Char cloth, also called char paper, is a material with low ignition temperature, used as
tinder
Tinder is easily Combustibility and flammability, combustible material used to Firemaking, start a fire. Tinder is a finely divided, open material which will begin to glow under a shower of sparks. Air is gently wafted over the glowing tinder unt ...
when lighting a fire. It is the main component in a
tinderbox. It is a small swatch of fabric made from a natural fibre (such as
linen
Linen () is a textile made from the fibers of the flax plant.
Linen is very strong and absorbent, and it dries faster than cotton. Because of these properties, linen is comfortable to wear in hot weather and is valued for use in garments. Lin ...
,
cotton
Cotton (), first recorded in ancient India, is a soft, fluffy staple fiber that grows in a boll, or protective case, around the seeds of the cotton plants of the genus '' Gossypium'' in the mallow family Malvaceae. The fiber is almost pure ...
,
jute
Jute ( ) is a long, rough, shiny bast fibre that can be Spinning (textiles), spun into coarse, strong threads. It is produced from flowering plants in the genus ''Corchorus'', of the mallow family Malvaceae. The primary source of the fiber is ...
etc.) that has been converted through
pyrolysis
Pyrolysis is a process involving the Bond cleavage, separation of covalent bonds in organic matter by thermal decomposition within an Chemically inert, inert environment without oxygen. Etymology
The word ''pyrolysis'' is coined from the Gree ...
.
Description
Char cloth looks like a black, fragile piece of cloth. It is usually made from swatches of organic fabrics, but similar tinder can be made in the same way using cotton balls or tampons, dried moss, leaves or fungus (
amadou for instance), raw unspun flax, etc. This is packed into a small, almost airtight, rectangular tin, then heated slowly and steadily over coals for a long period of time, allowing it to undergo thermal decomposition (aka, pyrolysis). The material that remains after this process is complete ignites very easily, making it the preferred tinder when lighting a fire using flint and steel.
Pyrolysis
Pyrolysis is a process involving the Bond cleavage, separation of covalent bonds in organic matter by thermal decomposition within an Chemically inert, inert environment without oxygen. Etymology
The word ''pyrolysis'' is coined from the Gree ...
is defined as "a
thermochemical decomposition of organic material at elevated temperatures in the absence of oxygen".
Essentially, pyrolysis is turning organic matter into
charcoal
Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, ca ...
, a low weight, high energy content, very easily ignited matter.
Fresh charcoal can even autoignite, even though its
autoignition temperature
The autoignition temperature or self-ignition temperature, often called spontaneous ignition temperature or minimum ignition temperature (or shortly ignition temperature) and formerly also known as kindling point, of a substance is the lowest tem ...
(349–455°C) is not that low (for instance, paper's is ); this is because, if even a small point ignites, it will generate more energy than lost, igniting the cloth around, so energy and temperature will build up until it turns red hot ember. The cloth usually does not produce enough gas for it to produce flames, but if close enough to something that can, a full fire will finally occur.
Technique
This material, when properly prepared, will ignite with the slightest spark and provides a slow burning, hot ember to build the fire around, making it very popular with campers; especially in harsh weather conditions when lighting a fire is more difficult. Applying the same principle that has been used throughout history by indigenous peoples, char cloth can start a fire with only the help of flint and steel, it is then placed in a tinder bundle and blown into flames.
It is easily made on a small scale, making it accessible and popular in the domestic sphere and while cooking on campfires.
When struck against steel, a flint edge produces sparks. 'The hard flint edge shaves off a particle of the steel that exposes iron, which reacts with
oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
from the atmosphere and can ignite the proper
tinder
Tinder is easily Combustibility and flammability, combustible material used to Firemaking, start a fire. Tinder is a finely divided, open material which will begin to glow under a shower of sparks. Air is gently wafted over the glowing tinder unt ...
'. With this flint and steel technique the char cloth will ignite and an "ember will flash through it" allowing for a flame to be built around the ember. Although the char cloth is slow burning, the spark will need to be fostered using small kindling materials such as dried leaves, small twigs or a tinder bundle.
Historical uses

Char cloths have been used to light fires for centuries.
One of the earliest recorded uses of a char cloth dates back to a
ninjutsu
, and are terms for the techniques and skills used by spies and scouts in pre-modern Japan known as ninja. Some of these techniques are recorded in ninja scrolls, some which have been published and translated. The study of these scrolls have c ...
manual written by
Hattori Hanzō in 1560 called the Ninpiden or Shinobi Hiden, or Legends of Ninja Secrets. The manual states how to make char cloth from either cotton, silk or paper.
"Crumple cotton, silk, or paper until it is soft. Divide it into small amounts, and dry-roast it until it is black, paying attention that it doesn't burn white. Keep it within a tightly covered container and be sure to always have some at hand."
Another use of char cloth was recorded by C. P. Mountford and R. M. Berndt in Making Fire by Percussion, where the introduction of char cloth to Australian Indigenous Aboriginals is detailed, saying the use of char cloth was easier than traditional methods.
Char cloth has also been noted as used by the indigenous people of Hawaii in 1940. In the Hawaiian Journal of History, when describing the smoking habits of the islanders, the use of char cloth to light tobacco is briefly mentioned as a method introduced by colonists to the Hawaiian people. "This was not a traditional Hawaiian way of starting fires but was the flint and steel method introduced from the West."
Scientific Investigation
The production of char cloth occurs when organic
cellulose
Cellulose is an organic compound with the chemical formula, formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of glycosidic bond, β(1→4) linked glucose, D-glucose units. Cellulose is an important s ...
based fibres undergo
pyrolysis
Pyrolysis is a process involving the Bond cleavage, separation of covalent bonds in organic matter by thermal decomposition within an Chemically inert, inert environment without oxygen. Etymology
The word ''pyrolysis'' is coined from the Gree ...
, an irreversible chemical reaction that includes the
thermal decomposition
Thermal decomposition, or thermolysis, is a chemical decomposition of a substance caused by heat. The decomposition temperature of a substance is the temperature at which the substance chemically decomposes. The reaction is usually endothermic ...
of material in an inert atmosphere (in the absence of oxygen).
At elevated temperatures of greater than 250 °C, cellulose decomposes to form considerable amounts of flammable products, one of these being
bio-mass. "Biomass is a complex material, mainly composed of hemicellulose, cellulose, and lignin in addition to extractives (tannins, fatty acids, resins) and inorganic salts". Char cloth is a form of bio-mass, termed bio-char. Char cloth is the result of incomplete combustion, as oxygen is a limiting reagent in the reaction due to the limited oxygen let into the tin during the production process.
References
{{Firelighting
Firelighting materials
Fire making