CataCXium F sulf is a water-soluble

organophosphorus compound Organophosphorus chemistry is the scientific study of the synthesis and properties of organophosphorus compounds, which are organic compounds containing phosphorus. They are used primarily in pest control as an alternative to chlorinated hydrocarbo ...

derived from

fluorene Fluorene , or 9''H''-fluorene is an organic compound with the formula (C6H4)2CH2. It forms white crystals that exhibit a characteristic, aromatic odor similar to that of naphthalene. Despite its name, it does not contain the element fluorine, but ...

. The

palladium Palladium is a chemical element; it has symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1802 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas (formally 2 Pallas), ...

complexes of the respective phosphine show an excellent activity in various

palladium-catalyzed coupling reactions In organic chemistry, a cross-coupling reaction is a reaction where two different fragments are joined. Cross-couplings are a subset of the more general coupling reactions. Often cross-coupling reactions require metal catalysts. One important reac ...

, including

Suzuki reaction The Suzuki reaction or Suzuki coupling is an organic reaction that uses a palladium complex catalyst to cross-couple a boronic acid to an organohalide. It was first published in 1979 by Akira Suzuki, and he shared the 2010 Nobel Prize in Chemi ...

Sonogashira coupling The Sonogashira reaction is a cross-coupling reaction used in organic synthesis to form carbon–carbon bonds. It employs a palladium catalyst as well as copper co-catalyst to form a carbon–carbon bond between a terminal alkyne and an aryl or vi ...

s and Buchwald–Hartwig reactions.

References

* C.A. Fleckenstein; H. Plenio, Highly efficient Suzuki-Miyaura coupling of heterocyclic substrates through rational reaction design. ''Chemistry-A European Journal'' 2008, ''14(14)'', 4267–4279. * C.A. Fleckenstein; H. Plenio, Aqueous/organic cross coupling: Sustainable protocol for Sonogashira reactions of heterocycles. ''Green Chemistry'' 2008, ''10'', 563–570. * C.A. Fleckenstein; H. Plenio, Efficient Suzuki-Miyaura Coupling of (Hetero)aryl Chlorides with Thiophene- and Furanboronic Acids in Aqueous ''n''-Butanol. ''Journal of Organic Chemistry'' 2008, ''73'', 3236–3244. * C.A Fleckenstein; R. Kadyrov; H. Plenio, Efficient Large-Scale Synthesis of 9-Alkylfluorenyl Phosphines for Pd-Catalyzed Cross-Coupling Reactions. ''Organic Process Research & Development'' 2008, ''12'', 475–479. * C.A. Fleckenstein; H. Plenio, Aqueous cross-coupling. Highly efficient Suzuki–Miyaura coupling of ''N''-heteroaryl halides and ''N''-heteroarylboronic acids. ''Green Chemistry'' 2007, ''9'', 1287–1291.

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Product information
from

Sigma-Aldrich Sigma-Aldrich (formally MilliporeSigma) is an American chemical, life science, and biotechnology company owned by the multinational chemical conglomerate Merck Group. Sigma-Aldrich was created in 1975 by the merger of Sigma Chemical Company and ...

information
from Strem Chemicals {{DEFAULTSORT:Catacxium F Sulf Organometallic chemistry Organophosphorus compounds Fluorenes Cyclohexyl compounds