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A chiral phenomenon is one that is not identical to its mirror image (see the article on mathematical chirality). The spin of a particle may be used to define a handedness, or helicity, for that particle, which, in the case of a massless particle, is the same as chirality. A symmetry transformation between the two is called parity transformation. Invariance under parity transformation by a Dirac fermion is called chiral symmetry.


Chirality and helicity

The helicity of a particle is positive ("right-handed") if the direction of its spin is the same as the direction of its motion. It is negative ("left-handed") if the directions of spin and motion are opposite. So a standard clock, with its spin vector defined by the rotation of its hands, has left-handed helicity if tossed with its face directed forwards. Mathematically, ''helicity'' is the sign of the projection of the spin vector onto the momentum vector: "left" is negative, "right" is positive. The chirality of a particle is more abstract: It is determined by whether the particle transforms in a right- or left-handed representation of the Poincaré group. For massless particlesphotons,
gluon A gluon ( ) is a type of Massless particle, massless elementary particle that mediates the strong interaction between quarks, acting as the exchange particle for the interaction. Gluons are massless vector bosons, thereby having a Spin (physi ...
s, and (hypothetical) gravitons – chirality is the same as helicity; a given massless particle appears to spin in the same direction along its axis of motion regardless of point of view of the observer. For massive particles – such as
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
s, quarks, and neutrinos – chirality and helicity must be distinguished: In the case of these particles, it is possible for an observer to change to a reference frame that is moving faster than the spinning particle is, in which case the particle will then appear to move backwards, and its helicity (which may be thought of as "apparent chirality") will be reversed. * Helicity is a constant of motion, but it is not Lorentz invariant. * Chirality is Lorentz invariant, but is not a constant of motion: a massive left-handed spinor, when propagating, will evolve into a right handed spinor over time, and vice versa. A ''massless'' particle moves with the speed of light, so no real observer (who must always travel at less than the speed of light) can be in any reference frame in which the particle appears to reverse its relative direction of spin, meaning that all real observers see the same helicity. Because of this, the direction of spin of massless particles is not affected by a change of inertial reference frame (a Lorentz boost) in the direction of motion of the particle, and the sign of the projection (helicity) is fixed for all reference frames: The helicity of massless particles is a ''relativistic invariant'' (a quantity whose value is the same in all inertial reference frames) and always matches the massless particle's chirality. The discovery of neutrino oscillation implies that neutrinos have mass, leaving the photon as the only confirmed massless particle;
gluon A gluon ( ) is a type of Massless particle, massless elementary particle that mediates the strong interaction between quarks, acting as the exchange particle for the interaction. Gluons are massless vector bosons, thereby having a Spin (physi ...
s are expected to also be massless, although this has not been conclusively tested. Hence, these are the only two particles now known for which helicity could be identical to chirality, of which only the photon has been confirmed by measurement. All other observed particles have mass and thus may have different helicities in different reference frames.


Chiral theories

Particle physicists have only observed or inferred left-chiral
fermion In particle physics, a fermion is a subatomic particle that follows Fermi–Dirac statistics. Fermions have a half-integer spin (spin 1/2, spin , Spin (physics)#Higher spins, spin , etc.) and obey the Pauli exclusion principle. These particles i ...
s and right-chiral antifermions engaging in the charged weak interaction. In the case of the weak interaction, which can in principle engage with both left- and right-chiral fermions, only two left-handed
fermion In particle physics, a fermion is a subatomic particle that follows Fermi–Dirac statistics. Fermions have a half-integer spin (spin 1/2, spin , Spin (physics)#Higher spins, spin , etc.) and obey the Pauli exclusion principle. These particles i ...
s interact. Interactions involving right-handed or opposite-handed fermions have not been shown to occur, implying that the universe has a preference for left-handed chirality. This preferential treatment of one chiral realization over another violates parity, as first noted by Chien Shiung Wu in her famous experiment known as the Wu experiment. This is a striking observation, since parity is a symmetry that holds for all other fundamental interactions. Chirality for a Dirac fermion is defined through the operator , which has eigenvalues ±1; the eigenvalue's sign is equal to the particle's chirality: +1 for right-handed, −1 for left-handed. Any Dirac field can thus be projected into its left- or right-handed component by acting with the projection operators or on . The coupling of the charged weak interaction to fermions is proportional to the first projection operator, which is responsible for this interaction's parity symmetry violation. A common source of confusion is due to conflating the , chirality operator with the helicity operator. Since the helicity of massive particles is frame-dependent, it might seem that the same particle would interact with the weak force according to one frame of reference, but not another. The resolution to this paradox is that , for which helicity is not frame-dependent. By contrast, for massive particles, chirality is not the same as helicity, or, alternatively, helicity is not Lorentz invariant, so there is no frame dependence of the weak interaction: a particle that couples to the weak force in one frame does so in every frame. A theory that is asymmetric with respect to chiralities is called a chiral theory, while a non-chiral (i.e., parity-symmetric) theory is sometimes called a vector theory. Many pieces of the Standard Model of physics are non-chiral, which is traceable to anomaly cancellation in chiral theories. Quantum chromodynamics is an example of a vector theory, since both chiralities of all quarks appear in the theory, and couple to gluons in the same way. The electroweak theory, developed in the mid 20th century, is an example of a chiral theory. Originally, it assumed that neutrinos were massless, and assumed the existence of only left-handed neutrinos and right-handed antineutrinos. After the observation of neutrino oscillations, which implies that no fewer than two of the three neutrinos are massive, the revised theories of the electroweak interaction now include both right- and left-handed neutrinos. However, it is still a chiral theory, as it does not respect parity symmetry. The exact nature of the neutrino is still unsettled and so the electroweak theories that have been proposed are somewhat different, but most accommodate the chirality of neutrinos in the same way as was already done for all other fermions.


Chiral symmetry

Vector gauge theories with massless Dirac fermion fields exhibit chiral symmetry, i.e., rotating the left-handed and the right-handed components independently makes no difference to the theory. We can write this as the action of rotation on the fields: : \psi_\rightarrow e^\psi_  and  \psi_\rightarrow \psi_ or : \psi_\rightarrow \psi_  and   \psi_\rightarrow e^\psi_. With flavors, we have unitary rotations instead: . More generally, we write the right-handed and left-handed states as a projection operator acting on a spinor. The right-handed and left-handed projection operators are : P_ = \frac and : P_ = \frac Massive fermions do not exhibit chiral symmetry, as the mass term in the Lagrangian, , breaks chiral symmetry explicitly. Spontaneous chiral symmetry breaking may also occur in some theories, as it most notably does in quantum chromodynamics. The chiral symmetry transformation can be divided into a component that treats the left-handed and the right-handed parts equally, known as vector symmetry, and a component that actually treats them differently, known as axial symmetry. (cf. '' Current algebra''.) A scalar field model encoding chiral symmetry and its breaking is the chiral model. The most common application is expressed as equal treatment of clockwise and counter-clockwise rotations from a fixed frame of reference. The general principle is often referred to by the name chiral symmetry. The rule is absolutely valid in the
classical mechanics Classical mechanics is a Theoretical physics, physical theory describing the motion of objects such as projectiles, parts of Machine (mechanical), machinery, spacecraft, planets, stars, and galaxies. The development of classical mechanics inv ...
of Newton and Einstein, but results from quantum mechanical experiments show a difference in the behavior of left-chiral versus right-chiral subatomic particles.


Example: u and d quarks in QCD

Consider quantum chromodynamics (QCD) with two ''massless'' quarks and (massive fermions do not exhibit chiral symmetry). The Lagrangian reads : \mathcal = \overline\,i\displaystyleD \,u + \overline\,i\displaystyleD\, d + \mathcal_\mathrm~. In terms of left-handed and right-handed spinors, it reads : \mathcal = \overline_\,i\displaystyleD \,u_ + \overline_\,i\displaystyleD \,u_ + \overline_\,i\displaystyleD \,d_ + \overline_\,i\displaystyleD \,d_ + \mathcal_\mathrm ~. (Here, is the imaginary unit and \displaystyleD the Dirac operator.) Defining : q = \begin u \\ d \end , it can be written as : \mathcal = \overline_\,i\displaystyleD \,q_ + \overline_\,i\displaystyleD\, q_ + \mathcal_\mathrm ~. The Lagrangian is unchanged under a rotation of ''q''L by any 2×2 unitary matrix , and ''q''R by any 2×2 unitary matrix . This symmetry of the Lagrangian is called ''flavor chiral symmetry'', and denoted as . It decomposes into : \mathrm(2)_\text \times \mathrm(2)_\text \times \mathrm(1)_V \times \mathrm(1)_A ~. The singlet vector symmetry, , acts as : q_\text \rightarrow e^ q_\text \qquad q_\text \rightarrow e^ q_\text ~, and thus invariant under gauge symmetry. This corresponds to baryon number conservation. The singlet axial group transforms as the following global transformation : q_\text \rightarrow e^ q_\text \qquad q_\text \rightarrow e^ q_\text ~. However, it does not correspond to a conserved quantity, because the associated axial current is not conserved. It is explicitly violated by a quantum anomaly. The remaining chiral symmetry turns out to be spontaneously broken by a quark condensate \textstyle \langle \bar^a_\text q^b_\text \rangle = v \delta^ formed through nonperturbative action of QCD gluons, into the diagonal vector subgroup known as isospin. The Goldstone bosons corresponding to the three broken generators are the three pions. As a consequence, the effective theory of QCD bound states like the baryons, must now include mass terms for them, ostensibly disallowed by unbroken chiral symmetry. Thus, this chiral symmetry breaking induces the bulk of hadron masses, such as those for the nucleons — in effect, the bulk of the mass of all visible matter. In the real world, because of the nonvanishing and differing masses of the quarks, is only an approximate symmetry to begin with, and therefore the pions are not massless, but have small masses: they are pseudo-Goldstone bosons.


More flavors

For more "light" quark species, flavors in general, the corresponding chiral symmetries are , decomposing into : \mathrm(N)_\text \times \mathrm(N)_\text \times \mathrm(1)_V \times \mathrm(1)_A ~, and exhibiting a very analogous chiral symmetry breaking pattern. Most usually, is taken, the u, d, and s quarks taken to be light (the eightfold way), so then approximately massless for the symmetry to be meaningful to a lowest order, while the other three quarks are sufficiently heavy to barely have a residual chiral symmetry be visible for practical purposes.


An application in particle physics

In
theoretical physics Theoretical physics is a branch of physics that employs mathematical models and abstractions of physical objects and systems to rationalize, explain, and predict List of natural phenomena, natural phenomena. This is in contrast to experimental p ...
, the electroweak model breaks parity maximally. All its
fermion In particle physics, a fermion is a subatomic particle that follows Fermi–Dirac statistics. Fermions have a half-integer spin (spin 1/2, spin , Spin (physics)#Higher spins, spin , etc.) and obey the Pauli exclusion principle. These particles i ...
s are chiral Weyl fermions, which means that the charged weak gauge bosons W and W only couple to left-handed quarks and leptons. Some theorists found this objectionable, and so conjectured a GUT extension of the weak force which has new, high energy W′ and Z′ bosons, which ''do'' couple with right handed quarks and leptons: : \frac to : \frac. Here, (pronounced " left") is from above, while is the baryon number minus the lepton number. The electric charge formula in this model is given by : Q = T_ + T_ + \frac\,; where \ T_\ and \ T_\ are the left and right weak isospin values of the fields in the theory. There is also the chromodynamic . The idea was to restore parity by introducing a left-right symmetry. This is a group extension of \mathbb_2 (the left-right symmetry) by : \frac to the semidirect product : \frac \rtimes \mathbb_2\ . This has two connected components where \mathbb_2 acts as an automorphism, which is the composition of an involutive outer automorphism of with the interchange of the left and right copies of with the reversal of . It was shown by Mohapatra & Senjanovic (1975) that left-right symmetry can be spontaneously broken to give a chiral low energy theory, which is the Standard Model of Glashow, Weinberg, and Salam, and also connects the small observed neutrino masses to the breaking of left-right symmetry via the seesaw mechanism. In this setting, the chiral quarks : (3,2,1)_ and : \left(\bar,1,2\right)_ are unified into an irreducible representation ("irrep") : (3,2,1)_ \oplus \left(\bar,1,2\right)_\ . The leptons are also unified into an irreducible representation : (1,2,1)_ \oplus (1,1,2)_\ . The Higgs bosons needed to implement the breaking of left-right symmetry down to the Standard Model are : (1,3,1)_2 \oplus (1,1,3)_2\ . This then provides three sterile neutrinos which are perfectly consistent with neutrino oscillation data. Within the seesaw mechanism, the sterile neutrinos become superheavy without affecting physics at low energies. Because the left–right symmetry is spontaneously broken, left–right models predict domain walls. This left-right symmetry idea first appeared in the Pati–Salam model (1974) and Mohapatra–Pati models (1975).


Chirality in materials science

Chirality in other branches of physics is often used for classifying and studying the properties of bodies and materials under external influences. Classification by chirality, as a special case of symmetry classification, allows for a better understanding of first-principles construction of
molecule A molecule is a group of two or more atoms that are held together by Force, attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemi ...
s, crystals, quasicrystals, and more. An example is the homochirality of amino acids in all known forms of
life Life, also known as biota, refers to matter that has biological processes, such as Cell signaling, signaling and self-sustaining processes. It is defined descriptively by the capacity for homeostasis, Structure#Biological, organisation, met ...
, which can be reproduced in physical experiments under external influence. Optical activity (including
circular dichroism Circular dichroism (CD) is dichroism involving circular polarization, circularly polarized light, i.e., the differential Absorption (electromagnetic radiation), absorption of left- and right-handed light. Left-hand circular (LHC) and right-hand ci ...
and magnetic circular dichroism) of materials is determined by their chirality. Chiral physical systems are characterized by the absence of invariance under the parity operator. An ambiguity arises in defining chirality in physics depending on whether one compares directions of motion using the reflection or spatial inversion operation. Accordingly, one distinguishes between "true" chirality (which is invariant under the time-reversal operation) and "false" chirality (non-invariant under time reversal). Many physical quantities change sign under the time-reversal operation (e.g.,
velocity Velocity is a measurement of speed in a certain direction of motion. It is a fundamental concept in kinematics, the branch of classical mechanics that describes the motion of physical objects. Velocity is a vector (geometry), vector Physical q ...
, power,
electric current An electric current is a flow of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is defined as the net rate of flow of electric charge through a surface. The moving particles are called charge c ...
, magnetization). Accordingly, "false" chirality is so typical in physics that the term can be misleading, and it is clearer to speak of T-invariant and T-non-invariant chirality. Effects related to chirality are described using pseudoscalar or axial vector physical quantities in general, and particularly, in magnetically ordered media, are described using time-direction-dependent chirality. This approach is formalized using dichromatic symmetry groups. T-invariant chirality corresponds to the absence in the symmetry group of any symmetry operations that include spatial inversion \bar or reflection m, according to international notation. The criterion for T-non-invariant chirality is the presence of these symmetry operations, but only when combined with time reversal 1', such as operations m′ or \bar'. At the level of atomic structure of materials, one distinguishes vector, scalar, and other types of chirality depending on the direction/sign of triple and vector products of spins.


See also

* Electroweak theory *
Chirality (chemistry) In chemistry, a molecule or ion is called chiral () if it cannot be superposed on its mirror image by any combination of rotation (geometry), rotations, translation (geometry), translations, and some Conformational isomerism, conformational cha ...
* Chirality (mathematics) * Chiral symmetry breaking * Handedness * Spinors * * Sigma model * Chiral model


Notes


References

* * * *


External links


History of science: parity violation

Helicity, Chirality, Mass, and the Higgs
(Quantum Diaries blog)

(Robert D. Klauber) {{DEFAULTSORT:Chirality (Physics) Quantum field theory Quantum chromodynamics Symmetry Chirality