Naturally occurring
chromium
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.
Chromium metal is valued for its high corrosion resistance and hardne ...
(
24Cr) is composed of four stable
isotopes;
50Cr,
52Cr,
53Cr, and
54Cr with
52Cr being the most abundant (83.789%
natural abundance).
50Cr is suspected of decaying by
β+β+ to
50Ti with a
half-life of (more than) 1.8×10
17 years. Twenty-two
radioisotopes, all of which are entirely synthetic, have been characterized with the most stable being
51Cr with a half-life of 27.7 days. All of the remaining
radioactive isotopes have half-lives that are less than 24 hours and the majority of these have half-lives that are less than 1 minute, the least stable being
66Cr with a half-life of 10 milliseconds. This element also has 2
meta states,
45mCr, the more stable one, and
59mCr, the least stable isotope or isomer.
53Cr is the
radiogenic decay product of
53 Mn. Chromium
isotopic contents are typically combined with
manganese isotopic contents and have found application in
isotope geology.
Mn-Cr isotope ratios reinforce the evidence from
26 Al and
107 Pd for the early history of the
Solar System. Variations in
53Cr/
52Cr and Mn/Cr ratios from several meteorites indicate an initial
53Mn/
55Mn ratio that suggests Mn-Cr isotope systematics must result from in-situ decay of
53Mn in differentiated planetary bodies. Hence
53Cr provides additional evidence for
nucleosynthetic processes immediately before coalescence of the Solar System. The same isotope is preferentially involved in certain
leaching reactions, thereby allowing its abundance in seawater sediments to be used as a proxy for atmospheric oxygen concentrations.
[
]
The isotopes of chromium range from
42Cr to
67Cr. The primary
decay mode
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...
before the most abundant stable isotope,
52Cr, is
electron capture and the primary mode after is
beta decay.
List of isotopes
, -
, rowspan=2,
42Cr
, rowspan=2 style="text-align:right" , 24
, rowspan=2 style="text-align:right" , 18
, rowspan=2, 42.00643(32)#
, rowspan=2, 14(3) ms
3(+4-2) ms,
β+ (>99.9%)
,
42V
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
,
2p (<.1%)
,
40Ti
, -
, rowspan=4,
43Cr
, rowspan=4 style="text-align:right" , 24
, rowspan=4 style="text-align:right" , 19
, rowspan=4, 42.99771(24)#
, rowspan=4, 21.6(7) ms
, β
+ (71%)
,
43V
, rowspan=4, (3/2+)
, rowspan=4,
, rowspan=4,
, -
, β
+, p (23%)
,
42Ti
, -
, β
+, 2p (6%)
,
41Sc
, -
, β
+,
α (<.1%)
,
39Sc
, -
, rowspan=2,
44Cr
, rowspan=2 style="text-align:right" , 24
, rowspan=2 style="text-align:right" , 20
, rowspan=2, 43.98555(5)#
, rowspan=2, 54(4) ms
3(+4-3) ms, β
+ (93%)
,
44V
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β
+, p (7%)
,
43Ti
, -
, rowspan=2,
45Cr
, rowspan=2 style="text-align:right" , 24
, rowspan=2 style="text-align:right" , 21
, rowspan=2, 44.97964(54)
, rowspan=2, 50(6) ms
, β
+ (73%)
,
45V
, rowspan=2, 7/2−#
, rowspan=2,
, rowspan=2,
, -
, β
+, p (27%)
,
44Ti
, -
, rowspan=2 style="text-indent:1em" ,
45mCr
, rowspan=2 colspan="3" style="text-indent:2em" , 50(100)# keV
, rowspan=2, 1# ms
,
IT
,
45Cr
, rowspan=2, 3/2+#
, rowspan=2,
, rowspan=2,
, -
, β
+
,
45V
, -
,
46Cr
, style="text-align:right" , 24
, style="text-align:right" , 22
, 45.968359(21)
, 0.26(6) s
, β
+
,
46V
, 0+
,
,
, -
,
47Cr
, style="text-align:right" , 24
, style="text-align:right" , 23
, 46.962900(15)
, 500(15) ms
, β
+
,
47V
, 3/2−
,
,
, -
,
48Cr
, style="text-align:right" , 24
, style="text-align:right" , 24
, 47.954032(8)
, 21.56(3) h
, β
+
,
48V
, 0+
,
,
, -
,
49Cr
, style="text-align:right" , 24
, style="text-align:right" , 25
, 48.9513357(26)
, 42.3(1) min
, β
+
,
49V
, 5/2−
,
,
, -
,
50Cr
, style="text-align:right" , 24
, style="text-align:right" , 26
, 49.9460442(11)
, colspan=3 align=center,
Observationally Stable[Suspected of decaying by double electron capture to 50Ti with a half-life of no less than 1.3 a]
, 0+
, 0.04345(13)
, 0.04294–0.04345
, -
,
51Cr
, style="text-align:right" , 24
, style="text-align:right" , 27
, 50.9447674(11)
, 27.7025(24) d
,
EC
,
51V
, 7/2−
,
,
, -
,
52Cr
, style="text-align:right" , 24
, style="text-align:right" , 28
, 51.9405075(8)
, colspan=3 align=center, Stable
, 0+
, 0.83789(18)
, 0.83762–0.83790
, -
,
53Cr
, style="text-align:right" , 24
, style="text-align:right" , 29
, 52.9406494(8)
, colspan=3 align=center, Stable
, 3/2−
, 0.09501(17)
, 0.09501–0.09553
, -
,
54Cr
, style="text-align:right" , 24
, style="text-align:right" , 30
, 53.9388804(8)
, colspan=3 align=center, Stable
, 0+
, 0.02365(7)
, 0.02365–0.02391
, -
,
55Cr
, style="text-align:right" , 24
, style="text-align:right" , 31
, 54.9408397(8)
, 3.497(3) min
, β
−
,
55Mn
, 3/2−
,
,
, -
,
56Cr
, style="text-align:right" , 24
, style="text-align:right" , 32
, 55.9406531(20)
, 5.94(10) min
, β
−
,
56Mn
, 0+
,
,
, -
,
57Cr
, style="text-align:right" , 24
, style="text-align:right" , 33
, 56.943613(2)
, 21.1(10) s
, β
−
,
57Mn
, (3/2−)
,
,
, -
,
58Cr
, style="text-align:right" , 24
, style="text-align:right" , 34
, 57.94435(22)
, 7.0(3) s
, β
−
,
58Mn
, 0+
,
,
, -
,
59Cr
, style="text-align:right" , 24
, style="text-align:right" , 35
, 58.94859(26)
, 460(50) ms
, β
−
,
59Mn
, 5/2−#
,
,
, -
, style="text-indent:1em" ,
59mCr
, colspan="3" style="text-indent:2em" , 503.0(17) keV
, 96(20) µs
,
,
, (9/2+)
,
,
, -
,
60Cr
, style="text-align:right" , 24
, style="text-align:right" , 36
, 59.95008(23)
, 560(60) ms
, β
−
,
60Mn
, 0+
,
,
, -
, rowspan=2,
61Cr
, rowspan=2 style="text-align:right" , 24
, rowspan=2 style="text-align:right" , 37
, rowspan=2, 60.95472(27)
, rowspan=2, 261(15) ms
, β
− (>99.9%)
,
61Mn
, rowspan=2, 5/2−#
, rowspan=2,
, rowspan=2,
, -
, β
−,
n (<.1%)
,
60Mn
, -
, rowspan=2,
62Cr
, rowspan=2 style="text-align:right" , 24
, rowspan=2 style="text-align:right" , 38
, rowspan=2, 61.95661(36)
, rowspan=2, 199(9) ms
, β
− (>99.9%)
,
62Mn
, rowspan=2, 0+
, rowspan=2,
, rowspan=2,
, -
, β
−, n
,
61Mn
, -
, rowspan=2,
63Cr
, rowspan=2 style="text-align:right" , 24
, rowspan=2 style="text-align:right" , 39
, rowspan=2, 62.96186(32)#
, rowspan=2, 129(2) ms
, β
−
,
63Mn
, rowspan=2, (1/2−)#
, rowspan=2,
, rowspan=2,
, -
, β
−, n
,
62Mn
, -
,
64Cr
, style="text-align:right" , 24
, style="text-align:right" , 40
, 63.96441(43)#
, 43(1) ms
, β
−
,
64Mn
, 0+
,
,
, -
,
65Cr
, style="text-align:right" , 24
, style="text-align:right" , 41
, 64.97016(54)#
, 27(3) ms
, β
−
,
65Mn
, (1/2−)#
,
,
, -
,
66Cr
, style="text-align:right" , 24
, style="text-align:right" , 42
, 65.97338(64)#
, 10(6) ms
, β
−
,
66Mn
, 0+
,
,
, -
,
67Cr
, style="text-align:right" , 24
, style="text-align:right" , 43
, 66.97955(75)#
, 10# ms
300 ns, β
−
,
67Mn
, 1/2−#
,
,
Chromium-51
Chromium-51 is a manmade isotope of chromium used in medicine as a radioisotopic tracer.
References
* Isotope masses from:
**
* Isotopic compositions and standard atomic masses from:
**
**
* Half-life, spin, and isomer data selected from the following sources.
**
**
**
External links
Chromium isotopes data from ''The Berkeley Laboratory Isotopes Project's''
{{Navbox element isotopes
Chromium
Chromium
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.
Chromium metal is valued for its high corrosion resistance and hardne ...