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Heavy fuel oil (HFO) is a category of
fuel oil Fuel oil is any of various fractions obtained from the distillation of petroleum (crude oil). Such oils include distillates (the lighter fractions) and residues (the heavier fractions). Fuel oils include heavy fuel oil (bunker fuel), marine f ...
s of a tar-like consistency. Also known as bunker fuel, or residual fuel oil, HFO is the result or remnant from the distillation and cracking process of
petroleum Petroleum, also known as crude oil or simply oil, is a naturally occurring, yellowish-black liquid chemical mixture found in geological formations, consisting mainly of hydrocarbons. The term ''petroleum'' refers both to naturally occurring un ...
. For this reason, HFO contains several different compounds that include
aromatics Aromatic compounds or arenes are organic compounds "with a chemistry typified by benzene" and "cyclically conjugated." The word "aromatic" originates from the past grouping of molecules based on odor, before their general chemical properties were ...
,
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
, and
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
, making emissions upon combustion more polluting compared to other fuel oils. HFO is predominantly used as a fuel source for marine vessel propulsion using
marine diesel engines Marine is an adjective meaning of or pertaining to the sea or ocean. Marine or marines may refer to: Ocean * Maritime (disambiguation) * Marine art * Marine biology * Marine current power * Marine debris * Marine energy * Marine habitats * ...
due to its relatively low cost compared to cleaner fuel sources such as distillates. The use and carriage of HFO on-board vessels presents several environmental concerns, namely the risk of
oil spill An oil spill is the release of a liquid petroleum hydrocarbon into the environment, especially the marine ecosystem, due to human activity, and is a form of pollution. The term is usually given to marine oil spills, where oil is released into th ...
and the emission of toxic compounds and
particulates Particulate matter (PM) or particulates are microscopic particles of solid or liquid matter suspension (chemistry), suspended in the atmosphere of Earth, air. An ''aerosol'' is a mixture of particulates and air, as opposed to the particulate ...
including
black carbon Black carbon (BC) is the light-absorbing refractory form of Chemical_element, elemental carbon remaining after pyrolysis (e.g., charcoal) or produced by incomplete combustion (e.g., soot). Tihomir Novakov originated the term black carbon in ...
. The use of HFOs is banned as a fuel source for ships travelling in the Antarctic as part of the
International Maritime Organization The International Maritime Organization (IMO; ; ) is a List of specialized agencies of the United Nations, specialized agency of the United Nations responsible for regulating maritime transport. The IMO was established following agreement at a ...
's (IMO) International Code for Ships Operating in Polar Waters (Polar Code). For similar reasons, an HFO ban in Arctic waters is currently being considered.


Heavy fuel oil characteristics

HFO consists of the remnants or residual of petroleum sources once the
hydrocarbons In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic; their odor is usually faint, and may b ...
of higher quality are extracted via processes such as thermal and catalytic cracking. Thus, HFO is also commonly referred to as residual fuel oil. The chemical composition of HFO is highly variable due to the fact that HFO is often mixed or blended with cleaner fuels; blending streams can include carbon numbers from C20 to greater than C50. HFOs are blended to achieve certain
viscosity Viscosity is a measure of a fluid's rate-dependent drag (physics), resistance to a change in shape or to movement of its neighboring portions relative to one another. For liquids, it corresponds to the informal concept of ''thickness''; for e ...
and flow characteristics for a given use. As a result of the wide compositional spectrum, HFO is defined by processing, physical and final use characteristics. Being the final remnant of the cracking process, HFO also contains mixtures of the following compounds to various degrees: "paraffins, cycloparaffins, aromatics, olefins, and asphaltenes as well as molecules containing sulfur, oxygen, nitrogen and/or organometals". HFO is characterized by a maximum density of 1010 kg/m3 at 15°C, and a maximum viscosity of 700 mm2/s (cSt) at 50°C according to ISO 8217.


Combustion and atmospheric reactions

Given HFO's elevated sulfur contamination (maximum of 5% by mass), the combustion reaction results in the formation of sulfur dioxide SO2.


Heavy fuel oil use and shipping

Since the middle of the 20th century, HFO has been used primarily by the
shipping industry Maritime transport (or ocean transport) or more generally waterborne transport, is the transport of people (passengers or goods (cargo) via waterways. Freight transport by watercraft has been widely used throughout recorded history, as it provi ...
due to its low cost compared with all other fuel oils, being up to 30% less expensive, as well as the historically lax regulatory requirements for emissions of
nitrogen oxides In atmospheric chemistry, is shorthand for nitric oxide () and nitrogen dioxide (), the nitrogen oxides that are most relevant for air pollution. These gases contribute to the formation of smog and acid rain, as well as affecting tr ...
(NOx) and
sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a colorless gas with a pungent smell that is responsible for the odor of burnt matches. It is r ...
(SO2) by the IMO. For these two reasons, HFO is the single most widely used engine fuel oil on-board ships. Data available until 2007 for global consumption of HFO at the international marine sector reports total fuel oil usages of 200 million tonnes, with HFO consumption accounting for 174 million tonnes. Data available until 2011 for fuel oil sales to the international marine shipping sector reports 207.5 million tonnes total fuel oil sales with HFO accounting for 177.9 million tonnes. Marine vessels can use a variety of different fuels for the purpose of propulsion, which are divided into two broad categories: residual oils or distillates. In contrast to HFOs, distillates are the petroleum products created through refining crude oil and include diesel, kerosene, naphtha and gas. Residual oils are often combined to various degrees with distillates to achieve desired properties for operational and/or environmental performance. Table 1 lists commonly used categories of marine fuel oil and mixtures; all mixtures including the low sulfur marine fuel oil are still considered HFO.


Arctic environmental concerns

The use and carriage of HFO in the Arctic is a commonplace marine industry practice. In 2015, over 200 ships entered Arctic waters carrying a total of 1.1 million tonnes of fuel with 57% of fuel consumed during Arctic voyages being HFO. In the same year, trends in carriage of HFO were reported to be 830,000 tonnes, representing a significant growth from the reported 400,000 tonnes in 2012. A report in 2017 by Norwegian Type Approval body DNV GL (Det Norske Veritas) calculated the total fuel use of HFO by mass in the Arctic to be over 75% with larger vessels being the main consumers. In light of increased area traffic and given that the Arctic is considered to be a sensitive ecological area with a higher response intensity to climate change, the environmental risks posed by HFO present concern for environmentalists and governments in the area. The two main environmental concerns for HFO in the Arctic are the risk of spill or accidental discharge and the emission of black carbon as a result of HFO consumption.


Environmental impacts of heavy fuel oil spills

Due to its very high viscosity and elevated density, HFO released into the environment is a greater threat to flora and fauna compared to distillate or other residual fuels. In 2009, the Arctic Council identified the spill of oil in the Arctic as the greatest threat to the local marine environment. Being the remnant of the distillation and cracking processes, HFO is characterized by an elevated overall toxicity compared to all other fuels. Its viscosity prevents breakdown into the environment, a property exacerbated by the cold temperatures in the Arctic resulting in the formation of tar-lumps, and an increase in volume through emulsification. Its density, tendency to persist and emulsify can result in HFO polluting both the water column and seabed.


History of major HFO spills from 2000 onward

The following HFO specific spills have occurred since the year 2000. The information is organized according to year and ship name and includes amount released and the spill location: * 2000 Janra, Germany (40 tons in the
Sea of Åland The Åland Sea (or the Sea of Åland; , ) is a waterway in the southern Gulf of Bothnia, between Åland and Sweden. It connects the Bothnian Sea with the Baltic Proper, Baltic Sea proper. The western part of the basin is in Swedish territorial w ...
) * 2001 Baltic Carrier, Marshall Islands (2350 tons in the Baltic Sea) * 2002 ''Prestige'' oil spill, Spain (17.8 million gallons in
Atlantic Ocean The Atlantic Ocean is the second largest of the world's five borders of the oceans, oceanic divisions, with an area of about . It covers approximately 17% of Earth#Surface, Earth's surface and about 24% of its water surface area. During the ...
) * 2003 Fu Shan Hai, China (1,680 tons in the
Baltic Sea The Baltic Sea is an arm of the Atlantic Ocean that is enclosed by the countries of Denmark, Estonia, Finland, Germany, Latvia, Lithuania, Poland, Russia, Sweden, and the North European Plain, North and Central European Plain regions. It is the ...
) * 2004 Selendang Ayu, Malaysia (336,000 gallons in Unalaska Island - near Arctic) * 2009 Full City, Panama (6,300-9,500 gallons in Langesund) * 2011 Godafoss, Malaysia (200,000 gallons in Hvaler Islands) * 2011 Golden Traded (205 tons in
Skagerrak The Skagerrak (; , , ) is a strait running between the North Jutlandic Island of Denmark, the east coast of Norway and the west coast of Sweden, connecting the North Sea and the Kattegat sea. The Skagerrak contains some of the busiest shipping ...
)


Environmental impacts of heavy fuel oil use

The combustion of HFO in ship engines results in the highest amount of
black carbon Black carbon (BC) is the light-absorbing refractory form of Chemical_element, elemental carbon remaining after pyrolysis (e.g., charcoal) or produced by incomplete combustion (e.g., soot). Tihomir Novakov originated the term black carbon in ...
emissions compared to all other fuels. The choice of marine fuel is the most important determinant of ship engine emission factors for black carbon. The second most important factor in the emission of black carbon is the ship load size, with emission factors of black carbon increasing up to six times given low engine loads. Black carbon is the product of incomplete combustion and a component of soot and fine particulate matter (<2.5 μg). It has a short atmospheric lifetime of a few days to a week and is typically removed upon precipitation events. Although there has been debate concerning the
radiative forcing Radiative forcing (or climate forcing) is a concept used to quantify a change to the balance of energy flowing through a planetary atmosphere. Various factors contribute to this change in energy balance, such as concentrations of greenhouse gases ...
of black carbon, combinations of ground and satellite observations suggest a global solar absorption of 0.9W·m−2, making it the second most important climate forcer after CO2. Black carbon affects the climate system by: decreasing the snow/ice albedo through dark soot deposits and increasing snowmelt timing, reducing the planetary albedo through absorption of solar radiation reflected by the cloud systems, earth surface and atmosphere, as well as directly decreasing cloud albedo with black carbon contamination of water and ice found therein. The greatest increase in Arctic surface temperature per unit of black carbon emissions results from the decrease in snow/ice albedo which makes Arctic specific black carbon release more detrimental than emissions elsewhere.


IMO and the Polar Code

The International Maritime Organization (IMO), a specialized arm of the
United Nations The United Nations (UN) is the Earth, global intergovernmental organization established by the signing of the Charter of the United Nations, UN Charter on 26 June 1945 with the stated purpose of maintaining international peace and internationa ...
, adopted into force on 1 January 2017 the International Code for Ships Operating in Polar Waters or Polar Code. The requirements of the Polar Code are mandatory under both the International Convention for the Prevention of Pollution from Ships (MARPOL) and the International Convention for the Safety of Life at Sea (SOLAS). The two broad categories covered by the Polar Code include safety and pollution prevention related to navigation in both Arctic and Antarctic polar waters. The carriage and use of HFO in the Arctic is discouraged by the Polar Code while being banned completely from the Antarctic under MARPOL Annex I regulation 43. The ban of HFO use and carriage in the Antarctic precedes the adoption of the Polar Code. At its 60th session (26 March 2010), The Marine Environmental Protection Committee (MEPC) adopted Resolution 189(60) which went into effect in 2011 and prohibits fuels of the following characteristics:
# crude oils having a density at 15°C higher than 900 kg/m3 ; # oils, other than crude oils, having a density at 15°C higher than 900 kg/m3 or a kinematic viscosity at 50°C higher than 180 mm2/s; or #
bitumen Bitumen ( , ) is an immensely viscosity, viscous constituent of petroleum. Depending on its exact composition, it can be a sticky, black liquid or an apparently solid mass that behaves as a liquid over very large time scales. In American Engl ...
, tar and their emulsions.
IMO's Marine Environmental Protection Committee (MEPC) tasked the Pollution Prevention Response Sub-Committee (PPR) to enact a ban on the use and carriage of heavy fuel in Arctic waters at its 72nd and 73rd sessions. This task is also accompanied by a requirement to properly define HFO taking into account its current definition under MARPOL Annex I regulation 43. The adoption of the ban is anticipated for 2021, with widespread implementation by 2023.


Resistance to heavy fuel oil phase-out

The Clean Arctic Alliance was the first IMO delegate nonprofit organization to campaign against the use of HFO in Arctic waters. However, the phase-out and ban of HFO in the Arctic was formally proposed to MEPC by eight countries in 2018: Finland, Germany, Iceland, the Netherlands, New Zealand, Norway, Sweden and the United States. Although these member states continue to support the initiative, several countries have been vocal about their resistance to an HFO ban on such a short time scale. The Russian Federation has expressed concern for impacts to the maritime shipping industry and trade given the relatively low cost of HFO. Russia instead suggested the development and implementation of mitigation measures for the use and carriage of HFO in Arctic waters. Canada and Marshall Islands have presented similar arguments, highlighting the potential impacts on Arctic communities (namely remote indigenous populations) and economies. To appease concerns and resistance, at its 6th session in February 2019, the PPR sub-committee working group developed a "draft methodology for analyzing impacts" of HFO to be finalized at PPR's 7th session in 2020. The purpose of the methodology being to evaluate the ban according to its economic and social impacts on Arctic indigenous communities and other local communities, to measure anticipated benefits to local ecosystems, and potentially consider other factors that could be positively or negatively affected by the ban.


See also

* Mazut


References

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