Brammallite
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Brammallite is a sodium rich analogue of
illite Illite, also called hydromica or hydromuscovite, is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandw ...
. First described in 1943 for an occurrence in
Llandybie Llandybie ( , " Saint Tybie's church") is a village and community in Carmarthenshire, Wales, with the village being situated north of Ammanford. According to the United Kingdom Census 2001, Llandybie village itself is home to a population of 3 ...
, Wales, it was named for
British British may refer to: Peoples, culture, and language * British people, nationals or natives of the United Kingdom, British Overseas Territories and Crown Dependencies. * British national identity, the characteristics of British people and culture ...
geologist A geologist is a scientist who studies the structure, composition, and History of Earth, history of Earth. Geologists incorporate techniques from physics, chemistry, biology, mathematics, and geography to perform research in the Field research, ...
and
mineralogist Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical mineralogy, optical) properties of minerals and mineralized artifact (archaeology), artifacts. Specific s ...
Alfred Brammall (1879–1954). Believed to be a degradation product of
paragonite Paragonite is a mineral, related to muscovite. Its empirical formula is . A wide solvus separates muscovite from paragonite, such that there is little solid solution along the vector Na+ K+ and apparent micas of intermediate composition is most ...
through the process of Na leaching, though can also occur when
muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavage y ...
, or other aluminous materials are altered. Just as illite it is a non-expanding, non-plastic,
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impuriti ...
-sized, micaceous mineral. Brammallite is a
phyllosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...
or layered silicate. Structurally, brammallite is quite similar to
muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavage y ...
or
sericite Sericite is the name given to very fine, ragged grains and Aggregate (geology), aggregates of white (colourless) micas, typically made of muscovite, illite, or paragonite. Sericite is produced by the alteration of orthoclase or plagioclase feldsp ...
with slightly more
silicon Silicon is a chemical element; it has symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic lustre, and is a tetravalent metalloid (sometimes considered a non-metal) and semiconductor. It is a membe ...
,
magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
,
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
, and water and slightly less tetrahedral
aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
and interlayer
potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...
. It occurs as aggregates of small
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in t ...
white crystals. Due to the small size, positive identification usually requires
x-ray diffraction X-ray diffraction is a generic term for phenomena associated with changes in the direction of X-ray beams due to interactions with the electrons around atoms. It occurs due to elastic scattering, when there is no change in the energy of the waves. ...
analysis. Similar to illite, it can be used as a flux in high fire ceramic bodies due to its high insoluble sodium content, but unlike common Na containing fluxes (i.e. feldspar) it has the advantages of its extremely small clay-sized particles that necessitate the need for grinding yet has the unique feature of being a clay but not expanding or becoming plastic with water. All of which it shares with illite, with the difference being their contents of corresponding sodium or potassium amounts.


References

Phyllosilicates Potassium minerals Aluminium minerals Magnesium minerals Monoclinic minerals {{silicate-mineral-stub