Cadmium nitrate describes any of the related members of a family of
inorganic compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemi ...
s with the general
formula Cd(NO3)2.\mathitH2O, the most commonly encountered form being the
tetrahydrate. The anhydrous form is volatile, but the others are colourless crystalline solids that are
deliquescent
Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substan ...
, tending to absorb enough moisture from the air to form an aqueous solution. Like other cadmium compounds, cadmium nitrate is known to be
carcinogenic
A carcinogen is any substance, radionuclide, or radiation that promotes carcinogenesis (the formation of cancer). This may be due to the ability to damage the genome or to the disruption of cellular metabolic processes. Several radioactive sub ...
.
Uses
Cadmium nitrate is used for coloring
glass
Glass is a non-Crystallinity, crystalline, often transparency and translucency, transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most ...
and
porcelain
Porcelain () is a ceramic material made by heating substances, generally including materials such as kaolinite, in a kiln to temperatures between . The strength and translucence of porcelain, relative to other types of pottery, arises main ...
[Karl-Heinz Schulte-Schrepping, Magnus Piscator "Cadmium and Cadmium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2007 Wiley-VCH, Weinheim. .] and as a
flash powder
Flash powder is a pyrotechnic composition, a mixture of oxidizer and metallic fuel, which burns quickly and produces a loud noise regardless of confinement. It is widely used in theatrical pyrotechnics and fireworks (namely salutes, e.g., cher ...
in
photography
Photography is the visual art, art, application, and practice of creating durable images by recording light, either electronically by means of an image sensor, or chemically by means of a light-sensitive material such as photographic film. It i ...
.
Preparation
Cadmium nitrate is prepared by dissolving cadmium metal or its oxide, hydroxide, or carbonate, in
nitric acid
Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available ni ...
followed by
crystallization
Crystallization is the process by which solid forms, where the atoms or molecules are highly organized into a structure known as a crystal. Some ways by which crystals form are precipitating from a solution, freezing, or more rarely de ...
:
: CdO + 2HNO
3 → Cd(NO
3)
2 + H
2O
: CdCO
3 + 2 HNO
3 → Cd(NO
3)
2 + CO
2 + H
2O
: Cd + 4 HNO
3 → 2 NO
2 + 2 H
2O + Cd(NO
3)
2
Reactions
Thermal dissociation at elevated temperatures produces
cadmium oxide and oxides of nitrogen. When
hydrogen sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The und ...
is passed through an acidified solution of cadmium nitrate, yellow
cadmium sulfide
Cadmium sulfide is the inorganic compound with the formula CdS. Cadmium sulfide is a yellow solid.Egon Wiberg, Arnold Frederick Holleman (2001''Inorganic Chemistry'' Elsevier It occurs in nature with two different crystal structures as the rare mi ...
is formed. A red modification of the sulfide is formed under boiling conditions.
When with
caustic soda
Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions .
Sodium hydroxide is a highly caustic base and alkal ...
solution, cadmium oxide forms precipitate of
cadmium hydroxide
Cadmium hydroxide is an inorganic compound with the formula Cd(OH)2. It is a white crystalline ionic compound that is a key component of nickel–cadmium battery.Karl-Heinz Schulte-Schrepping, Magnus Piscator "Cadmium and Cadmium Compounds" in U ...
. Many insoluble cadmium salts are obtained by such precipitation reactions.
References
External links
{{nitrates
Cadmium compounds
Nitrates
Deliquescent substances
IARC Group 1 carcinogens