A calcite sea is a sea in which low-magnesium

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

is the primary inorganic marine

calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...

precipitate. An

aragonite sea An aragonite sea contains aragonite and high-magnesium calcite as the primary inorganic calcium carbonate precipitates. The reason lies in the highly hydrated divalent ion, the second most abundant cation in seawater after , known to be a stron ...

is the alternate seawater chemistry in which

aragonite Aragonite is a carbonate mineral and one of the three most common naturally occurring crystal forms of calcium carbonate (), the others being calcite and vaterite. It is formed by biological and physical processes, including precipitation fr ...

and high-magnesium calcite are the primary inorganic carbonate precipitates. The Early

Paleozoic The Paleozoic ( , , ; or Palaeozoic) Era is the first of three Era (geology), geological eras of the Phanerozoic Eon. Beginning 538.8 million years ago (Ma), it succeeds the Neoproterozoic (the last era of the Proterozoic Eon) and ends 251.9 Ma a ...

and the Middle to Late

Mesozoic The Mesozoic Era is the Era (geology), era of Earth's Geologic time scale, geological history, lasting from about , comprising the Triassic, Jurassic and Cretaceous Period (geology), Periods. It is characterized by the dominance of archosaurian r ...

oceans were predominantly calcite seas, whereas the Middle Paleozoic through the Early Mesozoic and the

Cenozoic The Cenozoic Era ( ; ) is Earth's current geological era, representing the last 66million years of Earth's history. It is characterized by the dominance of mammals, insects, birds and angiosperms (flowering plants). It is the latest of three g ...

(including today) are characterized by aragonite seas. The most significant geological and biological effects of calcite sea conditions include rapid and widespread formation of carbonate hardgrounds, calcitic

ooids Ooids (, ) are small (commonly ≤2 mm in diameter), spheroidal, "coated" (layered) sedimentary grains, usually composed of calcium carbonate, but sometimes made up of iron- or phosphate-based minerals. Ooids usually form on the sea floor ...

, calcite cements, and the contemporaneous dissolution of aragonite shells in shallow warm seas. Hardgrounds were very common, for example, in the calcite seas of the

Ordovician The Ordovician ( ) is a geologic period and System (geology), system, the second of six periods of the Paleozoic Era (geology), Era, and the second of twelve periods of the Phanerozoic Eon (geology), Eon. The Ordovician spans 41.6 million years f ...

and

Jurassic The Jurassic ( ) is a Geological period, geologic period and System (stratigraphy), stratigraphic system that spanned from the end of the Triassic Period million years ago (Mya) to the beginning of the Cretaceous Period, approximately 143.1 Mya. ...

, but virtually absent from the aragonite seas of the

Permian The Permian ( ) is a geologic period and System (stratigraphy), stratigraphic system which spans 47 million years, from the end of the Carboniferous Period million years ago (Mya), to the beginning of the Triassic Period 251.902 Mya. It is the s ...

Fossils A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...

invertebrate Invertebrates are animals that neither develop nor retain a vertebral column (commonly known as a ''spine'' or ''backbone''), which evolved from the notochord. It is a paraphyletic grouping including all animals excluding the chordata, chordate s ...

organisms found in calcite sea deposits are usually dominated by either thick calcite shells and skeletons, were infaunal and/or had thick periostraca, or had an inner shell of aragonite and an outer shell of calcite. This was apparently because aragonite dissolved quickly on the seafloor and had to be either avoided or protected as a biomineral. Calcite seas were coincident with times of rapid

seafloor spreading Seafloor spreading, or seafloor spread, is a process that occurs at mid-ocean ridges, where new oceanic crust is formed through volcanic activity and then gradually moves away from the ridge. History of study Earlier theories by Alfred Wegener ...

and global greenhouse climate conditions. Seafloor spreading centers cycle seawater through

hydrothermal vent Hydrothermal vents are fissures on the seabed from which geothermally heated water discharges. They are commonly found near volcanically active places, areas where tectonic plates are moving apart at mid-ocean ridges, ocean basins, and hot ...

s, reducing the ratio of magnesium to calcium in the seawater through

metamorphism Metamorphism is the transformation of existing Rock (geology), rock (the protolith) to rock with a different mineral composition or Texture (geology), texture. Metamorphism takes place at temperatures in excess of , and often also at elevated ...

of calcium-rich minerals in basalt to magnesium-rich clays. This reduction in the Mg/Ca ratio favors the precipitation of calcite over aragonite. Increased seafloor spreading also means increased

volcanism Volcanism, vulcanism, volcanicity, or volcanic activity is the phenomenon where solids, liquids, gases, and their mixtures erupt to the surface of a solid-surface astronomical body such as a planet or a moon. It is caused by the presence of a he ...

and elevated levels of

carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...

in the atmosphere and oceans. This may also have an effect on which polymorph of

is precipitated. Further, high calcium concentrations of seawater favor the burial of CaCO₃, thereby removing

alkalinity Alkalinity (from ) is the capacity of water to resist Freshwater acidification, acidification. It should not be confused with base (chemistry), basicity, which is an absolute measurement on the pH scale. Alkalinity is the strength of a buffer s ...

from the ocean, lowering seawater pH and reducing its acid/base buffering. Image:CalciteSeasTable.jpg, Table showing the conditions for calcite and aragonite seas Image:MgCaRatioChanges.jpg,

Tectonic Tectonics ( via Latin ) are the processes that result in the structure and properties of the Earth's crust and its evolution through time. The field of ''planetary tectonics'' extends the concept to other planets and moons. These processes ...

mechanism for changing Mg/Ca ratios in seawater File:OoidSurface01.jpg, Grainstone with calcitic

and sparry calcite cement; Carmel Formation, Middle Jurassic, of southern Utah Image:EncrustedBivalveMold.jpg, An encrusted

bivalve Bivalvia () or bivalves, in previous centuries referred to as the Lamellibranchiata and Pelecypoda, is a class (biology), class of aquatic animal, aquatic molluscs (marine and freshwater) that have laterally compressed soft bodies enclosed b ...

external mold showing contemporaneous dissolution of the original aragonite shell and calcitic cementation of the mold File:Encrusted Ordovician nautiloid InternalExternal.jpg, An encrusted

nautiloid Nautiloids are a group of cephalopods (Mollusca) which originated in the Late Cambrian and are represented today by the living ''Nautilus'' and ''Allonautilus''. Fossil nautiloids are diverse and species rich, with over 2,500 recorded species. Th ...

internal mold showing contemporaneous dissolution of the original aragonite shell and calcitic cementation Image:Paleosabella4CS.jpg, The boring ''Palaeosabella'' in an

shell. The borings penetrated an inner aragonitic shell layer which dissolved away. Image:Petroxestes_borings_Ordovician.jpg, '' Petroxestes'' borings in an Upper

hardground Carbonate hardgrounds are surfaces of synsedimentarily cemented carbonate layers that have been exposed on the seafloor (Wilson and Palmer, 1992). A hardground is essentially, then, a lithified seafloor. Ancient hardgrounds are found in limeston ...

, southern Ohio

References

{{Reflist Limestone Marine geology Historical geology