Cembrene A, or sometimes neocembrene, is a natural monocyclic
diterpene
Diterpenes are a class of terpenes composed of four isoprene units, often with the molecular formula C20H32. They are biosynthesized by plants, animals and fungi via the HMG-CoA reductase pathway, with geranylgeranyl pyrophosphate being a primary ...
isolated from corals of the genus ''
Nephthea
''Litophyton'' is a genus of soft corals in the family Nephtheidae.
Species
The World Register of Marine Species includes the following species
A species () is often defined as the largest group of organisms in which any two individuals ...
''. It is a colorless oil with a faint wax-like odor.
Cembrene A is a trail
pheromone
A pheromone () is a secreted or excreted chemical factor that triggers a social response in members of the same species. Pheromones are chemicals capable of acting like hormones outside the body of the secreting individual, to affect the behavio ...
for termites; however, the chemical structure of cembrene is central to a very wide variety of other natural products found both in plants and in animals.
[''Terpenes: Flavors, Fragrances, Pharmaca, Pheromones'', Eberhard Breitmaier, page 7. ] ''
Pinus leucodermis
''Pinus heldreichii'', the Bosnian pine or Heldreich's pine, is a species of pine native to mountains of southeast Europe in the Balkans and southern Italy.
Description
It is an evergreen tree up to in height, and in trunk diameter. The bark i ...
'' tree bark and wood
essential oil
An essential oil is a concentrated hydrophobic liquid containing volatile (easily evaporated at normal temperatures) chemical compounds from plants. Essential oils are also known as volatile oils, ethereal oils, aetheroleum, or simply as the ...
s contain a high percentage of cembrene.
Cembrenes are biosynthesized by
macrocyclization of
geranylgeranyl pyrophosphate
Geranylgeranyl pyrophosphate is an intermediate in the biosynthesis of diterpenes and diterpenoids. It is also the precursor to carotenoids, gibberellins, tocopherols, and chlorophylls.
It is also a precursor to geranylgeranylated proteins, whic ...
.
References
{{reflist
Diterpenes
Alkene derivatives
Insect ecology
Insect pheromones
Cycloalkenes