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Chivinar is a high Late
Miocene The Miocene ( ) is the first geological epoch of the Neogene Period and extends from about (Ma). The Miocene was named by Scottish geologist Charles Lyell; the name comes from the Greek words (', "less") and (', "new") and means "less recent" ...
volcano A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates ...
in Northwest Argentina. The volcano is noted for having erupted
rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained ( aphanitic) in texture, but may be porphyritic, containing larger mineral crystals ( phenocrysts) in an otherwise fine-grained groundmass. The min ...
s containing
topaz Topaz is a silicate mineral of aluminium and fluorine with the chemical formula Al Si O( F, OH). It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can ma ...
in its early stage of evolution, the only known occurrence of such in South America. This topaz did form during the crystallization of the magma in a fluorine-rich phase thereof at low temperatures and pressures. The topazes reach sizes of . The topaz bearing rocks cover a surface area of that is interrupted by a lava flow. Much older
granitoid A granitoid is a generic term for a diverse category of coarse-grained igneous rocks that consist predominantly of quartz, plagioclase, and alkali feldspar. Granitoids range from plagioclase-rich tonalites to alkali-rich syenites and from quartz ...
bodies also lie in the area and are 502-425 million years old. The volcano has been constructed in three main phases. First, a set of rhyolite
lava dome In volcanology, a lava dome is a circular mound-shaped protrusion resulting from the slow extrusion of viscous lava from a volcano. Dome-building eruptions are common, particularly in convergent plate boundary settings. Around 6% of eruption ...
s and plugs was erupted and formed a platform beneath the edifice without evidence of explosive activity or caldera formation. This unit appears on the northern and western flanks of the volcano between and form about one third of the total volume, with the domes ranging in width and in height. They are heavily hydrothermally altered and deformed. A gap during which tectonic and climatic degradation of the earlier domes occurred separates this stage from the next. Subsequently, destruction of domes during eruptions generated a unit consisting of coarse
dacite Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained ( aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhy ...
in
pumice Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular v ...
and
breccia Breccia () is a rock composed of large angular broken fragments of minerals or rocks cemented together by a fine-grained matrix. The word has its origins in the Italian language, in which it means "rubble". A breccia may have a variety of d ...
form spreading out from the centre. On top of this unit, an andesitic cone formed, dated at 9
mya Mya may refer to: Brands and product names * Mya (program), an intelligent personal assistant created by Motorola * Mya (TV channel), an Italian Television channel * Midwest Young Artists, a comprehensive youth music program Codes * Burmese ...
. Some aphyric phenobasalts cover surfaces of the second unit. The early phase rhyolites contain
alkali feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldsp ...
(49±2% volume),
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...
containing
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
(14±3% volume) and
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
(36±2% volume). A number of gas rich inclusions and accessory minerals are also present, including topaz,
xenotime Xenotime is a rare-earth phosphate mineral, the major component of which is yttrium orthophosphate ( Y P O4). It forms a solid solution series with chernovite-(Y) ( Y As O4) and therefore may contain trace impurities of arsenic, as well as si ...
and
zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of th ...
. Hydrothermally altered rhyolites contain
rutile Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at visible wa ...
and secondary silicates in veins. All products are porphyritic, including the late andesites which contain
phenocryst 300px, Swiss side of the Mont Blanc massif, has large white plagioclase phenocrysts, triclinic minerals that give trapezoid shapes when cut through). 1 euro coins, 1 euro coin (diameter 2.3 cm) for scale. A phenocryst is an early forming, relati ...
s of
hornblende Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic ro ...
and
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...
with smaller amounts of
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more alum ...
,
clinopyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
,
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of w ...
s and
orthopyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
. Based on crystal analysis, the rhyolites were stored at pressures of and temperatures of . The volcano is situated at the point where the main
volcanic arc A volcanic arc (also known as a magmatic arc) is a belt of volcanoes formed above a subducting oceanic tectonic plate, with the belt arranged in an arc shape as seen from above. Volcanic arcs typically parallel an oceanic trench, with the arc ...
intersects the ''Calama–Olacapato–El Toro lineament'', a
fault zone In geology, a fault is a Fracture (geology), planar fracture or discontinuity in a volume of Rock (geology), rock across which there has been significant displacement as a result of rock-mass movements. Large faults within Earth's crust (geolo ...
that has formed over fifteen million years a number of volcanic structures including lava domes, stratovolcanoes and monogenetic scoria cones. This fault system has imparted the Chivinar centre an extensional characteristic. The Chivinar centre itself formed over an
Eocene The Eocene ( ) Epoch is a geological epoch that lasted from about 56 to 33.9 million years ago (mya). It is the second epoch of the Paleogene Period in the modern Cenozoic Era. The name ''Eocene'' comes from the Ancient Greek (''ēṓs'', " ...
-Miocene basement containing evaporites and sediments.


References

Miocene volcanoes Volcanoes of Salta Province {{Volcanology-stub