal parts when used as a coating, imparting surfaces with higher corrosion and wear resistance. These properties have been exploited in the field of
biomedical sciences Biomedical sciences are a set of sciences applying portions of natural science or formal science, or both, to develop knowledge, interventions, or technology that are of use in healthcare or public health. Such disciplines as medical microbio ...
for the design of specialized drug delivery systems.


Renewable energy

Cobalt boride has also been studied as a catalyst for hydrogen storage and
fuel cell A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requ ...
technologies.


Organic synthesis

Cobalt boride is also an effective hydrogenation catalyst used in
organic synthesis Organic synthesis is a special branch of chemical synthesis and is concerned with the intentional construction of organic compounds. Organic molecules are often more complex than inorganic compounds, and their synthesis has developed into one o ...
. In one study, cobalt boride was found to be the most selective transition metal based catalyst available for the production of
primary Primary or primaries may refer to: Arts, entertainment, and media Music Groups and labels * Primary (band), from Australia * Primary (musician), hip hop musician and record producer from South Korea * Primary Music, Israeli record label Works * ...
amines via nitrile reduction, even exceeding other cobalt containing catalysts such as
Raney cobalt Raney is a surname, and may refer to: *Albert Raney, Sr. (contemporary), developer of Mystic Caverns in Arkansas, USA *Catherine Raney (born 1980), American Olympic speed skater *Chad Raney (born 1970), American entrepreneur; founder of Lone Star Mu ...
.


Preparations


Materials coating

Cobalt boride is produced under high temperature such as 1500 Â°C. Coatings of cobalt boride on iron are produced by boriding, which involves first introducing a coating of FeB, Fe2B. On to this iron boride coating is deposited cobalt using a pack cementation process. Cobalt boride
nanoparticles A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 1 ...
in the size range of 18 to 22 nm have also been produced.


Catalyst

When used as a catalyst, cobalt boride is prepared by reducing a cobalt salt, such as
cobalt(II) nitrate Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, pro ...
, with sodium borohydride. Prior to reduction, the
surface area The surface area of a solid object is a measure of the total area that the surface of the object occupies. The mathematical definition of surface area in the presence of curved surfaces is considerably more involved than the definition of arc ...
of the catalyst is maximized by supporting the salt on another material; often this material is
activated carbon Activated carbon, also called activated charcoal, is a form of carbon commonly used to filter contaminants from water and air, among many other uses. It is processed (activated) to have small, low-volume pores that increase the surface area avail ...
.


See also

*
Nickel boride Nickel boride is the common name of materials composed chiefly of the elements nickel and boron that are widely used as catalysts in organic chemistry. Their approximate chemical composition is Ni2.5B, and they are often incorrectly denoted "" in ...
* Urushibara cobalt


References


Further reading

* * {{Borides Borides Cobalt compounds Hydrogenation catalysts