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Coal is a
combustible A combustible material is a material that can burn (i.e., sustain a flame) in air under certain conditions. A material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort a ...
black or brownish-black
sedimentary rock Sedimentary rocks are types of rock (geology), rock formed by the cementation (geology), cementation of sediments—i.e. particles made of minerals (geological detritus) or organic matter (biological detritus)—that have been accumulated or de ...
, formed as
rock strata In geology and related fields, a stratum (: strata) is a layer of rock or sediment characterized by certain lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by visible surfaces known as ...
called
coal seams Coal mining is the process of extracting coal from the ground or from a mine. Coal is valued for its energy content and since the 1880s has been widely used to generate electricity. Steel and cement industries use coal as a fuel for extra ...
. Coal is mostly
carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
with variable amounts of other elements, chiefly
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
,
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
,
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, and
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
. Coal is a type of
fossil fuel A fossil fuel is a flammable carbon compound- or hydrocarbon-containing material formed naturally in the Earth's crust from the buried remains of prehistoric organisms (animals, plants or microplanktons), a process that occurs within geolog ...
, formed when dead
plant matter Organic matter, organic material or natural organic matter is the large source of carbon-based compounds found within natural and engineered, terrestrial, and aquatic environments. It is matter composed of organic compounds that have come fro ...
decays into
peat Peat is an accumulation of partially Decomposition, decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, Moorland, moors, or muskegs. ''Sphagnum'' moss, also called peat moss, is one of the most ...
which is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former
wetland A wetland is a distinct semi-aquatic ecosystem whose groundcovers are flooded or saturated in water, either permanently, for years or decades, or only seasonally. Flooding results in oxygen-poor ( anoxic) processes taking place, especially ...
s called
coal forest Coal forests were the vast swathes of freshwater swamp and riparian forests that covered much of the lands on Earth's tropical regions during the late Carboniferous ( Pennsylvanian) and Permian periods.Cleal, C. J. & Thomas, B. A. (2005). "Pala ...
s that covered much of the Earth's tropical land areas during the late
Carboniferous The Carboniferous ( ) is a Geologic time scale, geologic period and System (stratigraphy), system of the Paleozoic era (geology), era that spans 60 million years, from the end of the Devonian Period Ma (million years ago) to the beginning of the ...
( Pennsylvanian) and
Permian The Permian ( ) is a geologic period and System (stratigraphy), stratigraphic system which spans 47 million years, from the end of the Carboniferous Period million years ago (Mya), to the beginning of the Triassic Period 251.902 Mya. It is the s ...
times. Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the
Industrial Revolution The Industrial Revolution, sometimes divided into the First Industrial Revolution and Second Industrial Revolution, was a transitional period of the global economy toward more widespread, efficient and stable manufacturing processes, succee ...
. With the invention of the
steam engine A steam engine is a heat engine that performs Work (physics), mechanical work using steam as its working fluid. The steam engine uses the force produced by steam pressure to push a piston back and forth inside a Cylinder (locomotive), cyl ...
, coal consumption increased. In 2020, coal supplied about a quarter of the world's
primary energy Primary energy (PE) is the energy found in nature that has not been subjected to any human engineered conversion process. It encompasses energy contained in raw fuels and other forms of energy, including waste, received as input to a system. Pri ...
and over a third of its
electricity Electricity is the set of physical phenomena associated with the presence and motion of matter possessing an electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by Maxwel ...
. Some
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
and
steel Steel is an alloy of iron and carbon that demonstrates improved mechanical properties compared to the pure form of iron. Due to steel's high Young's modulus, elastic modulus, Yield (engineering), yield strength, Fracture, fracture strength a ...
-making and other industrial processes burn coal. The extraction and burning of coal damages the environment, causing premature death and illness, and it is the largest
anthropogenic Anthropogenic ("human" + "generating") is an adjective that may refer to: * Anthropogeny, the study of the origins of humanity Anthropogenic may also refer to things that have been generated by humans, as follows: * Human impact on the enviro ...
source of
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
contributing to
climate change Present-day climate change includes both global warming—the ongoing increase in Global surface temperature, global average temperature—and its wider effects on Earth's climate system. Climate variability and change, Climate change in ...
. Fourteen billion tonnes of carbon dioxide were emitted by burning coal in 2020, which is 40% of total fossil fuel emissions and over 25% of total global
greenhouse gas emissions Greenhouse gas (GHG) emissions from human activities intensify the greenhouse effect. This contributes to climate change. Carbon dioxide (), from burning fossil fuels such as coal, petroleum, oil, and natural gas, is the main cause of climate chan ...
. As part of worldwide
energy transition An energy transition (or energy system transformation) is a major structural change to energy supply and consumption in an energy system. Currently, a transition to sustainable energy is underway to limit climate change. Most of the sustainab ...
, many countries have reduced or eliminated their use of coal power. The United Nations Secretary General asked governments to stop building new
coal plants A coal-fired power station or coal power plant is a thermal power station which burns coal to generate electricity. Worldwide there are about 2,500 coal-fired power stations, on average Nameplate capacity, capable of generating a gigawatts, ...
by 2020. Global coal use was 8.3 billion tonnes in 2022, and is set to remain at record levels in 2023. To meet the
Paris Agreement The Paris Agreement (also called the Paris Accords or Paris Climate Accords) is an international treaty on climate change that was signed in 2016. The treaty covers climate change mitigation, adaptation, and finance. The Paris Agreement was ...
target of keeping
global warming Present-day climate change includes both global warming—the ongoing increase in global average temperature—and its wider effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes ...
below coal use needs to halve from 2020 to 2030, and "phasing down" coal was agreed upon in the
Glasgow Climate Pact The Glasgow Climate Pact is an agreement reached at the 2021 United Nations Climate Change Conference (COP26). The pact is the first climate agreement explicitly planning to reduce unabated coal usage. A pledge to "phase out" coal was changed to ...
. The largest consumer and importer of coal in 2020 was
China China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
, which accounts for almost half the world's annual coal production, followed by
India India, officially the Republic of India, is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area; the List of countries by population (United Nations), most populous country since ...
with about a tenth.
Indonesia Indonesia, officially the Republic of Indonesia, is a country in Southeast Asia and Oceania, between the Indian Ocean, Indian and Pacific Ocean, Pacific oceans. Comprising over List of islands of Indonesia, 17,000 islands, including Sumatra, ...
and
Australia Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...
export the most, followed by
Russia Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...
.


Etymology

The word originally took the form ''col'' in
Old English Old English ( or , or ), or Anglo-Saxon, is the earliest recorded form of the English language, spoken in England and southern and eastern Scotland in the Early Middle Ages. It developed from the languages brought to Great Britain by Anglo-S ...
, from reconstructed
Proto-Germanic Proto-Germanic (abbreviated PGmc; also called Common Germanic) is the linguistic reconstruction, reconstructed proto-language of the Germanic languages, Germanic branch of the Indo-European languages. Proto-Germanic eventually developed from ...
*''kula''(''n''), from
Proto-Indo-European Proto-Indo-European (PIE) is the reconstructed common ancestor of the Indo-European language family. No direct record of Proto-Indo-European exists; its proposed features have been derived by linguistic reconstruction from documented Indo-Euro ...
root *''g''(''e'')''u-lo-'' "live coal". Germanic cognates include the
Old Frisian Old Frisian was a West Germanic language spoken between the late 13th century and the end of 16th century. It is the common ancestor of all the modern Frisian languages except for the North Frisian language#Insular North Frisian, Insular North ...
,
Middle Dutch Middle Dutch is a collective name for a number of closely related West Germanic dialects whose ancestor was Old Dutch. It was spoken and written between 1150 and 1500. Until the advent of Modern Dutch after 1500 or , there was no overarching sta ...
, Dutch ,
Old High German Old High German (OHG; ) is the earliest stage of the German language, conventionally identified as the period from around 500/750 to 1050. Rather than representing a single supra-regional form of German, Old High German encompasses the numerous ...
,
German German(s) may refer to: * Germany, the country of the Germans and German things **Germania (Roman era) * Germans, citizens of Germany, people of German ancestry, or native speakers of the German language ** For citizenship in Germany, see also Ge ...
and
Old Norse Old Norse, also referred to as Old Nordic or Old Scandinavian, was a stage of development of North Germanic languages, North Germanic dialects before their final divergence into separate Nordic languages. Old Norse was spoken by inhabitants ...
. Irish is also a cognate via the Indo-European root.


Formation of coal

The conversion of dead vegetation into coal is called coalification. At various times in the geologic past, the Earth had dense forests in low-lying areas. In these wetlands, the process of coalification began when dead plant matter was protected from
oxidation Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
, usually by mud or acidic water, and was converted into
peat Peat is an accumulation of partially Decomposition, decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, Moorland, moors, or muskegs. ''Sphagnum'' moss, also called peat moss, is one of the most ...
. The resulting
peat bog A bog or bogland is a wetland that accumulates peat as a deposit of dead plant materials often mosses, typically sphagnum moss. It is one of the four main types of wetlands. Other names for bogs include mire, mosses, quagmire, and muske ...
s, which trapped immense amounts of carbon, were eventually deeply buried by sediments. Then, over millions of years, the heat and pressure of deep burial caused the loss of water, methane and carbon dioxide and increased the proportion of carbon. The grade of coal produced depended on the maximum pressure and temperature reached, with
lignite Lignite (derived from Latin ''lignum'' meaning 'wood'), often referred to as brown coal, is a soft, brown, combustible sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35% and is considered the lowest ...
(also called "brown coal") produced under relatively mild conditions, and
sub-bituminous coal Sub-bituminous coal is a lower grade of coal that contains 35–45% carbon. The properties of this type are between those of lignite, the lowest grade of coal, and those of bituminous coal, the second-highest grade of coal. Sub-bituminous coal ...
,
bituminous coal Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the coal seam, ...
, or
anthracite coal Anthracite, also known as hard coal and black coal, is a hard, compact variety of coal that has a submetallic lustre. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the highe ...
(also called "hard coal" or "black coal") produced in turn with increasing temperature and pressure. Of the factors involved in coalification, temperature is much more important than either pressure or time of burial. Subbituminous coal can form at temperatures as low as while anthracite requires a temperature of at least . Although coal is known from most geologic periods, 90% of all coal beds were deposited in the
Carboniferous The Carboniferous ( ) is a Geologic time scale, geologic period and System (stratigraphy), system of the Paleozoic era (geology), era that spans 60 million years, from the end of the Devonian Period Ma (million years ago) to the beginning of the ...
and
Permian The Permian ( ) is a geologic period and System (stratigraphy), stratigraphic system which spans 47 million years, from the end of the Carboniferous Period million years ago (Mya), to the beginning of the Triassic Period 251.902 Mya. It is the s ...
periods. Paradoxically, this was during the
Late Paleozoic icehouse The late Paleozoic icehouse, also known as the Late Paleozoic Ice Age (LPIA) and formerly known as the Karoo ice age, was an ice age that began in the Late Devonian and ended in the Late Permian, occurring from 360 to 255 million years ago (Mya), ...
, a time of global
glaciation A glacial period (alternatively glacial or glaciation) is an interval of time (thousands of years) within an ice age that is marked by colder temperatures and glacier advances. Interglacials, on the other hand, are periods of warmer climate be ...
. However, the drop in global sea level accompanying the glaciation exposed
continental shelves A continental shelf is a portion of a continent that is submerged under an area of relatively shallow water, known as a shelf sea. Much of these shelves were exposed by drops in sea level during glacial periods. The shelf surrounding an island ...
that had previously been submerged, and to these were added wide
river delta A river delta is a landform, archetypically triangular, created by the deposition of the sediments that are carried by the waters of a river, where the river merges with a body of slow-moving water or with a body of stagnant water. The creat ...
s produced by increased
erosion Erosion is the action of surface processes (such as Surface runoff, water flow or wind) that removes soil, Rock (geology), rock, or dissolved material from one location on the Earth's crust#Crust, Earth's crust and then sediment transport, tran ...
due to the drop in
base level In geology and geomorphology a base level is the lower limit for the vertical position of an erosion, erosion process. The modern term was introduced by John Wesley Powell in 1875. The term was subsequently appropriated by William Morris Davis wh ...
. These widespread areas of wetlands provided ideal conditions for coal formation. The rapid formation of coal ended with the coal gap in the
Permian–Triassic extinction event The Permian–Triassic extinction event (also known as the P–T extinction event, the Late Permian extinction event, the Latest Permian extinction event, the End-Permian extinction event, and colloquially as the Great Dying,) was an extinction ...
, where coal is rare. Favorable geography alone does not explain the extensive Carboniferous coal beds. Other factors contributing to rapid coal deposition were high
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
levels, above 30%, that promoted intense
wildfire A wildfire, forest fire, or a bushfire is an unplanned and uncontrolled fire in an area of Combustibility and flammability, combustible vegetation. Depending on the type of vegetation present, a wildfire may be more specifically identified as a ...
s and formation of
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, ca ...
that was all but indigestible by decomposing organisms; high
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
levels that promoted plant growth; and the nature of Carboniferous forests, which included
lycophyte The lycophytes, when broadly circumscribed, are a group of vascular plants that include the clubmosses. They are sometimes placed in a division Lycopodiophyta or Lycophyta or in a subdivision Lycopodiophytina. They are one of the oldest lineag ...
trees whose
determinate growth In biology and botany, indeterminate growth is growth that is not terminated, in contrast to determinate growth that stops once a genetically predetermined structure has completely formed. Thus, a plant that grows and produces flowers and fruit ...
meant that carbon was not tied up in
heartwood Wood is a structural tissue/material found as xylem in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulosic fibers that are strong in tension and embedded in a matrix of lignin t ...
of living trees for long periods. One theory suggested that about 360 million years ago, some plants evolved the ability to produce
lignin Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidit ...
, a complex polymer that made their
cellulose Cellulose is an organic compound with the chemical formula, formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of glycosidic bond, β(1→4) linked glucose, D-glucose units. Cellulose is an important s ...
stems much harder and more woody. The ability to produce lignin led to the evolution of the first
trees In botany, a tree is a perennial plant with an elongated stem, or trunk, usually supporting branches and leaves. In some usages, the definition of a tree may be narrower, e.g., including only woody plants with secondary growth, only p ...
. But bacteria and fungi did not immediately evolve the ability to decompose lignin, so the wood did not fully decay but became buried under sediment, eventually turning into coal. About 300 million years ago, mushrooms and other fungi developed this ability, ending the main coal-formation period of earth's history. Although some authors pointed at some evidence of lignin degradation during the Carboniferous, and suggested that climatic and tectonic factors were a more plausible explanation, reconstruction of ancestral enzymes by phylogenetic analysis corroborated a hypothesis that lignin degrading enzymes appeared in fungi approximately 200 MYa. One likely tectonic factor was the
Central Pangean Mountains The Central Pangean Mountains were an extensive northeast–southwest trending mountain range in the central portion of the supercontinent Pangaea during the Carboniferous, Permian and Triassic periods. They were formed as a result of collision be ...
, an enormous range running along the equator that reached its greatest elevation near this time. Climate modeling suggests that the Central Pangean Mountains contributed to the deposition of vast quantities of coal in the late Carboniferous. The mountains created an area of year-round heavy precipitation, with no dry season typical of a
monsoon A monsoon () is traditionally a seasonal reversing wind accompanied by corresponding changes in precipitation but is now used to describe seasonal changes in Atmosphere of Earth, atmospheric circulation and precipitation associated with annu ...
climate. This is necessary for the preservation of peat in coal swamps. Coal is known from
Precambrian The Precambrian ( ; or pre-Cambrian, sometimes abbreviated pC, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of t ...
strata, which predate land plants. This coal is presumed to have originated from residues of algae. Sometimes coal seams (also known as coal beds) are interbedded with other sediments in a
cyclothem In geology, cyclothems are alternating stratigraphy, stratigraphic sequences of marine and non-marine Sedimentary structures, sediments, sometimes interbedded with coal seams. The cyclothems consist of repeated sequences, each typically several m ...
. Cyclothems are thought to have their origin in
glacial cycle An ice age is a long period of reduction in the temperature of Earth's surface and atmosphere, resulting in the presence or expansion of continental and polar ice sheets and alpine glaciers. Earth's climate alternates between ice ages, and gr ...
s that produced fluctuations in
sea level Mean sea level (MSL, often shortened to sea level) is an mean, average surface level of one or more among Earth's coastal Body of water, bodies of water from which heights such as elevation may be measured. The global MSL is a type of vertical ...
, which alternately exposed and then flooded large areas of continental shelf.


Chemistry of coalification

The woody tissue of plants is composed mainly of cellulose, hemicellulose, and lignin. Modern peat is mostly lignin, with a content of cellulose and hemicellulose ranging from 5% to 40%. Various other organic compounds, such as waxes and nitrogen- and sulfur-containing compounds, are also present. Lignin has a weight composition of about 54% carbon, 6% hydrogen, and 30% oxygen, while cellulose has a weight composition of about 44% carbon, 6% hydrogen, and 49% oxygen. Bituminous coal has a composition of about 84.4% carbon, 5.4% hydrogen, 6.7% oxygen, 1.7% nitrogen, and 1.8% sulfur, on a weight basis. The low oxygen content of coal shows that coalification removed most of the oxygen and much of the hydrogen a process called ''carbonization''. Carbonization proceeds primarily by
dehydration In physiology, dehydration is a lack of total body water that disrupts metabolic processes. It occurs when free water loss exceeds intake, often resulting from excessive sweating, health conditions, or inadequate consumption of water. Mild deh ...
,
decarboxylation Decarboxylation is a chemical reaction that removes a carboxyl group and releases carbon dioxide (CO2). Usually, decarboxylation refers to a reaction of carboxylic acids, removing a carbon atom from a carbon chain. The reverse process, which is ...
, and demethanation. Dehydration removes water molecules from the maturing coal via reactions such as :2 R–OH → R–O–R + H2O
Decarboxylation Decarboxylation is a chemical reaction that removes a carboxyl group and releases carbon dioxide (CO2). Usually, decarboxylation refers to a reaction of carboxylic acids, removing a carbon atom from a carbon chain. The reverse process, which is ...
removes carbon dioxide from the maturing coal: :RCOOH → RH + CO2 while demethanation proceeds by reaction such as :2 R-CH3 → R-CH2-R + CH4 :R-CH2-CH2-CH2-R → R-CH=CH-R + CH4 In these formulas, R represents the remainder of a cellulose or lignin molecule to which the reacting groups are attached. Dehydration and decarboxylation take place early in coalification, while demethanation begins only after the coal has already reached bituminous rank. The effect of decarboxylation is to reduce the percentage of oxygen, while demethanation reduces the percentage of hydrogen. Dehydration does both, and (together with demethanation) reduces the saturation of the carbon backbone (increasing the number of double bonds between carbon). As carbonization proceeds,
aliphatic compound In organic chemistry, hydrocarbons ( compounds composed solely of carbon and hydrogen) are divided into two classes: aromatic compounds and aliphatic compounds (; G. ''aleiphar'', fat, oil). Aliphatic compounds can be saturated (in which all ...
s convert to
aromatic compound Aromatic compounds or arenes are organic compounds "with a chemistry typified by benzene" and "cyclically conjugated." The word "aromatic" originates from the past grouping of molecules based on odor, before their general chemical properties were ...
s. Similarly, aromatic rings fuse into
polyaromatic A Polycyclic aromatic hydrocarbon (PAH) is any member of a class of organic compounds that is composed of multiple fused aromatic rings. Most are produced by the incomplete combustion of organic matter— by engine exhaust fumes, tobacco, incine ...
compounds (linked rings of carbon atoms). The structure increasingly resembles
graphene Graphene () is a carbon allotrope consisting of a Single-layer materials, single layer of atoms arranged in a hexagonal lattice, honeycomb planar nanostructure. The name "graphene" is derived from "graphite" and the suffix -ene, indicating ...
, the structural element of graphite. Chemical changes are accompanied by physical changes, such as decrease in average pore size.


Macerals

Macerals are coalified plant parts that retain the morphology and some properties of the original plant. In many coals, individual macerals can be identified visually. Some macerals include: * vitrinite, derived from woody parts * lipinite, derived from spores and algae * inertite, derived from woody parts that had been burnt in prehistoric times * huminite, a precursor to vitrinite. In coalification huminite is replaced by vitreous (shiny) ''vitrinite''. Maturation of bituminous coal is characterized by ''bitumenization'', in which part of the coal is converted to
bitumen Bitumen ( , ) is an immensely viscosity, viscous constituent of petroleum. Depending on its exact composition, it can be a sticky, black liquid or an apparently solid mass that behaves as a liquid over very large time scales. In American Engl ...
, a hydrocarbon-rich gel. Maturation to anthracite is characterized by ''debitumenization'' (from demethanation) and the increasing tendency of the anthracite to break with a
conchoidal fracture A conchoidal fracture is a break or fracture of a brittle material that does not follow any natural planes of separation. Mindat.org defines ''conchoidal fracture'' as follows: "a fracture with smooth, curved surfaces, typically slightly concave ...
, similar to the way thick glass breaks.


Types

As geological processes apply
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
to dead
biotic material Biotic material or biological derived material is any material that originates from living organisms. Most such materials contain carbon and are capable of decay. The earliest form of life on Earth arose at least 3.5 billion years ago.Schopf, ...
over time, under suitable conditions, its
metamorphic grade Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chem ...
or rank increases successively into: *
Peat Peat is an accumulation of partially Decomposition, decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, Moorland, moors, or muskegs. ''Sphagnum'' moss, also called peat moss, is one of the most ...
, a precursor of coal *
Lignite Lignite (derived from Latin ''lignum'' meaning 'wood'), often referred to as brown coal, is a soft, brown, combustible sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35% and is considered the lowest ...
, or brown coal, the lowest rank of coal, most harmful to health when burned, used almost exclusively as fuel for electric power generation *
Sub-bituminous coal Sub-bituminous coal is a lower grade of coal that contains 35–45% carbon. The properties of this type are between those of lignite, the lowest grade of coal, and those of bituminous coal, the second-highest grade of coal. Sub-bituminous coal ...
, whose properties range between those of lignite and those of bituminous coal, is used primarily as fuel for steam-electric power generation. *
Bituminous coal Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the coal seam, ...
, a dense sedimentary rock, usually black, but sometimes dark brown, often with well-defined bands of bright and dull material. It is used primarily as fuel in steam-electric power generation and to make coke. Known as steam coal in the UK, and historically used to raise steam in steam locomotives and ships *
Anthracite coal Anthracite, also known as hard coal and black coal, is a hard, compact variety of coal that has a submetallic lustre. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the highe ...
, the highest rank of coal, is a harder, glossy black coal used primarily for residential and commercial
space heating A heating system is a mechanism designed to regulate and maintain a desired temperature within a space by utilizing thermal energy. It is a fundamental component of Heating, Ventilation, and Air Conditioning (HVAC) systems, providing warmth to resi ...
. *
Graphite Graphite () is a Crystallinity, crystalline allotrope (form) of the element carbon. It consists of many stacked Layered materials, layers of graphene, typically in excess of hundreds of layers. Graphite occurs naturally and is the most stable ...
, a difficult to ignite coal which is mostly used in pencils, or powdered for
lubrication Lubrication is the process or technique of using a lubricant to reduce friction and wear and tear in a contact between two surfaces. The study of lubrication is a discipline in the field of tribology. Lubrication mechanisms such as fluid-lubr ...
. *
Cannel coal Cannel coal or candle coal is a type of bituminous coal, also classified as terrestrial type oil shale. Hutton(1987) Dyni (2006), pp. 3–4 Speight (2012), pp. 6–7 Due to its physical morphology and low mineral content cannel coal is considered ...
(sometimes called "candle coal"), a variety of fine-grained, high-rank coal with significant hydrogen content, which consists primarily of
liptinite In coal geology, liptinite is the finely-ground and macerated remains found in coal deposits. It replaced the term exinite as one of the four categories of kerogen. Liptinites were originally formed by spores, pollen, dinoflagellate cysts, leaf ...
. It is related to boghead coal. There are several international standards for coal. The classification of coal is generally based on the content of
volatiles Volatility or volatile may refer to: Chemistry * Volatility (chemistry), a measuring tendency of a substance or liquid to vaporize easily ** Volatile organic compounds, organic or carbon compounds that can evaporate at normal temperature and pre ...
. However the most important distinction is between thermal coal (also known as steam coal), which is burnt to generate electricity via steam; and
metallurgical coal Metallurgical coal or coking coal is a grade of coal that can be used to produce good-quality coke. Coke is an essential fuel and reactant in the blast furnace process for primary steelmaking. The demand for metallurgical coal is highly coupled ...
(also known as coking coal), which is burnt at high temperature to make
steel Steel is an alloy of iron and carbon that demonstrates improved mechanical properties compared to the pure form of iron. Due to steel's high Young's modulus, elastic modulus, Yield (engineering), yield strength, Fracture, fracture strength a ...
. Hilt's law is a geological observation that (within a small area) the deeper the coal is found, the higher its rank (or grade). It applies if the thermal gradient is entirely vertical; however,
metamorphism Metamorphism is the transformation of existing Rock (geology), rock (the protolith) to rock with a different mineral composition or Texture (geology), texture. Metamorphism takes place at temperatures in excess of , and often also at elevated ...
may cause lateral changes of rank, irrespective of depth. For example, some of the coal seams of the
Madrid, New Mexico Madrid ( , ) is a census-designated place (CDP) in Santa Fe County, New Mexico, United States. It is part of the Santa Fe, New Mexico Metropolitan Statistical Area. The population was 149 at the 2000 census and 204 in 2010. Today, Madrid has b ...
coal field were partially converted to anthracite by
contact metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of c ...
from an igneous sill while the remainder of the seams remained as bituminous coal.


History

The earliest recognized use is from the
Shenyang Shenyang,; ; Mandarin pronunciation: ; formerly known as Fengtian formerly known by its Manchu language, Manchu name Mukden, is a sub-provincial city in China and the list of capitals in China#Province capitals, provincial capital of Liaonin ...
area of China where by 4000 BC
Neolithic The Neolithic or New Stone Age (from Ancient Greek, Greek 'new' and 'stone') is an archaeological period, the final division of the Stone Age in Mesopotamia, Asia, Europe and Africa (c. 10,000 BCE to c. 2,000 BCE). It saw the Neolithic Revo ...
inhabitants had begun carving ornaments from black lignite. Coal from the
Fushun Fushun ( zh, s=, t=, p=Fǔshùn, historically Fuxi ()) is a prefecture level city in Liaoning province, China, about east of Shenyang, with a total area of , of which is the city proper. Situated on the Hun River ("muddy river"), it is one o ...
mine in northeastern China was used to smelt
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
as early as 1000 BC.
Marco Polo Marco Polo (; ; ; 8 January 1324) was a Republic of Venice, Venetian merchant, explorer and writer who travelled through Asia along the Silk Road between 1271 and 1295. His travels are recorded in ''The Travels of Marco Polo'' (also known a ...
, the Italian who traveled to China in the 13th century, described coal as "black stones ... which burn like logs", and said coal was so plentiful, people could take three hot baths a week. In Europe, the earliest reference to the use of coal as fuel is from the geological treatise ''On Stones'' (Lap. 16) by the Greek scientist
Theophrastus Theophrastus (; ; c. 371 – c. 287 BC) was an ancient Greek Philosophy, philosopher and Natural history, naturalist. A native of Eresos in Lesbos, he was Aristotle's close colleague and successor as head of the Lyceum (classical), Lyceum, the ...
(c. 371–287 BC):
Outcrop An outcrop or rocky outcrop is a visible exposure of bedrock or ancient superficial deposits on the surface of the Earth and other terrestrial planets. Features Outcrops do not cover the majority of the Earth's land surface because in most p ...
coal was used in Britain during the
Bronze Age The Bronze Age () was a historical period characterised principally by the use of bronze tools and the development of complex urban societies, as well as the adoption of writing in some areas. The Bronze Age is the middle principal period of ...
(3000–2000 BC), where it formed part of
funeral A funeral is a ceremony connected with the final disposition of a corpse, such as a burial or cremation, with the attendant observances. Funerary customs comprise the complex of beliefs and practices used by a culture to remember and respect th ...
pyre A pyre (; ), also known as a funeral pyre, is a structure, usually made of wood, for burning a body as part of a funeral rite or execution. As a form of cremation, a body is placed upon or under the pyre, which is then set on fire. In discussi ...
s.Britannica 2004: ''Coal mining: ancient use of outcropping coal'' In
Roman Britain Roman Britain was the territory that became the Roman province of ''Britannia'' after the Roman conquest of Britain, consisting of a large part of the island of Great Britain. The occupation lasted from AD 43 to AD 410. Julius Caes ...
, with the exception of two modern fields, "the Romans were exploiting coals in all the major coalfields in
England England is a Countries of the United Kingdom, country that is part of the United Kingdom. It is located on the island of Great Britain, of which it covers about 62%, and List of islands of England, more than 100 smaller adjacent islands. It ...
and
Wales Wales ( ) is a Countries of the United Kingdom, country that is part of the United Kingdom. It is bordered by the Irish Sea to the north and west, England to the England–Wales border, east, the Bristol Channel to the south, and the Celtic ...
by the end of the second century AD". Evidence of trade in coal, dated to about AD 200, has been found at the Roman settlement at Heronbridge, near
Chester Chester is a cathedral city in Cheshire, England, on the River Dee, Wales, River Dee, close to the England–Wales border. With a built-up area population of 92,760 in 2021, it is the most populous settlement in the borough of Cheshire West an ...
; and in the Fenlands of
East Anglia East Anglia is an area of the East of England, often defined as including the counties of Norfolk, Suffolk and Cambridgeshire, with parts of Essex sometimes also included. The name derives from the Anglo-Saxon kingdom of the East Angles, ...
, where coal from the
Midlands The Midlands is the central region of England, to the south of Northern England, to the north of southern England, to the east of Wales, and to the west of the North Sea. The Midlands comprises the ceremonial counties of Derbyshire, Herefor ...
was transported via the
Car Dyke The Car Dyke was, and to a large extent still is, a long ditch which runs along the western edge of the Fens in eastern England for a distance of over . It is generally accepted as being a Roman invasion of Britain, Roman construction and was, f ...
for use in drying grain. Coal cinders have been found in the hearths of villas and Roman forts, particularly in
Northumberland Northumberland ( ) is a ceremonial counties of England, ceremonial county in North East England, on the Anglo-Scottish border, border with Scotland. It is bordered by the North Sea to the east, Tyne and Wear and County Durham to the south, Cumb ...
, dated to around AD 400. In the west of England, contemporary writers described the wonder of a permanent brazier of coal on the altar of
Minerva Minerva (; ; ) is the Roman goddess of wisdom, justice, law, victory, and the sponsor of arts, trade, and strategy. She is also a goddess of warfare, though with a focus on strategic warfare, rather than the violence of gods such as Mars. Be ...
at
Aquae Sulis Aquae Sulis (Latin for ''Waters of Sulis'') was a small town in the Roman province of Roman Britain, Britannia. Today it is the England, English city of Bath, Somerset. The Antonine Itinerary register of Roman roads lists the town as ''Aquis Su ...
(modern day
Bath Bath may refer to: * Bathing, immersion in a fluid ** Bathtub, a large open container for water, in which a person may wash their body ** Public bathing, a public place where people bathe * Thermae, ancient Roman public bathing facilities Plac ...
), although in fact easily accessible surface coal from what became the
Somerset coalfield The Somerset Coalfield in northern Somerset, England is an area where coal was mined from the 15th century until 1973. It is part of a larger coalfield which stretched into southern Gloucestershire. The Somerset coalfield stretched from Cromh ...
was in common use in quite lowly dwellings locally. Evidence of coal's use for
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
-working in the city during the Roman period has been found. In
Eschweiler Eschweiler (, Ripuarian language, Ripuarian: ) is a municipality in the district of Aachen (district), Aachen in North Rhine-Westphalia in Germany on the river Inde, near the German-Dutch-Belgian border, and about east of Aachen and w ...
,
Rhineland The Rhineland ( ; ; ; ) is a loosely defined area of Western Germany along the Rhine, chiefly Middle Rhine, its middle section. It is the main industrial heartland of Germany because of its many factories, and it has historic ties to the Holy ...
, deposits of
bituminous coal Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the coal seam, ...
were used by the Romans for the smelting of
iron ore Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the f ...
. No evidence exists of coal being of great importance in Britain before about AD 1000, the
High Middle Ages The High Middle Ages, or High Medieval Period, was the periodization, period of European history between and ; it was preceded by the Early Middle Ages and followed by the Late Middle Ages, which ended according to historiographical convention ...
. Coal came to be referred to as "seacoal" in the 13th century; the wharf where the material arrived in London was known as Seacoal Lane, so identified in a charter of King Henry III granted in 1253. Initially, the name was given because much coal was found on the shore, having fallen from the exposed coal seams on cliffs above or washed out of underwater coal outcrops, but by the time of
Henry VIII Henry VIII (28 June 149128 January 1547) was King of England from 22 April 1509 until his death in 1547. Henry is known for his Wives of Henry VIII, six marriages and his efforts to have his first marriage (to Catherine of Aragon) annulled. ...
, it was understood to derive from the way it was carried to London by sea. In 1257–1259, coal from
Newcastle upon Tyne Newcastle upon Tyne, or simply Newcastle ( , Received Pronunciation, RP: ), is a City status in the United Kingdom, cathedral city and metropolitan borough in Tyne and Wear, England. It is England's northernmost metropolitan borough, located o ...
was shipped to London for the smiths and lime-burners building
Westminster Abbey Westminster Abbey, formally titled the Collegiate Church of Saint Peter at Westminster, is an Anglican church in the City of Westminster, London, England. Since 1066, it has been the location of the coronations of 40 English and British m ...
. Seacoal Lane and Newcastle Lane, where coal was unloaded at wharves along the
River Fleet The River Fleet is the largest of Subterranean rivers of London, London's subterranean rivers, all of which today contain foul water for treatment. It has been used as a culverted sewer since the development of Joseph Bazalgette's London sewe ...
, still exist. These easily accessible sources had largely become exhausted (or could not meet the growing demand) by the 13th century, when underground extraction by
shaft mining Shaft mining or shaft sinking is the action of excavating a mine shaft from the top down, where there is initially no access to the bottom. Shaft (civil engineering), Shallow shafts, typically sunk for civil engineering projects, differ greatly ...
or
adit An adit (from Latin ''aditus'', entrance) or stulm is a horizontal or nearly horizontal passage to an underground mine. Miners can use adits for access, drainage, ventilation, and extracting minerals at the lowest convenient level. Adits are a ...
s was developed. The alternative name was "pitcoal", because it came from mines. Cooking and home heating with coal (in addition to firewood or instead of it) has been done in various times and places throughout human history, especially in times and places where ground-surface coal was available and firewood was scarce, but a widespread reliance on coal for home hearths probably never existed until such a switch in fuels happened in London in the late sixteenth and early seventeenth centuries. Historian Ruth Goodman has traced the socioeconomic effects of that switch and its later spread throughout Britain and suggested that its importance in shaping the industrial adoption of coal has been previously underappreciated. The development of the
Industrial Revolution The Industrial Revolution, sometimes divided into the First Industrial Revolution and Second Industrial Revolution, was a transitional period of the global economy toward more widespread, efficient and stable manufacturing processes, succee ...
led to the large-scale use of coal, as the
steam engine A steam engine is a heat engine that performs Work (physics), mechanical work using steam as its working fluid. The steam engine uses the force produced by steam pressure to push a piston back and forth inside a Cylinder (locomotive), cyl ...
took over from the
water wheel A water wheel is a machine for converting the kinetic energy of flowing or falling water into useful forms of power, often in a watermill. A water wheel consists of a large wheel (usually constructed from wood or metal), with numerous b ...
. In 1700, five-sixths of the world's coal was mined in Britain. Britain would have run out of suitable sites for watermills by the 1830s if coal had not been available as a source of energy. In 1947 there were some 750,000 miners in Britain, but the last deep coal mine in the UK closed in 2015. A grade between bituminous coal and anthracite was once known as "steam coal" as it was widely used as a fuel for steam locomotives. In this specialized use, it is sometimes known as "sea coal" in the United States. Small "steam coal", also called ''dry small steam nuts'' (DSSN), was used as a fuel for domestic water heating. Coal played an important role in industry in the 19th and 20th century. The predecessor of the European Union, the European Coal and Steel Community, was based on the trading of this commodity. Coal continues to arrive on beaches around the world from both natural erosion of exposed coal seams and windswept spills from cargo ships. Many homes in such areas gather this coal as a significant, and sometimes primary, source of home heating fuel.


Composition

Coal is a mixture of diverse organic compounds and polymers. Several kinds exist, with variable dark colors and composition. Young coals (brown coal, lignite) are not completely black. The two main black coals are bituminous, which is more abundant, and anthracite. The type of coal with the highest percentage of carbon in its chemical composition is anthracite, followed by bituminous, then lignite, and finally brown coal. The fuel value of coal varies in the same order. Some anthracite deposits contain pure carbon in the form of graphite. For bituminous coal, the elemental composition on a dry, ash-free basis of 84.4% carbon, 5.4% hydrogen, 6.7% oxygen, 1.7% nitrogen, and 1.8% sulfur, on a weight basis. This composition reflects partly the composition of the precursor plants. The second main fraction of coal is ash, an undesirable, noncombustable mixture of inorganic minerals. The composition of ash is often discussed in terms of oxides obtained after combustion in air: Of particular interest is the sulfur content of coal, which can vary from less than 1% to as much as 4%. Most of the sulfur and most of the nitrogen is incorporated into the organic fraction in the form of organosulfur compounds and heterocycle, organonitrogen compounds. This sulfur and nitrogen are covalent bond, strongly bound within the hydrocarbon matrix. These elements are released as SO2 and NOx upon combustion. They cannot be removed, economically at least, otherwise. Some coals contain inorganic sulfur, mainly in the form of iron pyrite (FeS2). Being a dense mineral, it can be removed from coal by mechanical means, e.g. by froth flotation. Some sulfate occurs in coal, especially weathered samples. It is not volatilized and can be removed by washing. Minor components include: As minerals, Hg, As, and Se are not problematic to the environment, especially since they are only trace components. They become however mobile (volatile or water-soluble) when these minerals are combusted.


Uses

Most coal is used as fuel. 27.6% of world energy was supplied by coal in 2017 and Asia used almost three-quarters of it. Other large-scale applications also exist. The energy density of coal is roughly 24 megajoules per kilogram (approximately 6.7 kilowatt-hours per kg). For a coal power plant with a 40% efficiency, it takes an estimated of coal to power a 100 W lightbulb for one year.


Electricity generation

In 2022, 68% of global coal use was used for electricity generation. Coal burnt in list of coal power stations, coal power stations to electricity generation, generate electricity is called thermal coal. It is usually pulverized and then burned in a furnace with a boiler.Total World Electricity Generation by Fuel (2006)
. Source: IEA 2008.
The furnace heat converts boiler water to steam, which is then used to spin turbines which turn electrical generator, generators and create electricity. The thermodynamic efficiency of this process varies between about 25% and 50% depending on the pre-combustion treatment, turbine technology (e.g. supercritical steam generator) and the age of the plant. A few integrated gasification combined cycle (IGCC) power plants have been built, which burn coal more efficiently. Instead of pulverizing the coal and burning it directly as fuel in the steam-generating boiler, the coal gasification, coal is gasified to create syngas, which is burned in a gas turbine to produce electricity (just like natural gas is burned in a turbine). Hot exhaust gases from the turbine are used to raise steam in a heat recovery steam generator which powers a supplemental steam turbine. The overall plant efficiency when used to provide combined heat and power can reach as much as 94%. IGCC power plants emit less local pollution than conventional pulverized coal-fueled plants. Other ways to use coal are as coal-water slurry fuel (CWS), which was developed in the Soviet Union, or in magnetohydrodynamic generator, an MHD topping cycle. However these are not widely used due to lack of profit. In 2017 38% of the world's electricity came from coal, the same percentage as 30 years previously. In 2018 global installed capacity was 2terawatt, TW (of which 1TW is in China) which was 30% of total electricity generation capacity. The most dependent major country is South Africa, with over 80% of its electricity generated by coal; but China alone generates more than half of the world's coal-generated electricity. Efforts around the world to reduce the use of coal have led some regions to switch to natural gas and renewable energy. In 2018 coal-fired power station capacity factor averaged 51%, that is they operated for about half their available operating hours.


Coke

Coke is a solid carbonaceous residue that is used in manufacturing steel and other iron-containing products. Coke is made when
metallurgical coal Metallurgical coal or coking coal is a grade of coal that can be used to produce good-quality coke. Coke is an essential fuel and reactant in the blast furnace process for primary steelmaking. The demand for metallurgical coal is highly coupled ...
(also known as ''coking coal'') is baked in an oven without oxygen at temperatures as high as 1,000 °C, driving off the volatile constituents and fusing together the fixed carbon and residual ash. Metallurgical coke is used as a fuel and as a reducing agent in smelting iron ore in a blast furnace. The carbon monoxide produced by its combustion reduces hematite (an iron oxide) to iron. : Pig iron, which is too rich in dissolved carbon, is also produced. The coke must be Coke strength after reaction, strong enough to resist the weight of overburden in the blast furnace, which is why coking coal is so important in making steel using the conventional route. Coke from coal is grey, hard, and porous and has a heating value of 29.6 MJ/kg. Some coke-making processes produce byproducts, including coal tar, ammonia, light oils, and coal gas. Petroleum coke (petcoke) is the solid residue obtained in oil refining, which resembles coke but contains too many impurities to be useful in metallurgical applications.


Production of chemicals

Chemicals have been produced from coal since the 1950s. Coal can be used as a feedstock in the production of a wide range of chemical fertilizers and other chemical products. The main route to these products was coal gasification to produce syngas. Primary chemicals that are produced directly from the syngas include methanol,
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
, and carbon monoxide, which are the chemical building blocks from which a whole spectrum of derivative chemicals are manufactured, including olefins, acetic acid, formaldehyde, ammonia, urea, and others. The versatility of syngas as a precursor to primary chemicals and high-value derivative products provides the option of using coal to produce a wide range of commodities. In the 21st century, however, the use of coalbed methane is becoming more important. Because the slate of chemical products that can be made via coal gasification can in general also use feedstocks derived from natural gas and petroleum, the chemical industry tends to use whatever feedstocks are most cost-effective. Therefore, interest in using coal tended to increase for higher oil and natural gas prices and during periods of high global economic growth that might have strained oil and gas production. Coal to chemical processes require substantial quantities of water. Much coal to chemical production is in China where coal dependent provinces such as Shanxi are struggling to control its pollution.


Liquefaction

Coal can be converted directly into synthetic fuels equivalent to gasoline or diesel by hydrogenation or carbonization. Coal liquefaction emits more carbon dioxide than liquid fuel production from crude oil. Mixing in biomass and using carbon capture and storage (CCS) would emit slightly less than the oil process but at a high cost. State owned China Energy Investment runs a coal liquefaction plant and plans to build 2 more. Coal liquefaction may also refer to the cargo hazard when shipping coal.


Gasification

Coal gasification, as part of an integrated gasification combined cycle (IGCC) coal-fired power station, is used to produce syngas, a mixture of carbon monoxide (CO) and hydrogen (H2) gas to fire gas turbines to produce electricity. Syngas can also be converted into transportation fuels, such as gasoline and Diesel fuel, diesel, through the Fischer–Tropsch process; alternatively, syngas can be converted into methanol, which can be blended into fuel directly or converted to gasoline via the methanol to gasoline process. Gasification combined with Fischer–Tropsch technology was used by the Sasol chemical company of South Africa to make chemicals and motor vehicle fuels from coal. During gasification, the coal is mixed with
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
and steam while also being heated and pressurized. During the reaction, oxygen and water molecules oxidize the coal into carbon monoxide (CO), while also releasing
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
gas (H2). This used to be done in underground coal mines, and also to make town gas, which was piped to customers to burn for illumination, heating, and cooking. : 3C (''as Coal'') + O2 + H2O → H2 + 3CO If the refiner wants to produce gasoline, the syngas is routed into a Fischer–Tropsch reaction. This is known as indirect coal liquefaction. If hydrogen is the desired end-product, however, the syngas is fed into the water gas shift reaction, where more hydrogen is liberated: : CO + H2O → CO2 + H2


Coal industry


Mining

About 8,000 Mt of coal are produced annually, about 90% of which is hard coal and 10% lignite. just over half is from underground mines. The coal mining industry employs almost 2.7 million workers. More accidents occur during underground mining than surface mining. Not all countries publish mining accident statistics so worldwide figures are uncertain, but it is thought that most deaths occur in List of coal mining accidents in China, coal mining accidents in China: in 2017 there were 375 coal mining related deaths in China. Most coal mined is thermal coal (also called steam coal as it is used to make steam to generate electricity) but metallurgical coal (also called "metcoal" or "coking coal" as it is used to make coke to make iron) accounts for 10% to 15% of global coal use.


As a traded commodity

Coal in China, China mines almost half the world's coal, followed by
India India, officially the Republic of India, is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area; the List of countries by population (United Nations), most populous country since ...
with about a tenth. At 471 Mt and a 34% share of global exports, Indonesia was the largest exporter by volume in 2022, followed by Australia with 344 Mt and Russia with 224 Mt.Text was copied from this source, which is available under a creativecommons:by/4.0/, Creative Commons Attribution 4.0 International License Other major exporters of coal are the United States, South Africa, Colombia, and Canada. In 2022, China, India, and Japan were the biggest importers of coal, importing 301, 228, and 184 Mt respectively. Russia is increasingly orienting its coal exports from Europe to Asia as Europe transitions to renewable energy and subjects Russia to sanctions over its invasion of Ukraine. The price of metallurgical coal is volatile and much higher than the price of thermal coal because metallurgical coal must be lower in sulfur and requires more cleaning. Coal futures contracts provide coal producers and the electric power industry an important tool for Hedge (finance), hedging and risk management. In some countries, new onshore wind power, wind or solar power, solar generation already costs less than coal power from existing plants. However, for China this is forecast for the early 2020s and for southeast Asia not until the late 2020s. In India, building new plants is uneconomic and, despite being subsidized, existing plants are losing market share to renewables. In many countries in the Global North, there is a move away from the use of coal and former mine sites are being used as a tourist attraction.


Market trends

In 2022, China used 4520 Mt of coal, comprising more than half of global coal consumption. India, the European Union, and the United States, were the next largest consumers of coal, using 1162, 461, and 455 Mt respectively. Over the past decade, China has almost always accounted for the lion's share of the global growth in coal demand. Therefore, international market trends depend on Energy policy of China, Chinese energy policy. Although the government effort to reduce air pollution in China means that the global long-term trend is to burn less coal, the short and medium term trends may differ, in part due to Chinese financing of new coal-fired power plants in other countries. Preliminary analysis by International Energy Agency (IEA) indicates that global coal exports reached an all-time high in 2023. Through to 2026, the IEA expects global coal trade to decline by about 12%, driven by growing domestic production in coal-intensive economies such as China and India and coal phase-out plans elsewhere, such as in Europe. While thermal coal exports are expected to decline by about 16% by 2026, exports of metallurgical coal are expected to slightly increase by almost 2%.


Damage to human health

The use of coal as fuel causes health problems and deaths. The mining and processing of coal causes air and water pollution. Coal-powered plants emit nitrogen oxides, sulfur dioxide, particulate pollution, and heavy metals, which adversely affect human health. Coalbed methane extraction is important to avoid mining accidents. The deadly Pea soup fog#London, London smog was caused primarily by the heavy use of coal. Globally coal is estimated to cause 800,000 premature deaths every year, mostly in India and China. Burning coal is a major contributor to sulfur dioxide emissions, which creates PM2.5 particulates, the most dangerous form of air pollution. Coal smokestack emissions cause asthma, strokes, reduced intelligence, artery blockages, heart attacks, congestive heart failure, cardiac arrhythmias, mercury poisoning, Stenosis, arterial occlusion, and lung cancer.Coal Pollution Damages Human Health at Every Stage of Coal Life Cycle, Reports Physicians for Social Responsibility
. ''Physicians for Social Responsibility''. psr.org (18 November 2009)
Annual health costs in Europe from use of coal to generate electricity are estimated at up to €43 billion. In China, early deaths due to air pollution coal plants have been estimated at 200 per GW-year, however they may be higher around power plants where scrubbers are not used or lower if they are far from cities. Improvements to China's air quality and human health would grow with more stringent climate policies, mainly because the country's energy is so heavily reliant on coal. And there would be a net economic benefit. A 2017 study in the ''Economic Journal'' found that for Britain during the period 1851–1860, "a one standard deviation increase in coal use raised infant mortality by 6–8% and that industrial coal use explains roughly one-third of the urban mortality penalty observed during this period." Breathing in coal dust causes coalworker's pneumoconiosis or "black lung", so called because the coal dust literally turns the lungs black. In the US alone, it is estimated that 1,500 former employees of the coal industry die every year from the effects of breathing in coal mine dust. Huge amounts of coal ash and other waste is produced annually. Use of coal generates hundreds of millions of tons of ash and other waste products every year. These include fly ash, bottom ash, and flue-gas desulfurization sludge, that contain mercury (element), mercury, uranium, thorium, arsenic, and other heavy metals, along with non-metals such as selenium. Around 10% of coal is ash. Coal ash is hazardous and toxic to human beings and some other living things. Coal ash contains the radioactive elements uranium and thorium. Coal ash and other solid combustion byproducts are stored locally and escape in various ways that expose those living near
coal plants A coal-fired power station or coal power plant is a thermal power station which burns coal to generate electricity. Worldwide there are about 2,500 coal-fired power stations, on average Nameplate capacity, capable of generating a gigawatts, ...
to radiation and environmental toxics.


Damage to the environment

Coal mining, coal combustion wastes, and flue gas are causing major environmental damage. Water systems are affected by coal mining. For example, the mining of coal affects groundwater and water table levels and acidity. Spills of fly ash, such as the Kingston Fossil Plant coal fly ash slurry spill, can also contaminate land and waterways, and destroy homes. Power stations that burn coal also consume large quantities of water. This can affect the flows of rivers, and has consequential impacts on other land uses. In areas of water scarcity, such as the Thar Desert in Pakistan, coal mining and coal power plants contribute to the depletion of water resources. One of the earliest known impacts of coal on the water cycle was acid rain. In 2014, approximately 100 Orders of magnitude (mass)#106 to 1011 kg, Tg/S of sulfur dioxide (SO2) was released, over half of which was from burning coal. After release, the sulfur dioxide is oxidized to H2SO4 which scatters solar radiation, hence its increase in the atmosphere exerts a cooling effect on the climate. This beneficially masks some of the warming caused by increased greenhouse gases. However, the sulfur is precipitated out of the atmosphere as acid rain in a matter of weeks, whereas carbon dioxide remains in the atmosphere for hundreds of years. Release of SO2 also contributes to the widespread acidification of ecosystems. Disused coal mines can also cause issues. Subsidence can occur above tunnels, causing damage to infrastructure or cropland. Coal mining can also cause long lasting fires, and it has been estimated that thousands of coal seam fires are burning at any given time. For example, Brennender Berg has been burning since 1668, and is still burning in the 21st century. The production of coke from coal produces ammonia, coal tar, and gaseous compounds as byproducts which if discharged to land, air or waterways can pollute the environment. The Whyalla steelworks is one example of a coke producing facility where liquid ammonia was discharged to the marine environment.


Climate change

The largest and most long-term effect of coal use is the release of carbon dioxide, a greenhouse gas that causes
climate change Present-day climate change includes both global warming—the ongoing increase in Global surface temperature, global average temperature—and its wider effects on Earth's climate system. Climate variability and change, Climate change in ...
. Coal-fired power plants were the single largest contributor to the growth in global CO2 emissions in 2018,Gençsü (2019), p. 8 40% of the total fossil fuel emissions, and more than a quarter of total emissions. Coal mining can emit methane, another greenhouse gas. In 2016 world gross carbon dioxide emissions from coal usage were 14.5 gigatonnes. For every megawatt-hour generated, coal-fired electric power generation emits around a tonne of carbon dioxide, which is double the approximately 500 kg of carbon dioxide released by a natural gas-fired electric plant. The emission intensity of coal varies with type and generator technology and exceeds 1200 g per kWh in some countries. In 2013, the head of the UN climate agency advised that most of the world's coal reserves should be left in the ground to avoid catastrophic global warming. To keep global warming below 1.5 °C or 2 °C hundreds, or possibly thousands, of coal-fired power plants will need to be retired early.


Underground fires

Thousands of coal fires are burning around the world. Those burning underground can be difficult to locate and many cannot be extinguished. Fires can cause the ground above to subside, their combustion gases are dangerous to life, and breaking out to the surface can initiate surface
wildfire A wildfire, forest fire, or a bushfire is an unplanned and uncontrolled fire in an area of Combustibility and flammability, combustible vegetation. Depending on the type of vegetation present, a wildfire may be more specifically identified as a ...
s. Coal seams can be set on fire by spontaneous combustion or contact with a mine fire or surface fire. Lightning strikes are an important source of ignition. The coal continues to burn slowly back into the seam until oxygen (air) can no longer reach the flame front. A grass fire in a coal area can set dozens of coal seams on fire. Coal fires in China burn an estimated 120 million tons of coal a year, emitting 360 million metric tons of CO2, amounting to 2–3% of the annual worldwide production of CO2 from
fossil fuel A fossil fuel is a flammable carbon compound- or hydrocarbon-containing material formed naturally in the Earth's crust from the buried remains of prehistoric organisms (animals, plants or microplanktons), a process that occurs within geolog ...
s.


Pollution mitigation and carbon capture

Systems and technologies exist to mitigate the Health and environmental impact of the coal industry, health and environmental impact of burning coal for energy.


Precombustion treatment

Refined coal is the product of a coal-upgrading technology that removes moisture and certain pollutants from lower-rank coals such as sub-bituminous and lignite (brown) coals. It is one form of several precombustion treatments and processes for coal that alter coal's characteristics before it is burned. Thermal efficiency improvements are achievable by improved pre-drying (especially relevant with high-moisture fuel such as lignite or biomass). The goals of precombustion coal technologies are to increase efficiency and reduce emissions when the coal is burned. Precombustion technology can sometimes be used as a supplement to postcombustion technologies to control emissions from coal-fueled boilers.


Post combustion approaches

Post combustion approaches to mitigate pollution include flue-gas desulfurization, selective catalytic reduction, electrostatic precipitators, and fly ash reduction.


Carbon capture and storage

Carbon capture and storage (CCS) can be used to capture carbon dioxide from the flue gas of coal power plants and bury it securely in an underground reservoir. Between 1972 and 2017, plans were made to add CCS to enough coal and gas power plants to sequester 161 million tonnes of per year, but by 2021 98% of these plans had failed. Cost, the absence of measures to address long-term liability for stored CO2, and limited social acceptability have all contributed to project cancellations. As of 2024, CCS is in operation at only four coal power plants and one gas power plant worldwide.


"Clean coal" and "abated coal"

Since the mid-1980s, the term "clean coal" has been widely used with various meanings. Initially, "clean coal technology" referred to scrubbers and catalytic converters that reduced the pollutants that cause acid rain. The scope then expanded to include reduction of other pollutants such as mercury. Recently, the term has come to encompass the use of carbon capture and storage to reduce
greenhouse gas emissions Greenhouse gas (GHG) emissions from human activities intensify the greenhouse effect. This contributes to climate change. Carbon dioxide (), from burning fossil fuels such as coal, petroleum, oil, and natural gas, is the main cause of climate chan ...
. In political discourse, the term has been erroneously used to imply that coal itself can be clean. For instance, it has been suggested that "clean coal" can be produced and exported. Even with scrubbers and some CCS, coal still has a fairly high environmental impact. In discussions on greenhouse gas emissions, another common term is "abatement" of coal use. In the 2023 United Nations Climate Change Conference, an agreement was reached to phase down unabated coal use. Since the term ''abated'' was not defined, the agreement was criticized for being open to abuse. Without a clear definition, is possible for fossil fuel use to be called "abated" if it uses CCS only in a minimal fashion, such as capturing only 30% of the emissions from a plant. The Intergovernmental Panel on Climate Change (IPCC) considers fossil fuels to be unabated if they are "produced and used without interventions that substantially reduce the amount of greenhouse gases emitted throughout the life-cycle; for example, capturing 90% or more from power plants."


Economics

In 2018 was invested in coal supply but almost all for sustaining production levels rather than opening new mines. In the long term coal and oil could cost the world trillions of dollars per year. Coal alone may cost Australia billions, whereas costs to some smaller companies or cities could be on the scale of millions of dollars. The economies most damaged by coal (via climate change) may be India and the US as they are the countries with the highest social cost of carbon. Bank loans to finance coal are a risk to the Indian economy. China is the largest producer of coal in the world. It is the world's largest energy consumer, and coal in China supplies 60% of its primary energy. However two fifths of China's coal power stations are estimated to be loss-making. Air pollution from coal storage and handling costs the US almost 200 dollars for every extra ton stored, due to PM2.5. Coal pollution costs the each year. Measures to cut air pollution benefit individuals financially and the economies of countries such as China.


Subsidies

Subsidies for coal in 2021 have been estimated at , not including electricity subsidies, and are expected to rise in 2022. G20 countries provide at least of government support per year for the production of coal, including coal-fired power: many subsidies are impossible to quantify but they include in domestic and international public finance, in fiscal support, and in state-owned enterprise (SOE) investments per year. In the EU state aid to new coal-fired plants is banned from 2020, and to existing coal-fired plants from 2025. As of 2018, government funding for new coal power plants was supplied by Exim Bank of China, the Japan Bank for International Cooperation and Indian public sector banks. Energy in Kazakhstan#Coal, Coal in Kazakhstan was the main recipient of coal consumption subsidies totalling US$2 billion in 2017. coal in Turkey#Subsidies, Coal in Turkey benefited from substantial subsidies in 2021.


Stranded assets

Some coal-fired power stations could become stranded assets, for example China Energy Investment, the world's largest power company, risks losing half its capital. However, state-owned electricity utilities such as Eskom in South Africa, Perusahaan Listrik Negara in Indonesia, Sarawak Energy in Malaysia, Taipower in Taiwan, EGAT in Thailand, Vietnam Electricity and EÜAŞ in Turkey are building or planning new plants. As of 2021 this may be helping to cause a carbon bubble which could cause financial instability if it bursts.


Politics

Countries building or financing new coal-fired power stations, such as China, India, Indonesia, Vietnam, Turkey and Bangladesh, face mounting international criticism for obstructing the aims of the
Paris Agreement The Paris Agreement (also called the Paris Accords or Paris Climate Accords) is an international treaty on climate change that was signed in 2016. The treaty covers climate change mitigation, adaptation, and finance. The Paris Agreement was ...
. In 2019, the Pacific Island nations (in particular Vanuatu and Fiji) criticized Australia for failing to cut their emissions at a faster rate than they were, citing concerns about coastal inundation and erosion. In May 2021, the G7 members agreed to end new direct government support for international coal power generation.


Cultural usage

Coal is the List of U.S. state minerals, rocks, stones and gemstones, official state mineral of Kentucky, and the official state rock of Utah and West Virginia. These US states have a historic link to coal mining. Some cultures hold that children who misbehave will receive only a lump of coal from Santa Claus for Christmas in their christmas stocking, stockings instead of presents. It is also customary and considered lucky in Scotland to give coal as a gift on New Year's Day. This occurs as part of first-footing and represents warmth for the year to come.


See also

* * * * * * (stratigraphic unit) * * * * * * * * * * * Épinac coal mine


Notes


References


Further reading

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External links


Coal Transitions

Coal – International Energy Agency

CoalExit

European Association for Coal and Lignite

Coal news and industry magazine

Global Coal Plant Tracker

Centre for Research on Energy and Clean Air
* * * {{Authority control Coal, Coal mining Economic geology Fuels Sedimentary rocks Solid fuels Fossil fuels