Coalbed Methane
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''Coalbed methane'' (CBM or coal-bed methane), coalbed gas, or coal seam gas (CSG) is a form of
natural gas Natural gas (also fossil gas, methane gas, and gas) is a naturally occurring compound of gaseous hydrocarbons, primarily methane (95%), small amounts of higher alkanes, and traces of carbon dioxide and nitrogen, hydrogen sulfide and helium ...
extracted from
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...
beds. In recent decades it has become an important source of energy in United States, Canada, Australia, and other countries. The term refers to
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes ...
absorbed into the solid matrix of the coal. It is called "sweet gas" because of its lack of
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist ...
. The presence of this gas is well known from its occurrence in underground
coal mining Coal mining is the process of resource extraction, extracting coal from the ground or from a mine. Coal is valued for its Energy value of coal, energy content and since the 1880s has been widely used to Electricity generation, generate electr ...
, where it presents a serious safety risk. Coalbed methane is distinct from a typical
sandstone Sandstone is a Clastic rock#Sedimentary clastic rocks, clastic sedimentary rock composed mainly of grain size, sand-sized (0.0625 to 2 mm) silicate mineral, silicate grains, Cementation (geology), cemented together by another mineral. Sand ...
or other conventional gas reservoir, as the methane is stored within the coal by a process called adsorption. The methane is in a near-liquid state, lining the inside of pores within the coal (called the matrix). The open fractures in the coal (called the cleats) can also contain free gas or can be saturated with water. Unlike much natural gas from conventional reservoirs, coalbed methane contains very little heavier hydrocarbons such as
propane Propane () is a three-carbon chain alkane with the molecular formula . It is a gas at standard temperature and pressure, but becomes liquid when compressed for transportation and storage. A by-product of natural gas processing and petroleum ref ...
or
butane Butane () is an alkane with the formula C4H10. Butane exists as two isomers, ''n''-butane with connectivity and iso-butane with the formula . Both isomers are highly flammable, colorless, easily liquefied gases that quickly vaporize at ro ...
, and no
natural-gas condensate Natural-gas condensate, also called natural gas liquids, is a low-density mixture of hydrocarbon liquids that are present as gaseous components in the raw natural gas produced from many natural natural gas field, gas fields. Some gas species wit ...
. It often contains up to a few percent
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
. Coalbed methane is generally formed due to thermal maturation of kerogen and organic matter, in contrast to coal seams with regular groundwater recharge where methane is typically generated by microbial communities living in situ.


History

Coalbed methane grew out of venting methane from coal seams. Some coal beds have long been known to be "gassy" so, as a safety measure, boreholes were drilled into the seams from the surface, and the methane allowed to vent before mining. Coalbed methane as a natural-gas resource received a major push from the US federal government in the late 1970s. Federal price controls were discouraging natural gas drilling by keeping natural gas prices below market levels; at the same time, the government wanted to encourage more gas production. The US Department of Energy funded research into a number of unconventional gas sources, including coalbed methane. Coalbed methane was exempted from federal price controls, and was also given a federal tax credit. In Australia, commercial extraction of coal seam gas began in 1996 in the Bowen Basin of
Queensland Queensland ( , commonly abbreviated as Qld) is a States and territories of Australia, state in northeastern Australia, and is the second-largest and third-most populous state in Australia. It is bordered by the Northern Territory, South Austr ...
.


Reservoir properties

Gas contained in coal bed methane is mainly methane and trace quantities of
ethane Ethane ( , ) is a naturally occurring Organic compound, organic chemical compound with chemical formula . At standard temperature and pressure, ethane is a colorless, odorless gas. Like many hydrocarbons, ethane is List of purification methods ...
,
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
,
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
, and few other gases. Intrinsic properties of coal as found in nature determine the amount of gas that can be recovered.


Porosity

Coalbed methane reservoirs are considered as a dual-porosity reservoirs. Dual porosity reservoirs are reservoirs in which porosity related to cleats (natural fractures) are responsible for flow behavior and reservoir porosity of the matrix is responsible for the storage of gas. The
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
of a coalbed methane reservoir can vary from 10%-20%; However, the cleat porosity of the reservoir is estimated to be in the range of 0.1%-1%


Adsorption capacity

Adsorption capacity of coal is defined as the volume of gas adsorbed per unit mass of coal usually expressed in SCF (''standard cubic feet'', the volume at standard pressure and temperature conditions) gas/ton of coal. The capacity to adsorb depends on the rank and quality of coal. The range is usually between 100 and 800 SCF/ton for most coal seams found in the US. Most of the gas in coal beds is in the adsorbed form. When the reservoir is put into production, water in the fracture spaces is pumped off on first. This leads to a reduction of pressure enhancing desorption of gas from the matrix.


Fracture permeability

Fracture permeability acts as the major channel for the gas to flow. The higher the permeability, the higher the gas production. For most coal seams found in the US, the permeability lies in the range of 0.1–50 milliDarcys. The permeability of fractured reservoirs changes with the stress applied to them. Coal displays a stress-sensitive permeability and this process plays an important role during stimulation and production operations.S. Saurabh, S. Harpalani, V.K. Singh, Implications of stress re-distribution and rock failure with continued gas depletion in coalbed methane reservoirs, International Journal of Coal Geology, Volume 162, 2016, Pages 183-192, ISSN 0166-5162, https://dx.doi.org/10.1016/j.coal.2016.06.006. Fracture permeability in Coalbed methane reservoir tends to increase with depletion of gas; in contrast to conventional reservoirs. This unique behavior is because of shrinking of coal, when methane is released from its matrix, which results in opening up of fractures and increased permeability. It is also believed that due to shrinkage of coal matrix at lower reservoir pressures, there is a loss of horizontal stress in the reservoir which induces in-situ failure of coal. Such a failure has been attributed to sudden decrease in the fracture permeability of the reservoir


Thickness of formation and initial reservoir pressure

The thickness of the formation may not be directly proportional to the volume of gas produced in some areas. For example, it has been observed in the Cherokee Basin in Southeast Kansas that a well with a single zone of of pay can produce excellent gas rates, whereas an alternative formation with twice the thickness can produce next to nothing. Some coal (and shale) formations may have high gas concentrations regardless of the formation's thickness, probably due to other factors of the area's geology. The pressure difference between the well block and the sand face should be as high as possible as is the case with any producing reservoir in general.


Other properties

Other affecting parameters include coal density, initial gas-phase concentration, critical gas saturation, irreducible water saturation, and relative permeability to water and gas at conditions of Sw = 1.0 and Sg = 1-Sw irreducible respectively.


Extraction

To extract the gas, a steel-encased hole is drilled into the coal seam below ground. As the pressure within the coal seam declines due to natural production or the pumping of water from the coalbed, both gas and ''produced water'' come to the surface through tubing. Then the gas is sent to a compressor station and into natural gas pipelines. The produced water is either reinjected into isolated formations, released into streams, used for irrigation, or sent to evaporation ponds. The water typically contains dissolved solids such as
sodium bicarbonate Sodium bicarbonate ( IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda (or simply “bicarb” especially in the UK) is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cat ...
and
chloride The term chloride refers to a compound or molecule that contains either a chlorine anion (), which is a negatively charged chlorine atom, or a non-charged chlorine atom covalently bonded to the rest of the molecule by a single bond (). The pr ...
but varies depending on the formation geology. Coalbed methane wells often produce at lower gas rates than conventional reservoirs, typically peaking at near per day (about 0.100 m³/s), and can have large initial costs. The production profiles of CBM wells are typically characterized by a " negative decline" in which the gas production rate initially increases as the water is pumped off and gas begins to desorb and flow. A dry CBM well is similar to a standard gas well. The methane desorption process follows a curve (of gas content vs. reservoir pressure) called a Langmuir isotherm. The isotherm can be analytically described by a maximum gas content (at infinite pressure), and the pressure at which half that gas exists within the coal. These parameters (called the Langmuir volume and Langmuir pressure, respectively) are properties of the coal, and vary widely. A coal in
Alabama Alabama ( ) is a U.S. state, state in the Southeastern United States, Southeastern and Deep South, Deep Southern regions of the United States. It borders Tennessee to the north, Georgia (U.S. state), Georgia to the east, Florida and the Gu ...
and a coal in
Colorado Colorado is a U.S. state, state in the Western United States. It is one of the Mountain states, sharing the Four Corners region with Arizona, New Mexico, and Utah. It is also bordered by Wyoming to the north, Nebraska to the northeast, Kansas ...
may have radically different Langmuir parameters, despite otherwise similar coal properties. As production occurs from a coal reservoir, the changes in pressure are believed to cause changes in the porosity and permeability of the coal. This is commonly known as matrix shrinkage/swelling. As the gas is desorbed, the pressure exerted by the gas inside the pores decreases, causing them to shrink in size and restricting gas flow through the coal. As the pores shrink, the overall matrix shrinks as well, which may eventually increase the space the gas can travel through (the cleats), increasing gas flow. The potential of a particular coalbed as a CBM source depends on the following criteria. Cleat density/intensity: cleats are joints confined within coal sheets. They impart permeability to the coal seam. A high cleat density is required for profitable exploitation of CBM. Also important is the maceral composition: maceral is a microscopic, homogeneous, petrographic entity of a corresponding sedimentary rock. A high vitrinite composition is ideal for CBM extraction, while inertinite hampers the same. The rank of coal has also been linked to CBM content: a vitrinite reflectance of 0.8–1.5% has been found to imply higher productivity of the coalbed. The gas composition must be considered, because natural gas appliances are designed for gas with a heating value of about 1,000 BTU ( British thermal units) per cubic foot, or nearly pure methane. If the gas contains more than a few percent non-flammable gases such as
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
or
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
, either these will have to be removed or it will have to be blended with higher-BTU gas to achieve ''pipeline quality''. If the methane composition of the coalbed gas is less than 92%, it may not be commercially marketable. "Beyond conventional methods, research institutions like The Energy and Resources Institute (TERI) in India are investigating microbial techniques to enhance methane recovery from coal beds, with reported successful field trials."


Environmental impacts


Methane

As with all carbon-based fossil fuels, burning coalbed methane releases carbon dioxide (CO2) into the atmosphere. Its effect as greenhouse gas was first analyzed by chemist and physicist
Svante Arrhenius Svante August Arrhenius ( , ; 19 February 1859 – 2 October 1927) was a Swedish scientist. Originally a physicist, but often referred to as a chemist, Arrhenius was one of the founders of the science of physical chemistry. In 1903, he received ...
. CBM production also entails leaks of fugitive methane into the atmosphere. Methane is rated as having 72 times the effect on global warming per unit of mass than CO2. over 20 years, reducing to 25 times over 100 years and 7.5 times over 500 years.
IPCC The Intergovernmental Panel on Climate Change (IPCC) is an intergovernmental body of the United Nations. Its job is to "provide governments at all levels with scientific information that they can use to develop climate policies". The World M ...
Fourth Assessment Report
Table 2.14, Chap. 2, p. 212
/ref> Analysis of life-cycle greenhouse gas emissions of energy sources indicates that generating electricity from CBM, as with conventional natural gas, has less than half the greenhouse gas effect of coal. Globally, coal mining is also a significant source of methane emissions. To identify the volumes, the industry, governments, and NGOs rely on a combination of emissions monitoring and reporting, estimates, and satellite observations. The current methods for estimating emissions at the coal mine level rely on activity data from the operation and the methane gas content of the coal seams. The emissions methodologies for several academic studies, and NGOs like Global Energy Monitor and Climate Trace, are publicly available. Multiple Australian studies have indicated the long term negative environmental effects of coal seam gas extraction, both locally and globally. In the United States, methane escaping from coal during mining amounts to seven percent of total
methane emissions Increasing methane emissions are a major contributor to the rising concentration of greenhouse gases in Earth's atmosphere, and are responsible for up to one-third of near-term global heating. During 2019, about 60% (360 million tons) of methane r ...
. Recovery of coal mine methane in advance of mining is seen as a major opportunity to reduce methane emissions. Companies like CNX Resources have methane abatement programs to reduce greenhouse gas emissions from active and closed mines.


Infrastructure

CBM wells are connected by a network of roads, pipelines, and compressor stations. Over time, wells may be spaced more closely in order to extract the remaining methane.


Produced water

The produced water brought to the surface as a byproduct of gas extraction varies greatly in quality from area to area, but may contain undesirable concentrations of dissolved substances such as salts, naturally present chemicals, heavy metals, and
radionuclide A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...
s. In many producing regions the water is treated, such as through a reverse osmosis plant and used beneficially for irrigation, water for livestock, urban and industrial uses, or dust suppression.


Pilliga Scrub

In 2012 Eastern Star Gas was fined for "discharging polluting water containing high levels of salt into Bohena Creek" in the Pilliga Scrub. There were "16 spills or leaks of contaminated water" including "serious spills of saline water into woodland and a creek." In 2012, a NSW Legislative Council inquiry criticised the use of open holding ponds, recommending that "the NSW Government ban the open storage of produced water."


Powder River Basin

Not all coalbed methane produced water is saline or otherwise undesirable. Water from coalbed methane wells in the Powder River Basin of Wyoming, US, commonly meets federal drinking water standards, and is widely used in the area to water livestock. Its use for irrigation is limited by its relatively high sodium adsorption ratio.


Groundwater

Depending on aquifer connectivity, water withdrawal may depress aquifers over a large area and affect groundwater flows. In Australia, the CBM industry estimates extraction of to of groundwater per year; while the National Water Commission estimates extraction above a year.


Power generation

In 2012, the Aspen Skiing Company built a 3-megawatt methane-to-electricity plant in Somerset, Colorado at Oxbow Carbon's Elk Creek Mine.


Coalbed methane producing areas


Australia

Coal seam gas resources are in the major coal basins in Queensland and New South Wales, with further potential resources in South Australia. Commercial recovery of coal seam gas (CSG) began in Australia in 1996. As of 2014, coal seam gas, from Queensland and New South Wales, made up about ten percent of Australia's gas production. Demonstrated reserves were estimated to be 33 trillion cubic feet (35 905 petajoules) as of January 2014. * Bowen Basin * Surat Basin * Sydney Basin


Canada

In Canada,
British Columbia British Columbia is the westernmost Provinces and territories of Canada, province of Canada. Situated in the Pacific Northwest between the Pacific Ocean and the Rocky Mountains, the province has a diverse geography, with rugged landscapes that ...
is estimated to have approximately of coalbed gas.
Alberta Alberta is a Provinces and territories of Canada, province in Canada. It is a part of Western Canada and is one of the three Canadian Prairies, prairie provinces. Alberta is bordered by British Columbia to its west, Saskatchewan to its east, t ...
, in 2013, was the only province with commercial coalbed methane wells and is estimated to have approximately of economically recoverable coalbed methane, with overall reserves totaling up to . Coalbed methane is considered a non-renewable resource, although the Alberta Research Council, Alberta Geological Survey and others have argued coalbed methane is a
renewable resource A renewable resource (also known as a flow resource) is a natural resource which will replenish to replace the portion depleted by usage and consumption, either through natural reproduction or other recurring processes in a finite amount of t ...
because the bacterial action that formed the methane is ongoing. This is subject to debate since it has also been shown that the dewatering that accompanies CBM production destroys the conditions needed for the bacteria to produce methane and the rate of formation of additional methane is undetermined. This debate is currently causing a right of ownership issue in the
Canadian province Canada has ten provinces and three territories that are sub-national administrative divisions under the jurisdiction of the Constitution of Canada, Canadian Constitution. In the 1867 Canadian Confederation, three provinces of British North Amer ...
of
Alberta Alberta is a Provinces and territories of Canada, province in Canada. It is a part of Western Canada and is one of the three Canadian Prairies, prairie provinces. Alberta is bordered by British Columbia to its west, Saskatchewan to its east, t ...
, as only non-renewable resources can legally be owned by the province.


United Kingdom

Although gas in place in Britain's coal fields has been estimated to be 2,900 billion cubic meters, it may be that as little as one percent might be economically recoverable. Britain's CBM potential is largely untested. Some methane is extracted by coal mine venting operations, and burned to generate electricity. Assessment by private industry of coalbed methane wells independent of mining began in 2008, when 55 onshore exploration licences were issued, covering 7,000 square kilometers of potential coalbed methane areas. IGas Energy became the first in the UK to commercially extract coalbed methane separate from mine venting; as of 2012, the Igas coalbed methane wells at Doe Green, extracting gas for electrical generation, were the only commercial CBM wells in the UK. The use of CBM (in GWh) for electricity generation in the UK is as shown.


United States

United States coalbed methane production in 2017 was 1.76 trillion cubic feet (TCF), 3.6 percent of all US dry gas production that year. The 2017 production was down from the peak of 1.97 TCF in 2008. Most CBM production came from the Rocky Mountain states of Colorado, Wyoming, and New Mexico.


Kazakhstan

Kazakhstan could witness the development of a large coalbed methane (CBM) sector over the coming decades, according to industry professionals. Preliminary research suggests there may be as much as 900 billion m3 of gas in Kazakhstan's main coalfields – 85% of all reserves in Kazakhstan.


India

Great Eastern Energy (GEECL) was the first company with a field development plan approved. With the completion of the drilling of 23 vertical production wells by GEECL, coalbed methane became commercially available in India on 14 July 2007 with CNG priced at ₹30 per kg. Initially 90% of the CBM would be distributed as CNG gas to fuel vehicles. GEECL is responsible for Southeast Asia's first CBM station and is also locating one in the
West Bengal West Bengal (; Bengali language, Bengali: , , abbr. WB) is a States and union territories of India, state in the East India, eastern portion of India. It is situated along the Bay of Bengal, along with a population of over 91 million inhabi ...
city of Asansol. Prashant Modi, President and Chief Operating Officer of GEECL, said, "With the nation requiring higher energy sources to sustain its development pace, we are confident that CBM will play an important role as one of the prime energy sources for the future generations."
Essar Group Essar Group is an Indian Multinational company, multinational Conglomerate (company), conglomerate company, founded by Shashi and Ravi Ruia, Shashi Ruia and Ravi Ruia in 1969. The company, known as Essar Global Fund Limited (EGFL), owns a vari ...
's Essar Oil and Gas Exploration and Production Ltd.'s CBM portfolio includes 5 blocks. Currently, only one of them, Raniganj East, is currently operational. The others include Rajmahal in Jharkhand, Talcher and Ib Valley in Odisha, and Sohagpur in Madhya Pradesh. The 5 blocks possess an estimated 10 trillion cubic feet (CBF) of CBM reserves.


See also

* Firedamp * Underground coal gasification * Western Canada Sedimentary Basin


References


External links


The latest CBM news



U.S. Environmental Protection Agency page on CBM

British Columbia Ministry of Energy, Mines and Petroleum Resources guide to coalbed gas

Kansas Geological Survey guide to Coalbed Methane



Coal seam gas: by the numbers
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