Boulangerite
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Boulangerite or ''antimonbleiblende'' is an uncommon
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in t ...
orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic Lattice (group), lattices result from stretching a cubic crystal system, cubic lattice along two of its orthogonal pairs by two different factors, res ...
sulfosalt mineral,
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
antimony Antimony is a chemical element; it has chemical symbol, symbol Sb () and atomic number 51. A lustrous grey metal or metalloid, it is found in nature mainly as the sulfide mineral stibnite (). Antimony compounds have been known since ancient t ...
sulfide Sulfide (also sulphide in British English) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to large families o ...
, formula Pb5Sb4S11.Mineralienatlas
/ref> It was named in 1837 in honor of French mining engineer Charles Boulanger (1810–1849),http://www.mindat.org/min-738.html Mindat and had been a valid species since pre- IMA. It was first described prior to 1959, and is now grandfathered.http://webmineral.com/data/Boulangerite.shtml Webmineral data


Properties

Boulangerite was considered to be a really rare mineral until later they found numerous ore deposits of said mineral. Nowadays it is considered as an uncommon mineral, which is rather cheap, with a color of light blue to black to grey. The dust of the mineral is black. Pseudohexagonal shape is common for this mineral. It forms rings rarely. It is the homeotype of lopatkaite. The strong subcell is orthorhombic, and has a halved c. It forms small, elongated prismic or fine, needle-like crystals. Each crystal can grow up to a few centimeters, and crystals can only be told apart in either an enlarged photo or from under a microscope, as it is almost as thin and fine as hair is. One of its unique properties is the parallel fibers to the direction of the elongation, although fibrous-radial, feathery masses are not uncommon as well. In other words, it is plumose, meaning aggregates form plume-like shapes. The latter is the so-called plumosite variant of the mineral, the name derived from the aggregates being plumose, though it can occur in felt-like fibrous or in thick granular clusters as well. The luster of it is always either matte blueish-grey or metallic lead-grey. It is a really heavy, though soft mineral, which is easily breakable, though it cannot be scratched by using fingernails due to the same hardness (2.5–3). The mineral being heavy although being soft is due to its compact mass. The cleavage is generally good. In case of the fibrous type, the fibers are flexible. It is an opaque mineral. The melting point of it is really low, 1 on the Kobell fusibility-scale, which is around 525 in °C. This is the point, where the mineral is the easiest to fuse or at which temperature it melts. It is completely soluble in
hydrogen chloride The Chemical compound, compound hydrogen chloride has the chemical formula and as such is a hydrogen halide. At room temperature, it is a colorless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hyd ...
. During the reaction with
hydrochloric acid Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ...
, it creates
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist ...
. In
nitric acid Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most com ...
, it is partially soluble. It has a distinct anisotropism, and shows weak pleochroic attributes. Common impurities include iron, copper, tin and zinc. It mostly consists of lead (54.88%) thus it can be used as a lead ore, but the other main components are antimony (26.44%) (which is also why the mineral typically forms in antimony deposits) and sulfur (18.68%).


Formation

It typically forms in association of lead, zinc or
antimony Antimony is a chemical element; it has chemical symbol, symbol Sb () and atomic number 51. A lustrous grey metal or metalloid, it is found in nature mainly as the sulfide mineral stibnite (). Antimony compounds have been known since ancient t ...
deposits, in a
lode In geology, a lode is a deposit of metalliferous ore that fills or is embedded in a fracture (or crack) in a rock formation or a vein of ore that is deposited or embedded between layers of rock. The current meaning (ore vein) dates from th ...
ic environment. It can also be found in company of
metamorphic rocks Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock ( protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
as well, in the Apuan alps as well for instance. The specimens that get formed on these metamorphic rocks appear in the form of fine, crystal needles. It is also usually found with other
sulfide Sulfide (also sulphide in British English) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to large families o ...
s as well, like with arsenopyrite,
pyrrhotite Pyrrhotite (''Pyrrhus of Epirus, pyrrhos'' in Greek language, Greek meaning "flame-coloured"'')'' is an iron sulfide mineral with the formula Fe(1−x)S (x = 0 to 0.125). It is a nonstoichiometric compound, nonstoichiometric variant of FeS, th ...
,
galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crysta ...
or
sphalerite Sphalerite is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimentary exhalative, Carbonate-hoste ...
, but is also can occur with
siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). Its name comes from the Ancient Greek word (), meaning "iron". A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus. Zinc, magnesium, and manganese commonly ...
s,
dolomites The Dolomites ( ), also known as the Dolomite Mountains, Dolomite Alps or Dolomitic Alps, are a mountain range in northeastern Italy. They form part of the Southern Limestone Alps and extend from the River Adige in the west to the Piave Va ...
and
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
es. It may occur in intergrowths with jamesonite and meneghinite, quartz or sphalerite. Usual finding places include Germany, Switzerland, Canada, the Czech republic, the old Yugoslavia, the Ural region in Russia, and from the british park city mines in Utah. The most known finding places include the
Gutin mountains The Gutin Mountains (; ; ) are a mountain range within the Vihorlat-Gutin Area of the Inner Eastern Carpathians. They are centered in Maramureș County in Romania, bordering Satu Mare County, and also stretching further towards northwest as the Oa ...
, more specifically Herja, Baia Mare, Baia Sprie, although it appears in greater quantities at the Slovak Ore Mountains (Spišsko-gemerské rudohorie), specifically
Čučma Čučma () is a village and municipality in the Rožňava District in the Košice Region of eastern Slovakia. History In historical records the village was first mentioned in 1300. Before the establishment of independent Czechoslovakia in 1918 ...
and Zlatá Idka. A small few specimens can be found in Hungary, in the Gyöngyösoroszi ore mine, in French at
Provence Provence is a geographical region and historical province of southeastern France, which stretches from the left bank of the lower Rhône to the west to the France–Italy border, Italian border to the east; it is bordered by the Mediterrane ...
, and as mentioned above, in Italy, it can be found in the tuscan Apuan alps, in the Bottino mine, but it rarely occurs in carrara
marble Marble is a metamorphic rock consisting of carbonate minerals (most commonly calcite (CaCO3) or Dolomite (mineral), dolomite (CaMg(CO3)2) that have recrystallized under the influence of heat and pressure. It has a crystalline texture, and is ty ...
as well.


Identification and usage

At first glance, it is hard to differentiate boulangerite from zinkenite or jamesonite, so proper equipment is crucial for the identification. In the structure, there are interconnected SbS3 groups like in zinkenite, jamesonite and robinsonite. The smaller, and beautiful needle-like crystals attract a lot of collector's glimpses. As for the economical usage of boulangerite, it can be used up as a lead ore. The usage of said mineral is only reasonable when it appears in extended enough, quarriable deposits.


References

{{Reflist Lead minerals Antimony minerals Sulfosalt minerals Orthorhombic minerals Blendes Minerals in space group 62