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A carbon nanotube
quantum dot Quantum dots (QDs) are semiconductor particles a few nanometres in size, having optical and electronic properties that differ from those of larger particles as a result of quantum mechanics. They are a central topic in nanotechnology. When the q ...
(CNT QD) is a small region of a
carbon nanotube A scanning tunneling microscopy image of a single-walled carbon nanotube Rotating single-walled zigzag carbon nanotube A carbon nanotube (CNT) is a tube made of carbon with diameters typically measured in nanometers. ''Single-wall carbon nan ...
in which
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary partic ...
s are confined.


Formation

A CNT QD is formed when electrons are confined to a small region within a carbon nanotube. This is normally accomplished by application of a
voltage Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge t ...
to a
gate electrode The field-effect transistor (FET) is a type of transistor that uses an electric field to control the flow of current in a semiconductor. FETs ( JFETs or MOSFETs) are devices with three terminals: ''source'', ''gate'', and ''drain''. FETs con ...
, dragging the
valence band In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in ...
of the CNT down in energy, thereby causing electrons to pool in a region in the vicinity of the electrode. Experimentally this is accomplished by laying a CNT on a
silicon dioxide Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
surface, sitting on a doped
silicon wafer In electronics, a wafer (also called a slice or substrate) is a thin slice of semiconductor, such as a crystalline silicon (c-Si), used for the fabrication of integrated circuits and, in photovoltaics, to manufacture solar cells. The wafer ser ...
. This can be done by
chemical vapor deposition Chemical vapor deposition (CVD) is a vacuum deposition method used to produce high quality, and high-performance, solid materials. The process is often used in the semiconductor industry to produce thin films. In typical CVD, the wafer (subst ...
using
carbon monoxide Carbon monoxide ( chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the si ...
. The silicon wafer serves as the gate electrode. Metallic leads can then be laid over the nanotube in order to connect the CNT QD up to an electrical circuit.


Electronic structure

The CNT QD has interesting properties as a result of the strong correlation between the confined electrons. In addition to this the electrons possess orbital angular momentum, as is characteristic of CNT electrons. spin–orbit coupling has also been shown to be significant in these systems.M. Galpin et al., PRB, 81, 075437 (2010) These properties are often probed by connecting the nanotube to two metallic leads and measuring the conductance of the system.


Many-body systems

The CNT QD connected to metallic leads constitutes a genuine
many-body system The many-body problem is a general name for a vast category of physical problems pertaining to the properties of microscopic systems made of many interacting particles. ''Microscopic'' here implies that quantum mechanics has to be used to provid ...
, due to the electron correlations. Therefore, Wilson's
Numerical renormalization group The numerical renormalization group (NRG) is a technique devised by Kenneth Wilson to solve certain many-body problems where quantum impurity physics plays a key role. History The numerical renormalization group is an inherently non-perturbative ...
is often used to study the CNT QD. The CNT QD is modelled as an Anderson-type model, which can be reduced by Schrieffer-Wolff transformation to an effective Kondo-type model at low temperature.


Other nanotube system

Similar mesoscopic devices have been constructed from elements other than carbon. So called
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish ...
nanotubes (CuNTs), developed by the
Chinese Academy of Sciences The Chinese Academy of Sciences (CAS); ), known by Academia Sinica in English until the 1980s, is the national academy of the People's Republic of China for natural sciences. It has historical origins in the Academia Sinica during the Repub ...
, are fabricated by closely aligning individual copper atoms on a surface.


See also

* Cadmium-free quantum dot *
Carbon nanotube A scanning tunneling microscopy image of a single-walled carbon nanotube Rotating single-walled zigzag carbon nanotube A carbon nanotube (CNT) is a tube made of carbon with diameters typically measured in nanometers. ''Single-wall carbon nan ...
* Carbon quantum dot * Graphene quantum dot *
Optical properties of carbon nanotubes The optical properties of carbon nanotubes are highly relevant for materials science. The way those materials interact with electromagnetic radiation is unique in many respects, as evidenced by their peculiar absorption, photoluminescence (fl ...


Notes

{{DEFAULTSORT:Carbon Nanotube Quantum Dot Carbon nanotubes Quantum dots