Caesium
Caesium (IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that a ...
(
55Cs) has 40 known
isotopes, making it, along with
barium
Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element.
Th ...
and
mercury
Mercury commonly refers to:
* Mercury (planet), the nearest planet to the Sun
* Mercury (element), a metallic chemical element with the symbol Hg
* Mercury (mythology), a Roman god
Mercury or The Mercury may also refer to:
Companies
* Merc ...
, one of the elements with the most isotopes.
The
atomic masses of these isotopes range from 112 to 151. Only one isotope,
133Cs, is stable. The longest-lived
radioisotopes are
135Cs with a half-life of 2.3 million years, with a half-life of 30.1671 years and
134Cs with a half-life of 2.0652 years. All other isotopes have half-lives less than 2 weeks, most under an hour.
Beginning in 1945 with the commencement of
nuclear testing
Nuclear weapons tests are experiments carried out to determine nuclear weapons' effectiveness, yield, and explosive capability. Testing nuclear weapons offers practical information about how the weapons function, how detonations are affected by ...
, caesium radioisotopes were released into the
atmosphere
An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A s ...
where caesium is absorbed readily into solution and is returned to the surface of the earth as a component of
radioactive fallout. Once caesium enters the ground water, it is deposited on soil surfaces and removed from the landscape primarily by particle transport. As a result, the input function of these isotopes can be estimated as a function of time.
List of isotopes
, -
, rowspan=2,
112Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 57
, rowspan=2, 111.95030(33)#
, rowspan=2, 500(100) μs
,
p
,
111Xe
, rowspan=2, 1+#
, rowspan=2,
, rowspan=2,
, -
,
α
,
108I
, -
, rowspan=2,
113Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 58
, rowspan=2, 112.94449(11)
, rowspan=2, 16.7(7) μs
, p (99.97%)
,
112Xe
, rowspan=2, 5/2+#
, rowspan=2,
, rowspan=2,
, -
,
β+ (.03%)
,
113Xe
, -
, rowspan=4,
114Cs
, rowspan=4 style="text-align:right" , 55
, rowspan=4 style="text-align:right" , 59
, rowspan=4, 113.94145(33)#
, rowspan=4, 0.57(2) s
, β
+ (91.09%)
,
114Xe
, rowspan=4, (1+)
, rowspan=4,
, rowspan=4,
, -
, β
+, p (8.69%)
,
113I
, -
, β
+, α (.19%)
,
110Te
, -
, α (.018%)
,
110I
, -
, rowspan=2,
115Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 60
, rowspan=2, 114.93591(32)#
, rowspan=2, 1.4(8) s
, β
+ (99.93%)
,
115Xe
, rowspan=2, 9/2+#
, rowspan=2,
, rowspan=2,
, -
, β
+, p (.07%)
,
114I
, -
, rowspan=3,
116Cs
, rowspan=3 style="text-align:right" , 55
, rowspan=3 style="text-align:right" , 61
, rowspan=3, 115.93337(11)#
, rowspan=3, 0.70(4) s
, β
+ (99.67%)
,
116Xe
, rowspan=3, (1+)
, rowspan=3,
, rowspan=3,
, -
, β
+, p (.279%)
,
115I
, -
, β
+, α (.049%)
,
112Te
, -
, rowspan=3 style="text-indent:1em" ,
116mCs
, rowspan=3 colspan="3" style="text-indent:2em" , 100(60)# keV
, rowspan=3, 3.85(13) s
, β
+ (99.48%)
,
116Xe
, rowspan=3, 4+, 5, 6
, rowspan=3,
, rowspan=3,
, -
, β
+, p (.51%)
,
115I
, -
, β
+, α (.008%)
,
112Te
, -
,
117Cs
, style="text-align:right" , 55
, style="text-align:right" , 62
, 116.92867(7)
, 8.4(6) s
, β
+
,
117Xe
, (9/2+)#
,
,
, -
, style="text-indent:1em" ,
117mCs
, colspan="3" style="text-indent:2em" , 150(80)# keV
, 6.5(4) s
, β
+
,
117Xe
, 3/2+#
,
,
, -
, rowspan=3,
118Cs
, rowspan=3 style="text-align:right" , 55
, rowspan=3 style="text-align:right" , 63
, rowspan=3, 117.926559(14)
, rowspan=3, 14(2) s
, β
+ (99.95%)
,
118Xe
, rowspan=3, 2
, rowspan=3,
, rowspan=3,
, -
, β
+, p (.042%)
,
117I
, -
, β
+, α (.0024%)
,
114Te
, -
, rowspan=3 style="text-indent:1em" ,
118mCs
, rowspan=3 colspan="3" style="text-indent:2em" , 100(60)# keV
, rowspan=3, 17(3) s
, β
+ (99.95%)
,
118Xe
, rowspan=3, (7−)
, rowspan=3,
, rowspan=3,
, -
, β
+, p (.042%)
,
117I
, -
, β
+, α (.0024%)
,
114Te
, -
, rowspan=2,
119Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 64
, rowspan=2, 118.922377(15)
, rowspan=2, 43.0(2) s
, β
+
,
119Xe
, rowspan=2, 9/2+
, rowspan=2,
, rowspan=2,
, -
, β
+, α (2×10
−6%)
,
115Te
, -
, style="text-indent:1em" ,
119mCs
, colspan="3" style="text-indent:2em" , 50(30)# keV
, 30.4(1) s
, β
+
,
119Xe
, 3/2(+)
,
,
, -
, rowspan=3,
120Cs
, rowspan=3 style="text-align:right" , 55
, rowspan=3 style="text-align:right" , 65
, rowspan=3, 119.920677(11)
, rowspan=3, 61.2(18) s
, β
+
,
120Xe
, rowspan=3, 2(−#)
, rowspan=3,
, rowspan=3,
, -
, β
+, α (2×10
−5%)
,
116Te
, -
, β
+, p (7×10
−6%)
,
119I
, -
, rowspan=3 style="text-indent:1em" ,
120mCs
, rowspan=3 colspan="3" style="text-indent:2em" , 100(60)# keV
, rowspan=3, 57(6) s
, β
+
,
120Xe
, rowspan=3, (7−)
, rowspan=3,
, rowspan=3,
, -
, β
+, α (2×10
−5%)
,
116Te
, -
, β
+, p (7×10
−6%)
,
119I
, -
,
121Cs
, style="text-align:right" , 55
, style="text-align:right" , 66
, 120.917229(15)
, 155(4) s
, β
+
,
121Xe
, 3/2(+)
,
,
, -
, rowspan=2 style="text-indent:1em" ,
121mCs
, rowspan=2 colspan="3" style="text-indent:2em" , 68.5(3) keV
, rowspan=2, 122(3) s
, β
+ (83%)
,
121Xe
, rowspan=2, 9/2(+)
, rowspan=2,
, rowspan=2,
, -
,
IT (17%)
,
121Cs
, -
, rowspan=2,
122Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 67
, rowspan=2, 121.91611(3)
, rowspan=2, 21.18(19) s
, β
+
,
122Xe
, rowspan=2, 1+
, rowspan=2,
, rowspan=2,
, -
, β
+, α (2×10
−7%)
,
118Te
, -
, style="text-indent:1em" ,
122m1Cs
, colspan="3" style="text-indent:2em" , 45.8 keV
, >1 μs
,
,
, (3)+
,
,
, -
, style="text-indent:1em" ,
122m2Cs
, colspan="3" style="text-indent:2em" , 140(30) keV
, 3.70(11) min
, β
+
,
122Xe
, 8−
,
,
, -
, style="text-indent:1em" ,
122m3Cs
, colspan="3" style="text-indent:2em" , 127.0(5) keV
, 360(20) ms
,
,
, (5)−
,
,
, -
,
123Cs
, style="text-align:right" , 55
, style="text-align:right" , 68
, 122.912996(13)
, 5.88(3) min
, β
+
,
123Xe
, 1/2+
,
,
, -
, style="text-indent:1em" ,
123m1Cs
, colspan="3" style="text-indent:2em" , 156.27(5) keV
, 1.64(12) s
, IT
,
123Cs
, (11/2)−
,
,
, -
, style="text-indent:1em" ,
123m2Cs
, colspan="3" style="text-indent:2em" , 231.63+X keV
, 114(5) ns
,
,
, (9/2+)
,
,
, -
,
124Cs
, style="text-align:right" , 55
, style="text-align:right" , 69
, 123.912258(9)
, 30.9(4) s
, β
+
, ''
124Xe''
, 1+
,
,
, -
, style="text-indent:1em" ,
124mCs
, colspan="3" style="text-indent:2em" , 462.55(17) keV
, 6.3(2) s
, IT
,
124Cs
, (7)+
,
,
, -
,
125Cs
, style="text-align:right" , 55
, style="text-align:right" , 70
, 124.909728(8)
, 46.7(1) min
, β
+
,
125Xe
, 1/2(+)
,
,
, -
, style="text-indent:1em" ,
125mCs
, colspan="3" style="text-indent:2em" , 266.6(11) keV
, 900(30) ms
,
,
, (11/2−)
,
,
, -
,
126Cs
, style="text-align:right" , 55
, style="text-align:right" , 71
, 125.909452(13)
, 1.64(2) min
, β
+
,
126Xe
, 1+
,
,
, -
, style="text-indent:1em" ,
126m1Cs
, colspan="3" style="text-indent:2em" , 273.0(7) keV
, >1 μs
,
,
,
,
,
, -
, style="text-indent:1em" ,
126m2Cs
, colspan="3" style="text-indent:2em" , 596.1(11) keV
, 171(14) μs
,
,
,
,
,
, -
,
127Cs
, style="text-align:right" , 55
, style="text-align:right" , 72
, 126.907418(6)
, 6.25(10) h
, β
+
,
127Xe
, 1/2+
,
,
, -
, style="text-indent:1em" ,
127mCs
, colspan="3" style="text-indent:2em" , 452.23(21) keV
, 55(3) μs
,
,
, (11/2)−
,
,
, -
,
128Cs
, style="text-align:right" , 55
, style="text-align:right" , 73
, 127.907749(6)
, 3.640(14) min
, β
+
,
128Xe
, 1+
,
,
, -
,
129Cs
, style="text-align:right" , 55
, style="text-align:right" , 74
, 128.906064(5)
, 32.06(6) h
, β
+
,
129Xe
, 1/2+
,
,
, -
, rowspan=2,
130Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 75
, rowspan=2, 129.906709(9)
, rowspan=2, 29.21(4) min
, β
+ (98.4%)
,
130Xe
, rowspan=2, 1+
, rowspan=2,
, rowspan=2,
, -
, β
− (1.6%)
, ''
130Ba''
, -
, rowspan=2 style="text-indent:1em" ,
130mCs
, rowspan=2 colspan="3" style="text-indent:2em" , 163.25(11) keV
, rowspan=2, 3.46(6) min
, IT (99.83%)
,
130Cs
, rowspan=2, 5−
, rowspan=2,
, rowspan=2,
, -
, β
+ (.16%)
,
130Xe
, -
,
131Cs
, style="text-align:right" , 55
, style="text-align:right" , 76
, 130.905464(5)
, 9.689(16) d
,
EC
,
131Xe
, 5/2+
,
,
, -
, rowspan=2,
132Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 77
, rowspan=2, 131.9064343(20)
, rowspan=2, 6.480(6) d
, β
+ (98.13%)
,
132Xe
, rowspan=2, 2+
, rowspan=2,
, rowspan=2,
, -
, β
− (1.87%)
,
132Ba
, -
,
133Cs
[Used to define the ]second
The second (symbol: s) is the unit of time in the International System of Units (SI), historically defined as of a day – this factor derived from the division of the day first into 24 hours, then to 60 minutes and finally to 60 seconds ...
Fission product
Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the release ...
, style="text-align:right" , 55
, style="text-align:right" , 78
, 132.905451933(24)
, colspan=3 align=center, Stable
[Theoretically capable of ]spontaneous fission
Spontaneous fission (SF) is a form of radioactive decay that is found only in very heavy chemical elements. The nuclear binding energy of the elements reaches its maximum at an atomic mass number of about 56 (e.g., iron-56); spontaneous breakdo ...
, 7/2+
, 1.0000
,
, -
, rowspan=2,
134Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 79
, rowspan=2, 133.906718475(28)
, rowspan=2, 2.0652(4) y
, β
−
,
134Ba
, rowspan=2, 4+
, rowspan=2,
, rowspan=2,
, -
, EC (3×10
−4%)
,
134Xe
, -
, style="text-indent:1em" ,
134mCs
, colspan="3" style="text-indent:2em" , 138.7441(26) keV
, 2.912(2) h
, IT
,
134Cs
, 8−
,
,
, -
,
135Cs
, style="text-align:right" , 55
, style="text-align:right" , 80
, 134.9059770(11)
, 2.3 x10
6 y
, β
−
,
135Ba
, 7/2+
,
,
, -
, style="text-indent:1em" ,
135mCs
, colspan="3" style="text-indent:2em" , 1632.9(15) keV
, 53(2) min
, IT
,
135Cs
, 19/2−
,
,
, -
,
136Cs
, style="text-align:right" , 55
, style="text-align:right" , 81
, 135.9073116(20)
, 13.16(3) d
, β
−
,
136Ba
, 5+
,
,
, -
, rowspan=2 style="text-indent:1em" ,
136mCs
, rowspan=2 colspan="3" style="text-indent:2em" , 518(5) keV
, rowspan=2, 19(2) s
, β
−
,
136Ba
, rowspan=2, 8−
, rowspan=2,
, rowspan=2,
, -
, IT
,
136Cs
, -
, rowspan=2,
137Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 82
, rowspan=2, 136.9070895(5)
, rowspan=2, 30.1671(13) y
, β
− (95%)
,
137mBa
, rowspan=2, 7/2+
, rowspan=2,
, rowspan=2,
, -
, β
− (5%)
,
137Ba
, -
,
138Cs
, style="text-align:right" , 55
, style="text-align:right" , 83
, 137.911017(10)
, 33.41(18) min
, β
−
,
138Ba
, 3−
,
,
, -
, rowspan=2 style="text-indent:1em" ,
138mCs
, rowspan=2 colspan="3" style="text-indent:2em" , 79.9(3) keV
, rowspan=2, 2.91(8) min
, IT (81%)
,
138Cs
, rowspan=2, 6−
, rowspan=2,
, rowspan=2,
, -
, β
− (19%)
,
138Ba
, -
,
139Cs
, style="text-align:right" , 55
, style="text-align:right" , 84
, 138.913364(3)
, 9.27(5) min
, β
−
,
139Ba
, 7/2+
,
,
, -
,
140Cs
, style="text-align:right" , 55
, style="text-align:right" , 85
, 139.917282(9)
, 63.7(3) s
, β
−
,
140Ba
, 1−
,
,
, -
, rowspan=2,
141Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 86
, rowspan=2, 140.920046(11)
, rowspan=2, 24.84(16) s
, β
− (99.96%)
,
141Ba
, rowspan=2, 7/2+
, rowspan=2,
, rowspan=2,
, -
, β
−,
n (.0349%)
,
140Ba
, -
, rowspan=2,
142Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 87
, rowspan=2, 141.924299(11)
, rowspan=2, 1.689(11) s
, β
− (99.9%)
,
142Ba
, rowspan=2, 0−
, rowspan=2,
, rowspan=2,
, -
, β
−, n (.091%)
,
141Ba
, -
, rowspan=2,
143Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 88
, rowspan=2, 142.927352(25)
, rowspan=2, 1.791(7) s
, β
− (98.38%)
,
143Ba
, rowspan=2, 3/2+
, rowspan=2,
, rowspan=2,
, -
, β
−, n (1.62%)
,
142Ba
, -
, rowspan=2,
144Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 89
, rowspan=2, 143.932077(28)
, rowspan=2, 994(4) ms
, β
− (96.8%)
,
144Ba
, rowspan=2, 1(−#)
, rowspan=2,
, rowspan=2,
, -
, β
−, n (3.2%)
,
143Ba
, -
, rowspan=2 style="text-indent:1em" ,
144mCs
, rowspan=2 colspan="3" style="text-indent:2em" , 300(200)# keV
, rowspan=2, <1 s
, β
−
,
144Ba
, rowspan=2, (>3)
, rowspan=2,
, rowspan=2,
, -
, IT
,
144Cs
, -
, rowspan=2,
145Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 90
, rowspan=2, 144.935526(12)
, rowspan=2, 582(6) ms
, β
− (85.7%)
,
145Ba
, rowspan=2, 3/2+
, rowspan=2,
, rowspan=2,
, -
, β
−, n (14.3%)
,
144Ba
, -
, rowspan=2,
146Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 91
, rowspan=2, 145.94029(8)
, rowspan=2, 0.321(2) s
, β
− (85.8%)
,
146Ba
, rowspan=2, 1−
, rowspan=2,
, rowspan=2,
, -
, β
−, n (14.2%)
,
145Ba
, -
, rowspan=2,
147Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 92
, rowspan=2, 146.94416(6)
, rowspan=2, 0.235(3) s
, β
− (71.5%)
,
147Ba
, rowspan=2, (3/2+)
, rowspan=2,
, rowspan=2,
, -
, β
−, n (28.49%)
,
146Ba
, -
, rowspan=2,
148Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 93
, rowspan=2, 147.94922(62)
, rowspan=2, 146(6) ms
, β
− (74.9%)
,
148Ba
, rowspan=2,
, rowspan=2,
, rowspan=2,
, -
, β
−, n (25.1%)
,
147Ba
, -
, rowspan=2,
149Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 94
, rowspan=2, 148.95293(21)#
, rowspan=2, 150# ms
50 ms, β
−
,
149Ba
, rowspan=2, 3/2+#
, rowspan=2,
, rowspan=2,
, -
, β
−, n
,
148Ba
, -
, rowspan=2,
150Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 95
, rowspan=2, 149.95817(32)#
, rowspan=2, 100# ms
50 ms, β
−
,
150Ba
, rowspan=2,
, rowspan=2,
, rowspan=2,
, -
, β
−, n
,
149Ba
, -
, rowspan=2,
151Cs
, rowspan=2 style="text-align:right" , 55
, rowspan=2 style="text-align:right" , 96
, rowspan=2, 150.96219(54)#
, rowspan=2, 60# ms
50 ms, β
−
,
151Ba
, rowspan=2, 3/2+#
, rowspan=2,
, rowspan=2,
, -
, β
−, n
,
150Ba
Caesium-131
Caesium-131, introduced in 2004 for
brachytherapy by
Isoray
Isoray Inc. (Isoray) is a national isotope-based medical company and the sole producer of Cesium brachytherapy sources, which are expanding brachytherapy treatments for difficult to treat cancers. Isoray is a registered manufacturer with the FDA ...
,
has a
half-life of 9.7 days and 30.4 keV energy.
Caesium-133
Caesium-133 is the only stable
isotope of caesium. The
SI base unit
The SI base units are the standard units of measurement defined by the International System of Units (SI) for the seven base quantities of what is now known as the International System of Quantities: they are notably a basic set from which all ...
of time, the
second
The second (symbol: s) is the unit of time in the International System of Units (SI), historically defined as of a day – this factor derived from the division of the day first into 24 hours, then to 60 minutes and finally to 60 seconds ...
, is defined by a
specific caesium-133 transition. Since 1967, the official definition of a second is:
Caesium-134
Caesium-134 has a
half-life of 2.0652 years. It is produced both directly (at a very small yield because
134Xe is stable) as a
fission product
Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the release ...
and via
neutron capture from nonradioactive
133Cs (neutron capture
cross section 29
barns), which is a common fission product. Caesium-134 is not produced via
beta decay of other fission product
nuclides of mass 134 since beta decay stops at stable
134Xe. It is also not produced by
nuclear weapons
A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions (thermonuclear bomb), producing a nuclear explosion. Both bomb ...
because
133Cs is created by beta decay of original fission products only long after the nuclear explosion is over.
The combined yield of
133Cs and
134Cs is given as 6.7896%. The proportion between the two will change with continued neutron irradiation.
134Cs also captures neutrons with a cross section of 140 barns, becoming long-lived radioactive
135Cs.
Caesium-134 undergoes
beta decay (β
−), producing
134Ba directly and emitting on average 2.23
gamma ray photons (mean energy 0.698
MeV).
Caesium-135
Caesium-135 is a mildly
radioactive isotope of caesium with a half-life of 2.3 million years. It decays via emission of a low-energy beta particle into the stable isotope barium-135. Caesium-135 is one of the seven
long-lived fission product
Long-lived fission products (LLFPs) are radioactive materials with a long half-life (more than 200,000 years) produced by nuclear fission of uranium and plutonium. Because of their persistent radiotoxicity it is necessary to isolate them from man ...
s and the only alkaline one. In most types of
nuclear reprocessing
Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the ...
, it stays with the
medium-lived fission products (including which can only be separated from Cs-135 via
isotope separation) rather than with other long-lived fission products. The low
decay energy, lack of
gamma radiation
A gamma ray, also known as gamma radiation (symbol γ or \gamma), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically s ...
, and long half-life of
135Cs make this isotope much less hazardous than
137Cs or
134Cs.
Its precursor
135Xe has a high
fission product yield (e.g. 6.3333% for
235U and
thermal neutrons) but also has the highest known
thermal neutron capture cross section of any nuclide. Because of this, much of the
135Xe produced in current
thermal reactors (as much as >90% at steady-state full power)
will be converted to extremely long-lived (half-life on the order of 10
21 years) before it can decay to despite the relatively short half life of . Little or no will be destroyed by neutron capture after a reactor shutdown, or in a
molten salt reactor that continuously removes xenon from its fuel, a
fast neutron reactor, or a nuclear weapon. The
xenon pit
The iodine pit, also called the iodine hole or xenon pit, is a temporary disabling of a nuclear reactor due to buildup of short- lived nuclear poisons in the reactor core. The main isotope responsible is 135Xe, mainly produced by natural decay of ...
is a phenomenon of excess neutron absorption through buildup in the reactor after a reduction in power or a shutdown and is often managed by letting the decay away to a level at which neutron flux can be safely controlled via
control rod
Control rods are used in nuclear reactors to control the rate of fission of the nuclear fuel – uranium or plutonium. Their compositions include chemical elements such as boron, cadmium, silver, hafnium, or indium, that are capable of absorbing ...
s again.
A nuclear reactor will also produce much smaller amounts of
135Cs from the nonradioactive fission product
133Cs by successive neutron capture to
134Cs and then
135Cs.
The thermal neutron capture cross section and
resonance integral of
135Cs are and respectively.
Disposal of
135Cs by
nuclear transmutation
Nuclear transmutation is the conversion of one chemical element or an isotope into another chemical element. Nuclear transmutation occurs in any process where the number of protons or neutrons in the nucleus of an atom is changed.
A transmutatio ...
is difficult, because of the low cross section as well as because neutron irradiation of mixed-isotope fission caesium produces more
135Cs from stable
133Cs. In addition, the intense medium-term radioactivity of
137Cs makes handling of nuclear waste difficult.
ANL factsheet
Caesium-136
Caesium-136 has a half-life of 13.16 days. It is produced both directly (at a very small yield because
136Xe is
beta-stable) as a fission product and via neutron capture from long-lived
135Cs (neutron capture cross section 8.702 barns), which is a common fission product. Caesium-136 is not produced via beta decay of other fission product nuclides of mass 136 since beta decay stops at almost-stable
136Xe. It is also not produced by nuclear weapons because
135Cs is created by beta decay of original fission products only long after the nuclear explosion is over.
136Cs also captures neutrons with a cross section of 13.00 barns, becoming medium-lived radioactive
137Cs.
Caesium-136 undergoes beta decay (β−), producing
136Ba directly.
Caesium-137
Caesium-137, with a half-life of 30.17 years, is one of the two principal
medium-lived fission products, along with
90Sr, which are responsible for most of the
radioactivity of
spent nuclear fuel after several years of cooling, up to several hundred years after use. It constitutes most of the radioactivity still left from the
Chernobyl accident
The Chernobyl disaster was a nuclear accident that occurred on 26 April 1986 at the No. 4 reactor in the Chernobyl Nuclear Power Plant, near the city of Pripyat in the north of the Ukrainian SSR in the Soviet Union. It is one of only two nu ...
and is a major health concern for decontaminating land near the
Fukushima
may refer to:
Japan
* Fukushima Prefecture, Japanese prefecture
**Fukushima, Fukushima, capital city of Fukushima Prefecture, Japan
*** Fukushima University, national university in Japan
*** Fukushima Station (Fukushima) in Fukushima, Fukushim ...
nuclear power plant.
137Cs beta decays to barium-137m (a short-lived
nuclear isomer) then to nonradioactive
barium-137, and is also a strong emitter of gamma radiation.
137Cs has a very low rate of neutron capture and cannot yet be feasibly disposed of in this way unless advances in neutron beam collimation (not otherwise achievable by magnetic fields), uniquely available only from within
muon catalyzed fusion experiments (not in the other forms of
Accelerator Transmutation of Nuclear Waste) enables production of neutrons at high enough intensity to offset and overcome these low capture rates; until then, therefore,
137Cs must simply be allowed to decay.
137Cs has been used as a
tracer
Tracer may refer to:
Science
* Flow tracer, any fluid property used to track fluid motion
* Fluorescent tracer, a substance such as 2-NBDG containing a fluorophore that is used for tracking purposes
* Histochemical tracer, a substance used for tr ...
in hydrologic studies, analogous to the use of
3H.
Other isotopes of caesium
The other isotopes have half-lives from a few days to fractions of a second.
Almost all caesium produced from nuclear fission comes from beta decay of originally more neutron-rich fission products, passing through
isotopes of iodine then
isotopes of xenon. Because these elements are volatile and can diffuse through nuclear fuel or air, caesium is often created far from the original site of fission.
References
* Isotope masses from:
**
* Isotopic compositions and standard atomic masses from:
**
**
* Half-life, spin, and isomer data selected from the following sources.
**
**
**
{{Authority control
Caesium
Caesium (IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that a ...