Clinopyroxenite
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Pyroxenite is an
ultramafic Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are usua ...
igneous Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...
rock Rock most often refers to: * Rock (geology), a naturally occurring solid aggregate of minerals or mineraloids * Rock music, a genre of popular music Rock or Rocks may also refer to: Places United Kingdom * Rock, Caerphilly, a location in Wale ...
consisting essentially of
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
s of the
pyroxene The pyroxenes (commonly abbreviated Px) are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents ions of calcium (Ca), sodium (Na), iron ( ...
group, such as
augite Augite, also known as Augurite, is a common rock-forming pyroxene mineral with formula . The crystals are monoclinic and prismatic. Augite has two prominent cleavages, meeting at angles near 90 degrees. Characteristics Augite is a solid soluti ...
,
diopside Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
,
hypersthene Hypersthene is a common rock-forming inosilicate mineral belonging to the group of orthorhombic pyroxenes. Its chemical formula is . It is found in igneous and some metamorphic rocks as well as in stony and iron meteorites. Many references have f ...
,
bronzite Bronzite is a member of the pyroxene group of minerals, belonging with enstatite and hypersthene to the orthorhombic series of the group. Rather than a distinct species, it is really a ferriferous variety of enstatite, which owing to partial alt ...
or
enstatite Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and m ...
. Pyroxenites are classified into clinopyroxenites, orthopyroxenites, and the
websterite Websterite is ultramafic igneous rock, a type of pyroxenite that has less than 5% olivine and roughly equal proportions of orthopyroxene and clinopyroxene. Websterite is named after the town Webster in North Carolina North Carolina ...
s which contain both types of pyroxenes (see diagram below). Closely allied to this group are the
hornblendite Hornblendite is a plutonic rock consisting mainly of the amphibole hornblende. Hornblende-rich ultramafic rocks are rare and when hornblende is the dominant mineral phase they are classified as hornblendites with qualifiers such as garnet hornble ...
s, consisting essentially of
hornblende Hornblende is a complex silicate minerals#Inosilicates, inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common ...
and other
amphibole Amphibole ( ) is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
s. They are essentially of
igneous Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...
origin, though some pyroxenites are included in the
metamorphic Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causi ...
Lewisian complex The Lewisian complex or Lewisian gneiss is a suite of Precambrian metamorphic rocks that outcrop in the northwestern part of Scotland, forming part of the Hebridean terrane and the North Atlantic craton, North Atlantic Craton. These rocks are of ...
of
Scotland Scotland is a Countries of the United Kingdom, country that is part of the United Kingdom. It contains nearly one-third of the United Kingdom's land area, consisting of the northern part of the island of Great Britain and more than 790 adjac ...
where the pyroxene-rich rocks result from the type of
contact metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of c ...
known as pyroxene-hornfels facies, have siliceous sediment or basaltic
protoliths A protolith () is the original, unmetamorphosed rock from which a given metamorphic rock is formed. For example, the protolith of a slate is a shale or mudstone. Metamorphic rocks can be derived from any other kind of non-metamorphic rock and thu ...
, and are respectively metapelites and metabasites.


Intrusive and mantle pyroxenites

Igneous pyroxenites are closely allied to
gabbro Gabbro ( ) is a phaneritic (coarse-grained and magnesium- and iron-rich), mafic intrusive igneous rock formed from the slow cooling magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is ch ...
s and
norite Norite is a mafic Intrusive rock, intrusive igneous rock composed largely of the calcium-rich plagioclase labradorite, orthopyroxene, and olivine. The name ''norite'' is derived from Norway, by its Norwegian name ''Norge''. Norite, also known ...
s, from which they differ by the absence of
feldspar Feldspar ( ; sometimes spelled felspar) is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagiocl ...
, and to
peridotite Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high pr ...
s, which are distinguished from them by containing more than 40%
olivine The mineral olivine () is a magnesium iron Silicate minerals, silicate with the chemical formula . It is a type of Nesosilicates, nesosilicate or orthosilicate. The primary component of the Earth's upper mantle (Earth), upper mantle, it is a com ...
. This connection is indicated also by their mode of occurrence, for they usually accompany masses of gabbro and peridotite and seldom are found by themselves. They are often very coarse-grained, containing individual
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
s which may be several inches in length. The principal accessory minerals, in addition to olivine and feldspar, are
chromite Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of Iron, FeChromium, Cr2Oxygen, O4. It is an oxide mineral belonging to the spinel group. The ...
and other
spinel Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , a diminutive form of ''spine,'' in reference to its pointed crystals. Prop ...
s,
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...
,
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...
,
rutile Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at vis ...
, and
scapolite The scapolites (, "rod", and , "stone") are a group of rock-forming silicate minerals composed of aluminium, calcium, and sodium silicate with chlorine, carbonate and sulfate. The two endmembers are meionite () and marialite (). Silvialite i ...
. Pyroxenites can be formed as cumulates in ultramafic intrusions by accumulation of pyroxene crystals at the base of the magma chamber. Here they are generally associated with gabbro and anorthite cumulate layers and are typically high up in the intrusion. They may be accompanied by
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...
layers,
ilmenite Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printi ...
layers, but rarely
chromite Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of Iron, FeChromium, Cr2Oxygen, O4. It is an oxide mineral belonging to the spinel group. The ...
cumulates. Pyroxenites are also found as layers within masses of peridotite. These layers most commonly have been interpreted as products of reaction between ascending magmas and peridotite of the
upper mantle The upper mantle of Earth is a very thick layer of rock inside the planet, which begins just beneath the crust (geology), crust (at about under the oceans and about under the continents) and ends at the top of the lower mantle (Earth), lower man ...
. The layers typically are a few centimeters to a meter or so in thickness. Pyroxenites that occur as
xenolith A xenolith ("foreign rock") is a rock (geology), rock fragment (Country rock (geology), country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusi ...
s in
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
and in
kimberlite Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known as the main host matrix for diamonds. It is named after the town of Kimberley, Northern Cape, Kimberley in South Africa, where the discovery of an 83.5-Car ...
have been interpreted as fragments of such layers. Although some mantle pyroxenites contain garnet, they are not
eclogite Eclogite () is a metamorphic rock containing garnet ( almandine- pyrope) hosted in a matrix of sodium-rich pyroxene ( omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, zoisit ...
s, as clinopyroxene in them is less sodic than
omphacite Omphacite is a member of the clinopyroxene group of silicate minerals with formula: ( Ca, Na)( Mg, Fe2+, Al) Si2 O6. It is a variably deep to pale green or nearly colorless variety of clinopyroxene. It normally appears in eclogite, which is t ...
and the pyroxenite compositions typically are unlike that of
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
. Pyroxenites might play an important role in basalt genesis (e.g., Lambart et al., 2016), either by contributing directly to the magma production, or indirectly as the result of reaction between peridotite and magma derived from partial melting of eclogite (e.g., Sobolev and others, 2007).


Pyroxenite lavas

Purely pyroxene-bearing volcanic rocks are rare, restricted to spinifex-textured sills,
lava tube A lava tube, more rarely called a pyroduct, is a 'roofed conduit through which molten lava travels away from its vent'. If lava in the tube drains out, it will leave an empty cave. Lava tubes are common in low-viscosity volcanic systems. La ...
s and thick flows in the Archaean
greenstone belt Greenstone belts are zones of variably metamorphosed mafic to ultramafic volcanic sequences with associated sedimentary rocks that occur within Archaean and Proterozoic cratons between granite and gneiss bodies. The name comes from the green h ...
s. Here, the pyroxenite lavas are created by in-situ crystallisation and accumulation of pyroxene at the base of a lava flow, creating the distinctive spinifex texture, but also occasionally mesocumulate and orthocumulate segregations. This is in essence similar to the formation of olivine spinifex textures in
komatiite Komatiite is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% magnesium oxide (MgO). It is classified as a 'picritic rock'. Komatiites have low silicon, potassium and aluminium, and ...
lava flows, the chemistry of the magma differing only to favor crystallisation of pyroxene. A type locality is the Gullewa Greenstone Belt, in the Murchison region of
Western Australia Western Australia (WA) is the westernmost state of Australia. It is bounded by the Indian Ocean to the north and west, the Southern Ocean to the south, the Northern Territory to the north-east, and South Australia to the south-east. Western Aust ...
, and the Duketon Belt near Laverton, where pyroxene spinifex lavas are closely associated with gold deposits.


Distribution

They frequently occur in the form of dikes or segregations in gabbro and peridotite: in
Shetland Shetland (until 1975 spelled Zetland), also called the Shetland Islands, is an archipelago in Scotland lying between Orkney, the Faroe Islands, and Norway, marking the northernmost region of the United Kingdom. The islands lie about to the ...
, Cortland on the
Hudson River The Hudson River, historically the North River, is a river that flows from north to south largely through eastern New York (state), New York state. It originates in the Adirondack Mountains at Henderson Lake (New York), Henderson Lake in the ...
,
North Carolina North Carolina ( ) is a U.S. state, state in the Southeastern United States, Southeastern region of the United States. It is bordered by Virginia to the north, the Atlantic Ocean to the east, South Carolina to the south, Georgia (U.S. stat ...
(websterite),
Baltimore Baltimore is the most populous city in the U.S. state of Maryland. With a population of 585,708 at the 2020 census and estimated at 568,271 in 2024, it is the 30th-most populous U.S. city. The Baltimore metropolitan area is the 20th-large ...
,
New Zealand New Zealand () is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and List of islands of New Zealand, over 600 smaller islands. It is the List of isla ...
, and in
Saxony Saxony, officially the Free State of Saxony, is a landlocked state of Germany, bordering the states of Brandenburg, Saxony-Anhalt, Thuringia, and Bavaria, as well as the countries of Poland and the Czech Republic. Its capital is Dresden, and ...
. They are also found in the
Bushveld Igneous Complex The Bushveld Igneous Complex (BIC) is the largest Layered intrusion, layered igneous intrusion within the Earth's Crust (geology), crust. It has been tilted and Erosion, eroded forming the outcrops around what appears to be the edge of a great Ba ...
in South Africa and The
Great Dyke The Great Dyke or Dike is a linear geological feature that trends nearly north-south through the centre of Zimbabwe passing just to the west of the capital, Harare. It consists of a band of short, narrow ridges and hills spanning for approximate ...
in Zimbabwe.Stratigraphy of the BIC http://jgs.lyellcollection.org/content/161/6/903/F2.large.jpg The pyroxenites are often subject
serpentinization Serpentinization is a hydration and Metamorphic rock, metamorphic transformation of ferromagnesian minerals, such as olivine and pyroxene, in mafic and ultramafic rock to produce serpentinite. Minerals formed by serpentinization include the Serp ...
under low temperature retrograde metamorphism and
weathering Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no move ...
. The rocks are often completely replaced by serpentines, which sometimes preserve the original structures of the primary minerals, such as the lamination of hypersthene and the rectangular cleavage of augite. Under pressure-metamorphism hornblende is developed and various types of
amphibolite Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose ...
and hornblende-
schist Schist ( ) is a medium-grained metamorphic rock generally derived from fine-grained sedimentary rock, like shale. It shows pronounced ''schistosity'' (named for the rock). This means that the rock is composed of mineral grains easily seen with a l ...
are produced. Occasionally rocks rich in pyroxene are found as basic facies of
nepheline syenite Nepheline syenite is a holocrystalline Intrusion, plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varie ...
; a good example is provided by the
melanite Andradite is a mineral species of the garnet group. It is a nesosilicate, with chemical formula Ca3Fe2Si3O12. Andradite includes three varieties: * '' Colophonite'': a historical variety found in the Scandinavian islands, brownish or reddish in ...
pyroxenites associated with the ''borolanite'' variety found in the Loch Borralan igneous complex of
Scotland Scotland is a Countries of the United Kingdom, country that is part of the United Kingdom. It contains nearly one-third of the United Kingdom's land area, consisting of the northern part of the island of Great Britain and more than 790 adjac ...
.


References


Lambart, S. L., and others, 2016, ''The role of pyroxenite in basalt genesis: Melt-PX, a melting parameterization for mantle pyroxenites between 0.9 and 5 GPa'', Journal of Geophysical Research – Solid Earth 121, p. 5708–5735Sobolev, A. V., and others, 2007, ''The amount of recycled crust in sources of mantle-derived melts'', Science 316, p. 412-417
(abstract) Retrieved on 6 October 2007


External links

* * {{Rock type Ultramafic rocks Plutonic rocks Volcanic rocks