Cetane number (cetane rating) (CN) is an indicator of the

combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...

speed of

diesel fuel Diesel fuel, also called diesel oil, heavy oil (historically) or simply diesel, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a re ...

and compression needed for ignition. It plays a similar role for diesel as

octane rating An octane rating, or octane number, is a standard measure of a liquid fuel, fuel's ability to withstand Compression ratio, compression in an internal combustion engine without causing engine knocking. The higher the octane number, the more compres ...

does for

gasoline Gasoline ( North American English) or petrol ( Commonwealth English) is a petrochemical product characterized as a transparent, yellowish, and flammable liquid normally used as a fuel for spark-ignited internal combustion engines. When for ...

. The CN is an important factor in determining the quality of diesel fuel, but not the only one; other measurements of diesel fuel's quality include (but are not limited to) energy content,

density Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...

, lubricity, cold-flow properties and sulfur content.Werner Dabelstein, Arno Reglitzky, Andrea Schütze and Klaus Reders "Automotive Fuels" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2007, Wiley-VCH, Weinheim.

Definition

The cetane number of a fuel is defined by finding a blend of cetane and isocetane with the same ignition delay. Cetane has a cetane number defined to be 100, while isocetane's measured cetane number is 15, replacing the former reference fuel alpha-methylnaphthalene, which was assigned a cetane number of 0. Once the blend is known, the cetane number is calculated as a volume-weighted average, rounded to the nearest whole number, of cetane's 100 and isocetane's 15. :cetane number = % ''n''-cetane + 0.15(% isocetane) Cetane number is an inverse function of a fuel's ignition delay, the time period between the start of ignition and the first identifiable pressure increase during combustion of the fuel. In a particular diesel engine, higher cetane fuels will have shorter ignition delay periods than lower cetane fuels. Cetane numbers are only used for the relatively light distillate diesel oils. For heavy (residual) fuel oil two other scales are used, CCAI and CII.

Typical values

Generally, diesel engines operate well with a CN from 48 to 50. Fuels with lower cetane number have longer ignition delays, requiring more time for the fuel combustion process to be completed. Hence, higher speed diesel engines operate more effectively with higher cetane number fuels. In Europe, diesel cetane numbers were set at a minimum of 38 in 1994 and 40 in 2000. The standard for diesel sold in

European Union The European Union (EU) is a supranational union, supranational political union, political and economic union of Member state of the European Union, member states that are Geography of the European Union, located primarily in Europe. The u ...

Iceland Iceland is a Nordic countries, Nordic island country between the Atlantic Ocean, North Atlantic and Arctic Oceans, on the Mid-Atlantic Ridge between North America and Europe. It is culturally and politically linked with Europe and is the regi ...

Norway Norway, officially the Kingdom of Norway, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. The remote Arctic island of Jan Mayen and the archipelago of Svalbard also form part of the Kingdom of ...

and

Switzerland Switzerland, officially the Swiss Confederation, is a landlocked country located in west-central Europe. It is bordered by Italy to the south, France to the west, Germany to the north, and Austria and Liechtenstein to the east. Switzerland ...

is defined by standard EN 590. Since 1 January 2001 EN 590 demands a minimum cetane index of 46 and a minimum cetane number of 51. Premium diesel fuel can have a cetane number as high as 60. In Finland, premium diesel fuels sold by

filling station A filling station (also known as a gas station [] or petrol station []) is a facility that sells fuel and engine lubricants for motor vehicles. The most common fuels sold are gasoline (or petrol) and diesel fuel. Fuel dispensers are used to ...

chains St1 (Diesel Plus), Shell (containing GTL) and ABC (Smart Diesel) have a minimum cetane number of 60 with the typical value being at 63. Neste MY Renewable Diesel sold in Finland has a minimum cetane number of 70. In North America, most states adopt ASTM D975 as their diesel fuel standard and the minimum cetane number is set at 40, with typical values in the 42-45 range. Premium diesel fuel may or may not have higher cetane number depending on the supplier. Premium diesel often use additives to improve CN and

lubricity Lubricity is the measure of the reduction in friction and/or wear by a lubricant. The study of lubrication and wear mechanisms is called tribology. Measurement of lubricity The lubricity of a substance is not a material property, and cannot be m ...

detergent A detergent is a surfactant or a mixture of surfactants with Cleanliness, cleansing properties when in Concentration, dilute Solution (chemistry), solutions. There are a large variety of detergents. A common family is the alkylbenzene sulfonate ...

s to clean the fuel injectors and minimize

carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...

deposits, water dispersants, and other additives depending on geographical and seasonal needs.. California diesel fuel has a minimum cetane of 53. Under the Texas Low Emission Diesel (TxLED) program there are 110 counties where diesel fuel must have a cetane number of 48 or greater, or else must use an approved alternative formulation or comply with the designated alternative limits. Neste MY Renewable Diesel sold in North America has a cetane number of 70+.

Additives

Alkyl nitrates (principally 2-ethylhexyl nitrate) and di-''tert''-butyl peroxide are used as additives to raise the cetane number.

Alternative fuels

Biodiesel Biodiesel is a renewable biofuel, a form of diesel fuel, derived from biological sources like vegetable oils, animal fats, or recycled greases, and consisting of long-chain fatty acid esters. It is typically made from fats. The roots of bi ...

from vegetable oil sources have been recorded as having a cetane number range of 46 to 52, and animal-fat based biodiesels cetane numbers range from 56 to 60.

Dimethyl ether Dimethyl ether (DME; also known as methoxymethane) is the organic compound with the formula CH3OCH3, (sometimes ambiguously simplified to C2H6O as it is an isomer of ethanol). The simplest ether, it is a colorless gas that is a useful precursor ...

is a potential diesel fuel as it has a high cetane rating (55-60) and can be produced as a

biofuel Biofuel is a fuel that is produced over a short time span from Biomass (energy), biomass, rather than by the very slow natural processes involved in the formation of fossil fuels such as oil. Biofuel can be produced from plants or from agricu ...

. Most simple ethers, including liquid ones, such as

diethyl ether Diethyl ether, or simply ether, is an organic compound with the chemical formula , sometimes abbreviated as . It is a colourless, highly Volatility (chemistry), volatile, sweet-smelling ("ethereal odour"), extremely flammable liquid. It belongs ...

can be used as diesel fuels, although the lubricity can be of concern.

Chemical relevance

Cetane is the hydrocarbon with chemical formulas C₁₆H₃₄ and specifically the

structural formula The structural formula of a chemical compound is a graphic representation of the molecular structure (determined by structural chemistry methods), showing how the atoms are connected to one another. The chemical bonding within the molecule is al ...

CH₃(CH₂)₁₄CH₃. Also named n-hexadecane, it is an unbranched saturated

alkane In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in whi ...

. Cetane ignites with a short delay under compression, and is assigned a cetane number of 100. Alpha-methylnaphthalene, which has a long delay period, was assigned a cetane number of 0, but has been replaced as a reference fuel by 2,3,4,5,6,7,8-heptamethylnonane, which is assigned a cetane number of 15. All other

hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually fain ...

s in diesel fuel are indexed to cetane as to how rapidly they ignite under compression, i.e.

diesel engine The diesel engine, named after the German engineer Rudolf Diesel, is an internal combustion engine in which Combustion, ignition of diesel fuel is caused by the elevated temperature of the air in the cylinder due to Mechanics, mechanical Compr ...

conditions. Since hundreds of components comprise diesel fuel, the overall cetane number of that fuel is the average cetane quality of all the components. High-cetane components have a disproportionate influence, hence the use of high-cetane additives.

Measuring cetane number

Cetane numbers are rather difficult to measure accurately, as it requires a special diesel engine called a Cooperative Fuel Research (CFR) engine. Under standard test conditions, the operator of the CFR engine uses a manual-wheel to increase the

compression ratio The compression ratio is the ratio between the maximum and minimum volume during the compression stage of the power cycle in a piston or Wankel engine. A fundamental specification for such engines, it can be measured in two different ways. Th ...

(and therefore the peak pressure within the cylinder) of the engine until the time between fuel injection and ignition is 2.407 ms. The resulting cetane number is then calculated by determining which mixture of cetane ( hexadecane) and isocetane (2,2,4,4,6,8,8-heptamethylnonane) will result in the same ignition delay.

Ignition Quality Tester (IQT)

Another reliable method of measuring the derived cetane number (DCN) of diesel fuel is the Ignition Quality Tester (IQT). This instrument applies a simpler, more robust approach to CN measurement than the CFR. Fuel is injected into a constant volume combustion chamber at approximately 575 °C and . The time between the start of injection and the recovery of the combustion chamber pressure to is defined as the ignition delay. This measured ignition delay is then used to calculate the DCN of the fuel. The fuel's DCN is then calculated using an empirical inverse relationship to ignition delay. Because of the reproducibility, material cost, and speed of the IQT, this has been the definitive source for DCN measurements of fuels since the late 2000s.

Fuel ignition tester

Another reliable method of measuring the derived cetane number of diesel fuel is the Fuel Ignition Tester (FIT). This instrument applies a simpler, more robust approach to CN measurement than the CFR. Fuel is injected into a constant volume combustion chamber in which the ambient temperature is approximately 575 °C. The fuel combusts, and the high rate of pressure change within the chamber defines the start of combustion. The ignition delay of the fuel can then be calculated as the time elapsed between the start of fuel injection and the start of combustion. The fuel's derived cetane number can then be calculated using an empirical inverse relationship to ignition delay.

Cetane index

Another statistic used by fuel-users to control quality is the cetane index (CI), which is a calculated number based on the

and a distillation range of the fuel. There are various versions of this, depending on whether metric or

Imperial units The imperial system of units, imperial system or imperial units (also known as British Imperial or Exchequer Standards of 1826) is the system of units first defined in the British Weights and Measures Act 1824 and continued to be developed thr ...

are used, and the number of distillation points that are used. These days most

oil companies The following is a list of notable companies in the petroleum industry that are engaged in petroleum exploration and production. The list is in alphabetical order by continent and then by country. This list does not include companies only involved ...

use the '4-point method', ASTM D4737, based on density and 10% 50% and 90% recovery temperatures. The '2-point method' is defined in

ASTM ASTM International, formerly known as American Society for Testing and Materials, is a standards organization that develops and publishes voluntary consensus technical international standards for a wide range of materials, products, systems and s ...

D976 and uses just density and the 50% recovery temperature. This 2-point method tends to overestimate the cetane index and is not recommended. Cetane index calculations cannot account for cetane improver additives and therefore do not measure the total cetane number for additized diesel fuels. Diesel engine operation is primarily related to the actual cetane number, and the cetane index is merely an estimation of the base (unadditized) cetane number.

Industry standards

The industry standards for measuring cetane number are ASTM D613 (ISO 5165) for the CFR engine, D6890 for the IQT, and D7170 for the FIT.

References

External links

Article by Bruce Hamilton

Explanation of Cetane from BP
Diesel fuel Fuel technology Petroleum production Scales