Chemical Accident
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A chemical accident is the unintentional release of one or more
hazardous chemicals A hazard is a potential source of harm. Substances, events, or circumstances can constitute hazards when their nature would potentially allow them to cause damage to health, life, property, or any other interest of value. The probability of that ...
, which could harm human health and the environment. Such events include fires,
explosion An explosion is a rapid expansion in volume of a given amount of matter associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Explosions may also be generated ...
s, and release of
toxic Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a subst ...
materials that may cause people illness, injury, or disability. Chemical accidents can be caused for example by
natural disaster A natural disaster is the very harmful impact on a society or community brought by natural phenomenon or Hazard#Natural hazard, hazard. Some examples of natural hazards include avalanches, droughts, earthquakes, floods, heat waves, landslides ...
s,
human error Human error is an action that has been done but that was "not intended by the actor; not desired by a set of rules or an external observer; or that led the task or system outside its acceptable limits".Senders, J.W. and Moray, N.P. (1991) Human Er ...
, or deliberate acts for personal gain. Chemical accidents are generally understood to be industrial-scale ones, often with important offsite consequences. Unintended exposure to chemicals that occur at smaller work sites, as well as in private premises during everyday activities are usually not referred to as chemical accidents.
Process safety Process safety is an interdisciplinary engineering domain focusing on the study, prevention, and management of large-scale fires, explosions and chemical accidents (such as toxic gas clouds) in process plants or other facilities dealing with haza ...
is the engineering discipline dealing with chemical accident hazards understanding and management. Process safety's scope extends however to fires and explosions from hazardous materials generally not referred to as 'chemicals', such as refined and unrefined
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually fain ...
mixtures.


Frequency


United States

Chemical accidents are relatively common in the United States, with a significant accident occurring on average multiple times per week. Most chemical accidents never make national headline news. American chemical industry public relations professionals claim that such accidents are becoming less frequent but the U.S. Environmental Protection Agency states that they are increasing in frequency, with higher average annual rates of population evacuations and of people needing medical treatment resulting from chemical accidents. Texas is the leading U.S. state in chemical accidents.


United Kingdom

The
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Northwestern Europe, off the coast of European mainland, the continental mainland. It comprises England, Scotlan ...
responds to around 1,000 chemical incidents per year, the majority of these were relatively short-lived fires. Majority of the large-scale incidents occurred at industrial, commercial, and agricultural sites. These large-scale fires do cause significant amounts of damage however the after math can be worse by releasing toxic smoke, asbestos, and other potential hazards chemicals. Many of the UK's chemical hazard analysis and statistics are funded by the HPRUs or the health protection research units.


China

Since 2015 to 2021 China has experienced 295 chemical accidents which had led to the deaths of 1325 people. The areas most affected in China are those with low GDP such as
Shandong Shandong is a coastal Provinces of China, province in East China. Shandong has played a major role in Chinese history since the beginning of Chinese civilization along the lower reaches of the Yellow River. It has served as a pivotal cultural ...
,
Tianjin Tianjin is a direct-administered municipality in North China, northern China on the shore of the Bohai Sea. It is one of the National Central City, nine national central cities, with a total population of 13,866,009 inhabitants at the time of the ...
,
Jiangsu Jiangsu is a coastal Provinces of the People's Republic of China, province in East China. It is one of the leading provinces in finance, education, technology, and tourism, with its capital in Nanjing. Jiangsu is the List of Chinese administra ...
, and
Hebei Hebei is a Provinces of China, province in North China. It is China's List of Chinese administrative divisions by population, sixth-most populous province, with a population of over 75 million people. Shijiazhuang is the capital city. It bor ...
Provinces. Out of the providences precisely mentioned from 2016 to 2021 chemical accident and casualties have been an upward trend.


Examples


Bhopal Accident

The most dangerous chemical accident recorded in history was the 1984 Bhopal gas tragedy in
India India, officially the Republic of India, is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area; the List of countries by population (United Nations), most populous country since ...
, in which more than 3,000 people died after highly toxic
methyl isocyanate Methyl isocyanate (MIC) is an organic compound with the molecular formula CH3NCO. Synonyms are isocyanatomethane and methyl carbylamine. Methyl isocyanate is an intermediate chemical in the production of carbamate pesticides and Haffmann Bromam ...
was released at a
Union Carbide Union Carbide Corporation (UCC) is an American chemical company headquartered in Seadrift, Texas. It has been a wholly owned subsidiary of Dow Chemical Company since 2001. Union Carbide produces chemicals and polymers that undergo one or more f ...
pesticide Pesticides are substances that are used to control pests. They include herbicides, insecticides, nematicides, fungicides, and many others (see table). The most common of these are herbicides, which account for approximately 50% of all p ...
s factory. The release happened after the storage tank safety valve had failed to contain the excess
pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
created by the
exothermic reaction In thermochemistry, an exothermic reaction is a "reaction for which the overall standard enthalpy change Δ''H''⚬ is negative." Exothermic reactions usually release heat. The term is often confused with exergonic reaction, which IUPAC define ...
between water and
methyl isocyanate Methyl isocyanate (MIC) is an organic compound with the molecular formula CH3NCO. Synonyms are isocyanatomethane and methyl carbylamine. Methyl isocyanate is an intermediate chemical in the production of carbamate pesticides and Haffmann Bromam ...
. The accident was caused by a faulty valve that let the water into the tank. The safety refrigeration unit for the tank also was not functional since it did not have any coolant.


Beirut Accident

The
2020 Beirut explosion On 4 August 2020, a major explosion occurred in Beirut, Lebanon, triggered by the ignition of 2,750 tonnes of ammonium nitrate. The chemical, confiscated in 2014 from the cargo ship and stored at the Port of Beirut without adequate safety me ...
was one of the biggest non-nuclear
explosion An explosion is a rapid expansion in volume of a given amount of matter associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Explosions may also be generated ...
s in history. It happened when approximately 2,750 tons of
ammonium nitrate Ammonium nitrate is a chemical compound with the formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, but does not form hydrates. It is predominantly us ...
inside a warehouse at the port exploded. The improper storage alongside a fire breaking out near the warehouse caused the explosion. The explosion killed 218 people, injured 7,000, and displaced 300,000 people.


Tianjin Explosion China

Two chemical explosions occurred in a warehouse at a port in Tianjin China which contained flammable chemicals such as
calcium carbide Calcium carbide, also known as calcium acetylide, is a chemical compound with the chemical formula of . Its main use industrially is in the production of acetylene and calcium cyanamide. The pure material is colorless, while pieces of technica ...
. Chinese officials have still yet to identify the direct cause of the explosion however officials have stated the likely cause is that the calcium carbide mixed with water and an explosion occurred. The explosion was the equivalent to three tons of
TNT Troponin T (shortened TnT or TropT) is a part of the troponin complex, which are proteins integral to the contraction of skeletal and heart muscles. They are expressed in skeletal and cardiac myocytes. Troponin T binds to tropomyosin and helps ...
where the second explosion had the power of 21 tons of TNT. The explosion destroyed a significant portion of the surrounding port, tossing shipping containers. 720 people were taken to the hospital and out of the 720, 60 were critically injured. The people living in the surrounding area had to evacuate their homes and were moved to local schools.


Regulation and government agencies


European Union

In the
European Union The European Union (EU) is a supranational union, supranational political union, political and economic union of Member state of the European Union, member states that are Geography of the European Union, located primarily in Europe. The u ...
, incidents such as the Flixborough disaster and the Seveso disaster led to legislation such as the Seveso Directive, which mandates safety reports to be prepared by process and storage plants and issued to local and regional authorities.


United States

In the
United States The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
, concern about chemical accidents after the Bhopal disaster led to the passage of the 1986
Emergency Planning and Community Right-to-Know Act The Emergency Planning and Community Right-to-Know Act of 1986 is a United States federal law passed by the 99th United States Congress located at Title 42, Chapter 116 of the U.S. Code, concerned with emergency response preparedness. On Octobe ...
. The EPCRA requires local
emergency An emergency is an urgent, unexpected, and usually dangerous situation that poses an immediate risk to health, life, property, or environment and requires immediate action. Most emergencies require urgent intervention to prevent a worsening ...
planning efforts throughout the country, including emergency notifications. The law also requires companies to make publicly available information about their storage of toxic chemicals. Based on such information, citizens can identify the vulnerable zones in which severe toxic releases could cause harm or even in some cases death. Alongside the EPCRA two other government regulations were formed the
Process Safety Management Process safety management (PSM) is a practice to manage business operations critical to process safety. It can be implemented using the established OSHA scheme or others made available by the EPA, AIChE's Center for Chemical Process Safety, or ...
and the Risk Management Plans. These agencies help with the control and management of chemical accidents however the differ slightly from each other. PSM focuses on protecting workers and employees that can potentially be exposed and is run by
OSHA The Occupational Safety and Health Administration (OSHA; ) is a regulatory agency of the United States Department of Labor that originally had federal visitorial powers to inspect and examine workplaces. The United States Congress established ...
. The RMP focuses on the outside community and environment and is controlled by the EPA. In 1990 the Chemical Safety and Hazard Investigation Board (CSB) was established by
Congress A congress is a formal meeting of the representatives of different countries, constituent states, organizations, trade unions, political parties, or other groups. The term originated in Late Middle English to denote an encounter (meeting of ...
, though it did not become operational until 1998. The Board's mission is to determine the root causes of chemical accidents and issue safety recommendations to prevent future chemical accidents. Note that the CSB does not issue fines or citations since the Congress designed the agency to be non-regulatory. It also organizes workshops on a number of issues related to preparing for, preventing, and responding to chemical accidents.


United Nations

To prevent Chemical Accidents around the Globe the
United Nations The United Nations (UN) is the Earth, global intergovernmental organization established by the signing of the Charter of the United Nations, UN Charter on 26 June 1945 with the stated purpose of maintaining international peace and internationa ...
has put forth many regulatory and precautionary action thru their environmental protection branch. They have put forth the process of CAPP, Chemical Action Prevention and Preparedness. The three main goals of CAPP are to increase countries' understanding of chemical accidents, Increase the capabilities of environmental agencies in other countries, and help countries develop their own CAPP programs.


United Kingdom

The
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Northwestern Europe, off the coast of European mainland, the continental mainland. It comprises England, Scotlan ...
has one agency specializing in chemical exposures the UKHSA, their priority is to identify and strengthen capabilities relating to chemical exposures. The UKHSA has two tools the NSRA, National Security Risk Assessment and the NRR, National Risk Register both these agencies identify chemical hazards and risk which helps inform the UKHSA.


China

Chinas chemical industry is a trillion-dollar industry, and it has been the world's largest since 2011. Many different industrial chemicals have been shifted thru China increasing the risk and severity of chemical accidents, so China devolved the China Chemical Safety and Technology Association. This agency was in charge of Chinas chemical industry however as the need for more specialized assistance became required the agency became the China Chemical Safety Association. This agency solely focuses on chemical accidents and their effects.


See also

*
Chemical safety Chemical safety includes all safety policies, procedures and practices designed to minimize the risk of exposure to potentially hazardous chemicals. This includes the risks of exposure to persons handling the chemicals, to the surrounding environme ...
*
Process safety Process safety is an interdisciplinary engineering domain focusing on the study, prevention, and management of large-scale fires, explosions and chemical accidents (such as toxic gas clouds) in process plants or other facilities dealing with haza ...
*
Process safety management Process safety management (PSM) is a practice to manage business operations critical to process safety. It can be implemented using the established OSHA scheme or others made available by the EPA, AIChE's Center for Chemical Process Safety, or ...


References


External links


24-7 ResponseBrandweerinformatiecentrum voor gevaarlijke stoffen/Fire services information centre for dangerous goods (Dutch organization, English site)


** ttps://web.archive.org/web/20070622111345/http://www2.oecd.org/guidingprinciples/index.asp Guiding Principles for Chemical Accident Prevention, Preparedness and Responsebr>Preventing Chemical Accidents – How to Prevent Chemicals From Contaminating Your Workplace – Safety Storage Systems

U.S. Chemical Safety Board
{{DEFAULTSORT:Chemical Accident Process safety Chemical hazards Industrial fires and explosions