Earthen plaster is made of
clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
,
sand
Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is usually defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a textural ...
and often mixed with plant fibers. The material is often used as an aesthetically pleasing finish coat and also has several functional benefits. This natural plaster layer is known for its breathability, moisture-regulating ability and ability to promote a healthy indoor environment. In the context of stricter
indoor air quality
Indoor air quality (IAQ) is the air quality within buildings and Nonbuilding structure, structures. Poor indoor air quality due to indoor air pollution is known to affect the health, comfort, and well-being of building occupants. It has also be ...
regulations, earthen plaster shows great potential because of its properties as a building material.
Physical composition
All
plasters and
stuccos
Stucco or render is a construction material made of aggregates, a binder, and water. Stucco is applied wet and hardens to a very dense solid. It is used as a decorative coating for walls and ceilings, exterior walls, and as a sculptural and a ...
have several common features: they all contain a structural component, a binding element, and some form of fiber. Usually the term plaster refers to a wall covering made from
earth
Earth is the third planet from the Sun and the only astronomical object known to Planetary habitability, harbor life. This is enabled by Earth being an ocean world, the only one in the Solar System sustaining liquid surface water. Almost all ...
,
lime
Lime most commonly refers to:
* Lime (fruit), a green citrus fruit
* Lime (material), inorganic materials containing calcium, usually calcium oxide or calcium hydroxide
* Lime (color), a color between yellow and green
Lime may also refer to:
Bo ...
or
gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...
, while stucco uses a
cement
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mi ...
or synthetic binding element.
Clay: the binding agent
Clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
, a crucial
soil
Soil, also commonly referred to as earth, is a mixture of organic matter, minerals, gases, water, and organisms that together support the life of plants and soil organisms. Some scientific definitions distinguish dirt from ''soil'' by re ...
component with particles smaller than 2 micrometers, exhibits glue-like properties in the presence of water due to its extremely small particle size and high surface-to-volume ratio. This allows it to bind effectively with sand and
fibers
Fiber (spelled fibre in British English; from ) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often inco ...
, playing a key role in holding the mixture together and securing it to the wall. Additionally, when clay is wet, its plasticity enhances the workability of plaster mixtures.
Within the domain of earthen building materials, clay particles act as primary binders. These particles not only provide workability during the plastic phase but also ensure cohesion after drying, contributing to the structural integrity of the construction. Notable clay minerals involved in this process include
montmorillonite
Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite grou ...
,
chlorite
The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
and
illite
Illite, also called hydromica or hydromuscovite, is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandw ...
, each adding distinct properties to the composition. Despite the chemical variation among clays, their prevailing crystalline phases primarily consist of phyllosilicates, such as the mentioned clay minerals. The colloidal component further includes poorly crystalline hydrous
aluminum silicates, along with iron and aluminum oxides.
The clay proportion significantly influences mixture characteristics, impacting strength, shrinkage, and mixing water requirements. However, it's essential to note that the recommended maximum clay content in the earth mixture is 25%.
Sand: structural strength
Sand, the granular skeletal component, provides structure, durability, and volume to earthen plasters. Consisting of tiny mineral particles derived from its original rock material, sand is predominantly made up of
silicon dioxide
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundan ...
(
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
) and is recognized as a non-reactive substance.
Sand is incorporated into the plaster mixture not just for structural purposes but also plays a vital role in minimizing the likelihood of cracks during the drying process. Moreover, the presence of sand not only helps in preventing cracks but also results in a reduction in the sorptive capacity of the mixture. This dual impact indicates the careful balancing act required in soil composition to achieve both structural integrity and controlled moisture absorption.
Given that sand naturally occurs in various
subsoils
Subsoil is the layer of soil under the topsoil on the surface of the ground. Like topsoil, it is composed of a variable mixture of small particles such as sand, silt and clay, but with a much lower percentage of organic matter and humus. The su ...
, there's a possibility that all the necessary sand is already inherent in the soil.
Fiber: tensile strength and reinforcement
In the context of improving adhesion and compatibility with different substrates, fibers may be introduced to earthen plasters without compromising their environmental profile. Various natural fibers, such as dry straw, hemp, cattails, coconut fiber, shells, and animal hair, prove to be suitable choices for reinforcing earthen plasters.
Research indicates that the inclusion of
natural fibers
Natural fibers or natural fibres (see spelling differences) are fibers that are produced by geological processes, or from the bodies of plants or animals.
They can be used as a component of composite materials, where the orientation of fibers ...
, moderately increases open porosity, facilitating improved pore interconnection. A meshwork is formed within the plaster, enhancing cohesion and providing flexibility to the dried mixture.
Clay tends to shrink and crack during drying, the added fibers effectively counteract these issues. The presence of fibers in the mixture significantly reduces drying shrinkage, with larger fibers exhibiting a more pronounced effect than finer ones. This reduction is attributed to the increased water content required for workability when adding more and finer fibers.
Exploring the physical performance changes resulting from the addition of natural fibers reveals a reduction in material density. The bulk density decreases with higher fiber content, while adhesion strength experiences a positive trend with the addition of fibers, particularly when more and finer fibers are incorporated.
The addition of fibers to plasters is observed to have various benefits, including reduced density, minimized shrinkage cracks, and improved adhesion strength. While the general influence on compressive strength and tensile strength may vary depending on base materials and fibers, the overall conclusion of the research affirms the positive impact of adding fibers to earthen plasters. This enhancement encompasses reduced heat conduction, decreased drying shrinkage, and an improved hygienic buffering capacity.
Water: viscosity
Water plays a crucial role in the formulation and application of clay plaster, impacting both its workability and structural integrity. As mentioned earlier, clay exhibits adhesive properties in the presence of water, emphasizing the waters vital role in providing structural support. The amount of water added is determined by the specific characteristics of the clay and the overall mixture proportions.
However, the balance between water content and plaster performance becomes apparent in the compressive strength of the material. An increase in initial water content can negatively affect compressive strength. Striking a balance is crucial. For optimal plasticity, the water requirement for plasters should fall within the liquid and plastic limits of the soil. Opting for a water-clay content close to the liquid boundary can enhance ease of application and mitigate surface cracking. The recommended approach is to maintain an initial water content between 30% and 40% of the clay's weight.
It's noteworthy that as the clay content in the mixture increases, so does the demand for water. However, a delicate equilibrium must be maintained to prevent potential shrinkage cracks associated with higher water content. Achieving an optimal water-clay ratio is crucial for utilize the benefits of clay plaster while preserving its structural integrity.
Additives
Additives can be incorporated into the composition of clay, sand, water, and fiber to enhance various properties of the plaster. Depending on the application, these additives may be selectively applied to the final coat or included in all layers. Many commonly used additives originate either from natural sources or result from industrial and agricultural processes, providing a cost-effective means to refine the characteristics of clay plaster. The diversity of additives allows for their blending in various proportions, each inducing distinct alterations in the plaster. Due to the absence of a comprehensive theoretical model explaining these effects, predicting the impact of a specific additive in a particular plaster mixture relies on empirical testing for each combination.
The primary utilization of additives revolves around addressing inherent weaknesses in clay plaster, such as dry shrinkage, mechanical strength, or adhesion. Furthermore, certain additives aim to enhance properties crucial for indoor applications, including thermal resistance and moisture buffering capacity.
Biopolymers
Biopolymers are a broad group of additives that are produced from plants or animals. They can serve many purposes: some biopolymers can act as a glue holding the matrix together, while others help fill cavities and supplement the particle distribution, both will increase the cohesion. This can cause multiple benefits: increased density often leads to an increase in overall strength, while less porous plasters prove more water resistant and durable. Some biopolymers also influence the viscosity and processability of the plaster, requiring less water and therefore reducing the dry shrinkage.
Some of the most common biopolymer additives are
wheat flour paste, manure, cactus juice, casein (milk protein) and various natural oils such as
linseed oil
Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colorless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by pressing, sometimes followed by ...
. Other additives include:
stearate,
tallow
Tallow is a rendered form of beef or mutton suet, primarily made up of triglycerides.
In industry, tallow is not strictly defined as beef or mutton suet. In this context, tallow is animal fat that conforms to certain technical criteria, inc ...
,
tannin
Tannins (or tannoids) are a class of astringent, polyphenolic biomolecules that bind to and Precipitation (chemistry), precipitate proteins and various other organic compounds including amino acids and alkaloids. The term ''tannin'' is widel ...
,
leaves
A leaf (: leaves) is a principal appendage of the stem of a vascular plant, usually borne laterally above ground and specialized for photosynthesis. Leaves are collectively called foliage, as in "autumn foliage", while the leaves, stem, ...
and
bark
Bark may refer to:
Common meanings
* Bark (botany), an outer layer of a woody plant such as a tree or stick
* Bark (sound), a vocalization of some animals (which is commonly the dog)
Arts and entertainment
* ''Bark'' (Jefferson Airplane album), ...
of certain trees,natural gums and glues,
kelp
Kelps are large brown algae or seaweeds that make up the order (biology), order Laminariales. There are about 30 different genus, genera. Despite its appearance and use of photosynthesis in chloroplasts, kelp is technically not a plant but a str ...
,
powdered milk
Powdered milk, also called milk powder, dried milk, or dry milk, is a manufactured dairy product made by evaporating milk to dryness. One purpose of drying milk is to preserve it; milk powder has a far longer shelf life than liquid milk and do ...
, or the
blood
Blood is a body fluid in the circulatory system of humans and other vertebrates that delivers necessary substances such as nutrients and oxygen to the cells, and transports metabolic waste products away from those same cells.
Blood is com ...
of livestock.
= Flour paste
=
Cooked flour paste is a cheap natural
glue
Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation.
The use of adhesives offers certain advantage ...
that is easy to make from common ingredients. The water and flour slurry is cooked until the gluten binds the elements of the mixture, creating a durable glue. In plaster, the flour paste serves as a binding agent and a hardener.
= Manure
=
Manure serves as a binding agent and gives plaster more body. Manure also contains small natural fibers that provide additional
tensile strength
Ultimate tensile strength (also called UTS, tensile strength, TS, ultimate strength or F_\text in notation) is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials, the ultimate ...
as well as reduce cracking and
water erosion
Erosion is the action of surface processes (such as water flow or wind) that removes soil, rock, or dissolved material from one location on the Earth's crust and then transports it to another location where it is deposited. Erosion is disti ...
. Different types of manure have different effects. Horse manure has a high microfiber content, but cow manure has more hardening enzymes. People have reported success with
llama
The llama (; or ) (''Lama glama'') is a domesticated South American camelid, widely used as a List of meat animals, meat and pack animal by Inca empire, Andean cultures since the pre-Columbian era.
Llamas are social animals and live with ...
and
alpaca
The alpaca (''Lama pacos'') is a species of South American camelid mammal. Traditionally, alpacas were kept in herds that grazed on the level heights of the Andes of Southern Peru, Western Bolivia, Ecuador, and Northern Chile. More recentl ...
dung. Manure should be fresh or fermented when mixed with plaster, as composted manure loses its
enzyme
An enzyme () is a protein that acts as a biological catalyst by accelerating chemical reactions. The molecules upon which enzymes may act are called substrate (chemistry), substrates, and the enzyme converts the substrates into different mol ...
s and adhesive qualities. Manure should be sifted before use.
= Prickly pear cactus juice
=
The liquid from
prickly pear cactus used to be one of the most common additives in
the Americas
The Americas, sometimes collectively called America, are a landmass comprising the totality of North America and South America.'' Webster's New World College Dictionary'', 2010 by Wiley Publishing, Inc., Cleveland, Ohio. When viewed as a sin ...
.
The juice from the prickly pear cactus leaf pads will serve many functions. According to some sources, it helps the plaster set and increases its stickiness or
adhesion
Adhesion is the tendency of dissimilar particles or interface (matter), surfaces to cling to one another. (Cohesion (chemistry), Cohesion refers to the tendency of similar or identical particles and surfaces to cling to one another.)
The ...
. Cactus juice also serves as a stabilizer in that it helps make earthen plasters more water-resistant and more durable. It also prevents dusting.
Cactus juice can increase plaster's workability and its ability to be formed into the desired shape. Workability depends on the water content, the shape and size distribution of its
aggregate (such as rock, sand, natural fiber, etc.), the age of the plaster, and the amount of other natural binder(s) (such as
lime
Lime most commonly refers to:
* Lime (fruit), a green citrus fruit
* Lime (material), inorganic materials containing calcium, usually calcium oxide or calcium hydroxide
* Lime (color), a color between yellow and green
Lime may also refer to:
Bo ...
,
wheatpaste
Wheatpaste (also known as flour and water paste, flour paste, or simply paste) is a gel or liquid adhesive made from wheat flour or starch and water. It has been used since antiquity for various arts and crafts such as bookbinding, ''Decoupage, ...
, cactus juice, hardening
vegetable oil
Vegetable oils, or vegetable fats, are oils extracted from seeds or from other parts of edible plants. Like animal fats, vegetable fats are ''mixtures'' of triglycerides. Soybean oil, grape seed oil, and cocoa butter are examples of seed ...
,
casein
Casein ( , from Latin ''caseus'' "cheese") is a family of related phosphoproteins (CSN1S1, αS1, aS2, CSN2, β, K-casein, κ) that are commonly found in mammalian milk, comprising about 80% of the proteins in cow's milk and between 20% and 60% of ...
and other
protein
Proteins are large biomolecules and macromolecules that comprise one or more long chains of amino acid residue (biochemistry), residues. Proteins perform a vast array of functions within organisms, including Enzyme catalysis, catalysing metab ...
s, etc.) Altering the water content, changing the aggregate mix, soaking the clay, or changing the binders will increase or decrease the plaster's workability. Excessive water will lead to increased bleeding (surface water) and/or segregation of aggregates (when the natural binder and aggregates start to separate), with the resulting plaster having reduced quality. The use of an aggregate with an undesirable gradation can result in a very harsh mix design with a very low workability, which cannot be readily made more workable by addition of reasonable amounts of water or binder.
Cactus juice works well because it contains
pectin
Pectin ( ': "congealed" and "curdled") is a heteropolysaccharide, a structural polymer contained in the primary lamella, in the middle lamella, and in the cell walls of terrestrial plants. The principal chemical component of pectin is galact ...
, a water-soluble long-chain
carbohydrate
A carbohydrate () is a biomolecule composed of carbon (C), hydrogen (H), and oxygen (O) atoms. The typical hydrogen-to-oxygen atomic ratio is 2:1, analogous to that of water, and is represented by the empirical formula (where ''m'' and ''n'' ...
that acts as the binding agent to increase the adhesion of an earthen plaster. Pectin is also responsible for increasing the water resistance of an earthen plaster and has been used to augment
lime plaster
Lime plaster is a type of plaster composed of sand, water, and lime, usually non-hydraulic hydrated lime (also known as slaked lime, high calcium lime or air lime). Ancient lime plaster often contained horse hair for reinforcement and pozzolan ...
s in both Mexico and the southwestern United States for hundreds of years.
Cactus juice is extracted by immersing cut leaves in water for as long as two weeks.
Other additives
= Industrial waste
=
Certain industrial byproducts can be added to attain better mechanical properties, namely strength and shrinkage. Researchers have tested fly ash, limestone sludge, hydraulic lime and dextrin and its effects on the plaster.The addition of limestone sludge and hydraulic lime resulted in a reduced shrinkage when drying, which helps prevent cracks and improve adhesion to application surface. Fly ash and dextrin both improved the mechanical strength of the plaster. It should be noted however that the dosage proved to be very important for the final properties, with each additive showing different results depending on the amount that was mixed in.
= Paper waste
=
Paper waste can also be included in the plaster to improve its hygrothermal properties. Because it is a waste product is often very cheap and broadly available. Research shows that the addition of paper waste improved the moisture buffering capacity of clay plaster, while also lowering its density. This lowering in density also means that the plaster becomes a better thermal insulator.
Interior earthen plaster
Earthen plasters are becoming more popular in interior design due to its sustainable and eco-friendly characteristics. The plaster influences the thermal comfort, the indoor air quality and energy efficiency in a positive way. During the drying process however, there is shrinkage which affects its ability to adhere properly to the surface.
This can be solved by using different types of wire meshes, using composite plasters or other additives. The other possibility is to paint a mixture of sand and wheat paste on to the surface on which the plaster will be applied.
There are different ways to applicate the earthen plaster. The plaster can be applied in three coats, this is the Spanish process known as 'alisando'. The first layer is the scratch coat which provides adherence for the second layer the brown coat or levelling coat. The final layer is the color coat or finishing coat. This layer is usually clay with sand but without fiber. Other manufacturers only apply the color/finishing coat. This single layer provides less of the advantages discussed later, but it still has advantages compared to gypsum plaster.
Effect on indoor climate
In principle, all wall coverings have an effect on the room climate: vapour permeable coatings designed to be capillary conductive, allow the wall layers behind them to absorb moisture and release it again. Due to the property of clay plasters to absorb moisture, a buffer is created on the wall, which absorbs moisture and releases it again when the air humidity is low. The area and the thickness of the plastered wall have the greatest influence on the ability of the clay plaster to act as a climatic buffer. The majority of the moisture is kept in the top layer of the clay plaster, so this layer is the most important for the climate buffer effect. Clay also has a high specific heat capacity, this allows the clay plaster to compensate for temperature fluctuations in the room.
Moisture buffering
Moisture has a significant impact on the indoor environment of a building. Excessive moisture can lead to mold growth, poor air quality, and structural damage. Conversely, a too dry environment can cause discomfort, affecting both health and material preservation. Effective moisture regulation is therefore crucial for a healthy, sustainable, and comfortable living environment. Clay is renowned for its remarkable ability to regulate moisture, a property known as moisture buffering.
Clay possesses the unique capability to both adsorb and absorb water. Adsorption refers to the retention of moisture on the surface of clay particles, while absorption pertains to the uptake of moisture into the material's pores. As the humidity in a space rises, clay can absorb excess moisture. At lower humidity levels, clay gradually releases the absorbed moisture through evaporation.
The porous nature of clay and its high specific surface area, contribute to its moisture-buffering properties. The pores act as reservoirs where moisture can be retained and released. Additionally, the clay content plays a role in moisture buffering. Clay naturally attracts and holds water molecules. Consequently, a higher clay content results in enhanced buffering, although it does not necessarily translate to improved clay plaster. However, clay has the drawback of shrinking as it dries. A higher clay content in the clay plaster may lead to increased shrinkage, potentially causing crack formation.
Not only does the clay content, but also the mineralogical composition, play a crucial role. Clay is considered hygroscopic, indicating its ability to absorb water from the surrounding environment. This contributes to the regulation of relative humidity in a space. However, different clay minerals exhibit varying hygroscopicity. For instance, the montmorillonite clay mineral demonstrates high hygroscopicity, whereas kaolinite exhibits low hygroscopicity. Clay plasters with different compositions and ratios will consequently have distinct moisture-buffering capacities.
Ozone
= General information
=
Ozone reacts with many indoor materials, as well with compounds in the indoor air. Reactions between ozone and building surfaces are able to generate and release aerosols and irritating carcinogenic gases, they may be irritating or harmful for building occupants. Indoor air quality is very important, because it is known that most of the people in developed countries spend almost 90% of their lives indoor. In a human body, ozone reacts with tissue cells that promote inflammation and increased permeability of the epithelial lining fluid, which allows for greater penetration of pollutants from lung air into the blood stream. Several studies show that there are some PRMs, passive removal materials, that passively, without using energy, remove ozone out of the indoor air without generating harmful byproducts. Clay wall plaster appears a promising passive removal material for ozone, due to its relatively high ozone reaction probability.
= Production of ozone
=
Ozone is produced outdoors, but there are also sources of ozone in indoor environments, for example laser printers, photocopy machines. Various measurements show that the indoor ozone concentration closely tracks outdoor concentration and it is dependent on the air exchange rate. The indoor ozone concentration divided by the outdoor ozone concentration (I/O) remains relatively constant.
= Indoor air pollution
=
Many sources contribute to indoor air pollution. There are pollutants originate from the outside and pollutants which originate from indoor materials. Outdoor air pollutants are classified as biological pollutants (UOB), such as ozone, sulfur oxides, nitrogen oxides, benzene and lead compounds... . The pollutants originating from the interior of the building are building compounds and chemicals released from the indoor materials and pollutants resulting from human and machine activities. They are examined in three categories. The first category includes pollutants, second gases and chemicals, last particles and fibers. There are two types of indoor air pollutants. Primary pollutants or VOC’s can be emitted directly from a surface. Secondary pollutants or VOC’s are caused by gas-phase transformations or surface oxidation. An important difference between primary and secondary VOC’s is the temporal evolution. The emission of primary VOC’s decline at a predictable rate and reduces to lower levels within a year. The emission of secondary VOC’s is more prolonged and can continue for several years. Examples of secondary pollutants, which are more damaging for human health, are aldehydes, ketones and SOA.
Passive removal materials are an alternative method for removing ozone from indoor environments. The characteristics of a passive removal material are, removing ozone out of indoor environments without consuming energy, ozone removal over long time, minimal reaction product formation, large surface area coverage, while maintaining aesthetic appeal. PRM's for ozone are inorganic materials, including clay-based bricks and plasters.
= Ozone reactions
=
There are two types of reactions that take place. Gas-phase, or homogeneous reactions take place between ozone and some chemicals that are emitted to indoor air. For example, alkenes emitted from building materials, furniture, and numerous cleaning and consumer products. These homogeneous reactions can produce secondary organic aerosols (SOA's) as well as a range of gaseous oxidized products. There are also surface or heterogeneous reactions that can occur on furniture, dust, human skin.
These reactions can produce C1-C10 carbonyls, dicarbonyls and hydroxycarbonyls, that may be irritating or harmful to building occupants.
= Effect of indoor air pollution on human health
=
Important things to consider when talking about the impact of indoor air pollution on human health are the way of exposure to the pollutants, the interaction of the pollutants with their surrounding environment and the identification of the source. The nose and lungs are the parts of the human body which are most exposed to indoor air pollution, which is logically as the respiratory system is most affected by indoor air pollution. The size of the pollutants is also an important factor. Particles with a diameter greater than 10 microns are trapped in mouth and nose, smaller particles can pass through the mouth and nose into the respiratory system. The smallest particles of 2-3 microns can pass through the lungs and stick to the alveoli.
= Quantified parameters ozone
=
Deposition velocity
Deposition velocity = is a mass-transfer coefficient that relates the bulk-air concentration to the flux of ozone to a surface.
# Deposition velocity = is a mass-transfer coefficient that relates the bulk-air concentration to the flux of ozone to a surface.
Clay wall plaster and clay wall paint have a very high deposition velocity. In general, fleecy and porous materials exhibit higher deposition velocities than smooth sealed surfaces. The high deposition velocities exhibited by clay wall plaster or paint may be due to iron or aluminum catalyzed decomposition of ozone.
Reaction probability
2. Reaction probability is the probability of reaction if an ozone molecule collides with a surface. Where <
> is the Boltzmann velocity (
for ozone at 296K)
Reaction probabilities for clay paint in comparison to clay plaster are higher. The clay paint is statistically more reactive than the clay plaster because it contains cellulose and alcohol esters, two components who reacts with ozone. Reaction probabilities of clay plaster are due to its major component, kaolinite. Kaolinite is a hydrous aluminosilicate mineral that comprises 50% of the clay plaster. Consistent with the trend for deposition velocity, fleecy and porous materials exhibit higher reaction probabilities than smooth, non-porous materials.
yield
3. Yield= molar yield is defined as the molar emission rate of carbonyl compounds formed due to reactions between the material and ozone divided by the molar flux of ozone between the material surface.
Of the highly reactive materials, only clay-based wall plaster combines very low yields with high ozone removal rates.
Clay wall plaster exhibited very high deposition velocities and negligible yields. Clay and materials containing clay (e.g. bricks) consume ozone readily, perhaps because of a reaction catalyzed by metals present in the clay. Clay plaster with very high ozone uptake rates, has certain surface roughness, and porosity. Several studies propose that the high aluminum or iron content and high surface area combine to make the clay plaster, a particularly good ozone scavenging building material. Field test show that materials as clay paint and carpet become less reactive over interval of years, probably due to slow oxidation of organic coatings. This process is named as “ozone aging”. Clay does not appear to become substantially less reactive. Clay plaster has the ability to “regenerate” after periods without lot of ozone exposure. Materials composed of clay are not necessarily good at removing ozone. Even though they are composed of clay, ceramic tiles exhibit low deposition velocities.
Surface removal
Ozone surface removal rate of a material (
) depends on its ozone deposition rate (
), surface area (A) and volume (V) of the enclosed space in which the material is placed.