Charles Goodyear (December 29, 1800 – July 1, 1860) was an American
self-taught chemist
A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a graduated scientist trained in the study of chemistry, or an officially enrolled student in the field. Chemists study the composition of ...
and
manufacturing engineer
Manufacturing engineering or production engineering is a branch of professional engineering that shares many common concepts and ideas with other fields of engineering such as mechanical, chemical, electrical, and industrial engineering.
Manufac ...
who developed
vulcanized rubber, for which he received patent number 3633 from the
United States Patent Office
The United States Patent and Trademark Office (USPTO) is an agency in the U.S. Department of Commerce that serves as the national patent office and trademark registration authority for the United States. The USPTO's headquarters are in Ale ...
on June 15, 1844.
Goodyear is credited with inventing the chemical process to create and manufacture pliable, waterproof, moldable rubber.
Goodyear's discovery of the vulcanization process followed five years of searching for a more stable rubber and stumbling upon the effectiveness of heating after
Thomas Hancock. His discovery initiated decades of successful rubber manufacturing in the
Lower Naugatuck Valley in Connecticut, as rubber was adopted to multiple applications, including footwear and tires. The
Goodyear Tire and Rubber Company
The Goodyear Tire & Rubber Company is an American multinational tire manufacturer headquartered in Akron, Ohio. Goodyear manufactures tires for passenger vehicles, aviation, commercial trucks, military and police vehicles, motorcycles, recreati ...
is named after (though not founded by) him.
Early life
Charles Goodyear was born on December 29, 1800, in
New Haven, Connecticut
New Haven is a city of the U.S. state of Connecticut. It is located on New Haven Harbor on the northern shore of Long Island Sound. With a population of 135,081 as determined by the 2020 United States census, 2020 U.S. census, New Haven is List ...
, the son of Amasa Goodyear, and the oldest of six children. His father was a descendant of Stephen Goodyear, successor to Governor Eaton as the head of the company London Merchants, who founded the colony of
New Haven
New Haven is a city of the U.S. state of Connecticut. It is located on New Haven Harbor on the northern shore of Long Island Sound. With a population of 135,081 as determined by the 2020 U.S. census, New Haven is the third largest city in Co ...
in 1638.
Around 1817, Charles left his home and went to
Philadelphia
Philadelphia ( ), colloquially referred to as Philly, is the List of municipalities in Pennsylvania, most populous city in the U.S. state of Pennsylvania and the List of United States cities by population, sixth-most populous city in the Unit ...
to learn the hardware business.
He worked industriously until he was twenty-five years old, and then, returning to
Connecticut
Connecticut ( ) is a U.S. state, state in the New England region of the Northeastern United States. It borders Rhode Island to the east, Massachusetts to the north, New York (state), New York to the west, and Long Island Sound to the south. ...
, entered into a partnership in his father's business in
Naugatuck, CT where they manufactured not only
ivory
Ivory is a hard, white material from the tusks (traditionally from elephants) and Tooth, teeth of animals, that consists mainly of dentine, one of the physical structures of teeth and tusks. The chemical structure of the teeth and tusks of mamm ...
and metal buttons, but also a variety of agricultural supplements. He had siblings Nelson Goodyear, Henry Goodyear, Robert Goodyear, Harriet Goodyear Tomlinson, Amasa Goodyear, Jr.
Marriage and early career

On August 3, 1824, he married Clarissa Beecher, whom he met at his Congregational Church. Two years later the family moved to
Philadelphia
Philadelphia ( ), colloquially referred to as Philly, is the List of municipalities in Pennsylvania, most populous city in the U.S. state of Pennsylvania and the List of United States cities by population, sixth-most populous city in the Unit ...
, and there Charles Goodyear opened a hardware store. This is where he did most of his work. His specialties were the valuable agricultural implements that his firm had been manufacturing, and after the first distrust of domestically made goods had worn away—for all agricultural implements were imported from England at that time—he found himself heading a successful business.
This continued to increase until it seemed that he was to be a wealthy man. Between 1829 and 1830 he broke down in health, being troubled with
dyspepsia
Indigestion, also known as dyspepsia or upset stomach, is a condition of impaired digestion. Symptoms may include upper abdominal fullness, heartburn, nausea, belching, or upper abdominal pain. People may also experience feeling full earlier ...
. At the same time, the failure of a number of business endeavors seriously embarrassed his firm. They struggled on, however, for some time, but were finally obliged to fail.
Between the years 1831 and 1832, Goodyear heard about
gum elastic (natural rubber) and examined every article that appeared in the newspapers relative to this new material. The Roxbury Rubber Company, of
Boston
Boston is the capital and most populous city in the Commonwealth (U.S. state), Commonwealth of Massachusetts in the United States. The city serves as the cultural and Financial centre, financial center of New England, a region of the Northeas ...
, had been for some time experimenting with the gum, and believed it had found means for manufacturing goods from it. It had a large plant and was sending its goods all over the country. It was some of Roxbury's goods that first attracted Goodyear's attention. Soon after this, Goodyear visited New York, and his attention went to
life preservers, and it struck him that the tube used for inflation was not very effective nor well-made. Therefore, upon returning to Philadelphia, he made tubes and brought them back to New York and showed them to the manager of the
Roxbury Rubber Company.
The manager was pleased with the ingenuity that Goodyear had shown in manufacturing the tubes. He confessed to Goodyear that the business was on the verge of ruin and that his products had to be tested for a year before it could be determined if they were perfect or not. To their surprise, goods that they had determined to be of good quality were being returned, the gum having rotted, making them useless. Goodyear at once made up his mind to experiment on this gum and see if he could overcome the problems with these rubber products.
However, when he returned to
Philadelphia
Philadelphia ( ), colloquially referred to as Philly, is the List of municipalities in Pennsylvania, most populous city in the U.S. state of Pennsylvania and the List of United States cities by population, sixth-most populous city in the Unit ...
, a creditor had him arrested and imprisoned. While there, he tried his first experiments with
India rubber. The gum was inexpensive then, and by heating it and working it in his hands, he managed to incorporate in it a certain amount of
magnesia which produced a white compound that appeared to take away the stickiness.
He thought he had discovered the secret, and through the kindness of friends was able to improve his invention in New Haven. The first thing that he made was shoes, and he used his own house for grinding, calendering and vulcanizing, with the help of his wife and children. His compound at this time consisted of India rubber,
lampblack
Carbon black (with subtypes acetylene black, channel black, furnace black, lamp black and thermal black) is a material produced by the incomplete combustion of coal tar, vegetable matter, or petroleum products, including fuel oil, fluid catalyt ...
, and magnesia, the whole dissolved in
turpentine
Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthine, terebenthene, terebinthine and, colloquially, turps) is a fluid obtainable by the distillation of resin harvested from living trees, mainly pines. Principall ...
and spread upon the flannel cloth which served as the lining for the shoes. It was not long, however, before he discovered that the gum, even treated this way, became sticky. His creditors, completely discouraged, decided that he would not be allowed to go further in his research.
Goodyear, however, had no mind to stop here in his experiments. Selling his furniture and placing his family in a quiet boarding place, he went to New York and, helped by a friendly druggist, continued his experiments in an attic. His next step was to compound the rubber with magnesia and then boil it in
quicklime
Calcium oxide (formula: Ca O), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term '' lime'' connotes calcium-containin ...
and water. This appeared to solve the problem. At once it was noticed abroad that he had treated India Rubber to lose its stickiness, and he received international acclamation. He seemed on the high road to success, until, one day, he noticed that a drop of weak
acid
An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis ...
, falling on the cloth, neutralized the
alkali
In chemistry, an alkali (; from the Arabic word , ) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The a ...
and immediately caused the rubber to become soft again. This proved to him that his process was not a successful one. He therefore continued experimenting, and after preparing his mixtures in his attic in New York, would walk three miles to a mill in
Greenwich Village
Greenwich Village, or simply the Village, is a neighborhood on the west side of Lower Manhattan in New York City, bounded by 14th Street (Manhattan), 14th Street to the north, Broadway (Manhattan), Broadway to the east, Houston Street to the s ...
to try various experiments.
In the line of these, he discovered that rubber dipped in
nitric acid
Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most com ...
formed a surface cure, and he made many products with this acid cure which were held in high regard, and he even received a letter of commendation from
Andrew Jackson
Andrew Jackson (March 15, 1767 – June 8, 1845) was the seventh president of the United States from 1829 to 1837. Before Presidency of Andrew Jackson, his presidency, he rose to fame as a general in the U.S. Army and served in both houses ...
.
Exposure to harsh
chemical
A chemical substance is a unique form of matter with constant chemical composition and characteristic properties. Chemical substances may take the form of a single element or chemical compounds. If two or more chemical substances can be combin ...
s, such as nitric acid and
lead oxide
Lead oxides are a group of inorganic compounds with formulas including lead (Pb) and oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), gr ...
, adversely affected his health. Once, he nearly suffocated himself by gas generated in his laboratory. Goodyear survived, but the resulting fever came close to taking his life.
Together with an old business partner, he built up a factory and began to make clothing, life preservers, rubber shoes, and a great variety of rubber goods. They also had a large factory with special machinery, built at
Staten Island
Staten Island ( ) is the southernmost of the boroughs of New York City, five boroughs of New York City, coextensive with Richmond County and situated at the southernmost point of New York (state), New York. The borough is separated from the ad ...
, where he moved his family and again had a home of his own. Just about this time, when everything looked bright, the
panic of 1837
The Panic of 1837 was a financial crisis in the United States that began a major depression (economics), depression which lasted until the mid-1840s. Profits, prices, and wages dropped, westward expansion was stalled, unemployment rose, and pes ...
came and swept away the entire fortune of his associate and left Goodyear penniless.
His next move was to go to Boston, where he became acquainted with J. Haskins, of the Roxbury Rubber Company. Goodyear found him to be a good friend, who lent him money and stood by him when no one would have anything to do with the visionary inventor. A man named Mr. Chaffee was also exceedingly kind and ever ready to lend a listening ear to his plans, and to also assist him in a pecuniary way. About this time it occurred to Mr. Chaffee that much of the trouble that they had experienced in working India Rubber might come from the solvent that was used. He therefore invented a huge machine for doing the mixing by mechanical means. The goods that were made in this way were beautiful to look at, and it appeared, as it had before, that all difficulties were overcome.
Goodyear discovered a new method for making rubber shoes and received a patent which he sold to the Providence Company in
Rhode Island
Rhode Island ( ) is a state in the New England region of the Northeastern United States. It borders Connecticut to its west; Massachusetts to its north and east; and the Atlantic Ocean to its south via Rhode Island Sound and Block Is ...
. However, a method had not yet been found to process rubber so that it would withstand hot and cold temperatures and acids, and so the rubber goods were constantly growing sticky, decomposing and being returned to the manufacturers.
Perfection and patent of vulcanization
From 1834 through 1839, Goodyear worked anywhere he could find investors, and often moved locations, mostly within New York, Massachusetts, Philadelphia, and Connecticut. In 1839, Goodyear was at the Eagle India Rubber Company in
Woburn, Massachusetts
Woburn ( ) is a city in Middlesex County, Massachusetts, Middlesex County, Massachusetts, United States. The population was 40,876 at the 2020 United States census, 2020 census. Woburn is located north of Boston. Woburn uses Massachusetts' ...
, where he discovered that combining rubber and sulfur over a hot stove caused the rubber to become rigid, a process which he called
vulcanization
Vulcanization (British English: vulcanisation) is a range of processes for hardening rubbers. The term originally referred exclusively to the treatment of natural rubber with sulfur, which remains the most common practice. It has also grown to ...
because of the heat involved. For this Goodyear received US patent number 1090 on February 24 of the same year.
Several years earlier, Goodyear had started a small factory at
Springfield, Massachusetts
Springfield is the most populous city in Hampden County, Massachusetts, United States, and its county seat. Springfield sits on the eastern bank of the Connecticut River near its confluence with three rivers: the western Westfield River, the ea ...
, to which he moved his primary operations in 1842. The factory was run largely by Nelson and his brothers. Charles Goodyear's brother-in-law, Mr. De Forest, a wealthy woolen manufacturer became involved as well. The work of making the invention practical was continued. In 1844, the process was sufficiently perfected and Goodyear received US patent number 3633, which mentions New York but not Springfield. Also in 1844, Goodyear's brother Henry introduced mechanical mixing of the mixture in place of the use of solvents. Goodyear sold some of these patents to
Hiram Hutchinson who founded
Hutchinson SA in France in 1853.
Court cases regarding vulcanization
In the year 1852, Goodyear went to Europe, a trip that he had long planned, and saw
Thomas Hancock, then in the employ of
Charles Macintosh
Charles Macintosh FRS (29 December 1766 – 25 July 1843) was a Scottish chemist and the inventor of the modern waterproof raincoat. The Mackintosh raincoat (the variant spelling is now standard) is named after him.
Biography
Macintosh was ...
& Company. Hancock claimed to have invented vulcanization independently, and received a British patent, initiated in 1843, but finalized in 1844. In 1855, in the last of three patent disputes with fellow British rubber pioneer,
Stephen Moulton, Hancock's patent was challenged with the claim that Hancock had copied Goodyear. Goodyear attended the trial. If Hancock lost, Goodyear stood to have his own British patent application granted, allowing him to claim royalties from both Hancock and Moulton. Both had examined Goodyear's vulcanized rubber in 1842, but several chemists testified that it would not have been possible to determine how it was made by studying it. Hancock prevailed.
Despite his misfortune with patents, Goodyear wrote, “In reflecting upon the past, as relates to these branches of industry, the writer is not disposed to repine, and say that he has planted, and others have gathered the fruits. The advantages of a career in life should not be estimated exclusively by the standard of dollars and cents, as is too often done. Man has just cause for regret when he sows and no one reaps.”
Death and legacy
Goodyear died on July 1, 1860, while traveling to see his dying daughter. After arriving in New York, he was informed that she had already died. He collapsed and was taken to the Fifth Avenue Hotel in New York City, where he died at the age of 59.
In 1898, almost four decades after his death, The
Goodyear Tire & Rubber Company was founded and named after Goodyear by
Frank Seiberling
Franklin Augustus "Frank" Seiberling (October 6, 1859 – August 11, 1955), also known as F.A. Seiberling, was an American innovator and entrepreneur best known for co-founding the Goodyear Tire & Rubber Company in 1898 and the Seiberling Rubber ...
.
On February 8, 1976, he was among six individuals selected for induction into the
National Inventors Hall of Fame
The National Inventors Hall of Fame (NIHF) is an American not-for-profit organization, founded in 1973, which recognizes individual engineers and inventors who hold a US patent of significant technology. Besides the Hall of Fame, it also operate ...
.
In
Woburn, Massachusetts
Woburn ( ) is a city in Middlesex County, Massachusetts, Middlesex County, Massachusetts, United States. The population was 40,876 at the 2020 United States census, 2020 census. Woburn is located north of Boston. Woburn uses Massachusetts' ...
, there is an elementary school named after him.
The Government of France made him a Chevalier de la Légion d'honneur in 1855.
The ACS Rubber Division awards a medal named in Goodyear's honor, the
Charles Goodyear Medal
The Charles Goodyear Medal is the highest honor conferred by the American Chemical Society#Organization, American Chemical Society, Rubber Division. Established in 1941, the award is named after Charles Goodyear, the discoverer of vulcanization, ...
. The medal honors principal inventors, innovators, and developers whose contributions resulted in a significant change to the nature of the rubber industry.
The
Goodyear welt, a technique in shoemaking, was named after and in honor of its inventor, Charles' son; Charles Goodyear Jr.
See also
*
Leverett Candee, first person to manufacture rubber footwear under the Goodyear vulcanization process.
*
William Henry Goodyear, his son
*
Goodyear Tire and Rubber Company
The Goodyear Tire & Rubber Company is an American multinational tire manufacturer headquartered in Akron, Ohio. Goodyear manufactures tires for passenger vehicles, aviation, commercial trucks, military and police vehicles, motorcycles, recreati ...
*
Vulcanization
Vulcanization (British English: vulcanisation) is a range of processes for hardening rubbers. The term originally referred exclusively to the treatment of natural rubber with sulfur, which remains the most common practice. It has also grown to ...
References
External links
*
The Charles Goodyear Story
– Goodyear's U.S. Patent No. 240: Improvement in the Process of Divesting Caoutchouc, Gum-Elastic, or India-Rubber of its Adhesive Properties, and also of Bleaching the Same, and Thereby Adapting it to Various Useful Purposes.
*
{{DEFAULTSORT:Goodyear, Charles
1800 births
1860 deaths
Businesspeople from New Haven, Connecticut
19th-century American inventors
American polymer scientists and engineers
People from Staten Island
Burials at Grove Street Cemetery
People of the American Industrial Revolution
American people of English descent
Engineers from New York (state)
19th-century American engineers
19th-century American businesspeople