Californium Trifluoride
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Californium(III) fluoride is a binary
inorganic compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...
of
californium Californium is a synthetic chemical element; it has symbol Cf and atomic number 98. It was first synthesized in 1950 at Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory) by bombarding curium with al ...
and
fluorine Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
with the formula


Physical properties

Californium(III) fluoride is a yellow-green solid and has two crystalline structures that are temperature dependent. At low temperatures the orthorhombic structure ( type) is found with
lattice constant A lattice constant or lattice parameter is one of the physical dimensions and angles that determine the geometry of the unit cells in a crystal lattice, and is proportional to the distance between atoms in the crystal. A simple cubic crystal has ...
s ''a'' = 665.3(3) pm, ''b'' = 703.9(1) pm and ''c'' = 439.3(3) pm. At higher temperatures it forms a trigonal system ( type) with: ''a'' = 694.5(3) pm and ''c'' = 710.1(2) pm. Here, each californium atom is surrounded by nine fluorine atoms in a distorted triply-capped trigonal-prismatic structure.


References

Californium compounds Fluorides Actinide halides {{inorganic-compound-stub