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The Bonnington Chemical Works was a pioneer
coal tar Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoria ...
processing plant established in
Edinburgh Edinburgh is the capital city of Scotland and one of its 32 Council areas of Scotland, council areas. The city is located in southeast Scotland and is bounded to the north by the Firth of Forth and to the south by the Pentland Hills. Edinburgh ...
. It was perhaps the first successful independent facility established for the integrated treatment of
gasworks A gasworks or gas house is an industrial plant for the production of flammable gas. Many of these have been made redundant in the developed world by the use of natural gas, though they are still used for storage space. Early gasworks Coal ...
waste, and
manufactured Manufacturing is the creation or production of goods with the help of equipment, labor, machines, tools, and chemical or biological processing or formulation. It is the essence of the secondary sector of the economy. The term may refer to a ...
the residues of the Edinburgh gasworks into useful products for over half a century.


History

Gas lighting Gas lighting is the production of artificial light from combustion of a fuel gas such as methane, propane, butane, acetylene, ethylene, hydrogen, carbon monoxide, coal gas (town gas) or natural gas. The light is produced either directly by ...
was introduced in Edinburgh in 1818. The production of
coal gas Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. It is produced when coal is heated strongly in the absence of air. Town gas is a more general term referring to manufactured gaseous ...
generated considerable residues of
coal tar Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoria ...
and ammoniacal liquor which were further processed at the Bonnington Chemical Works. The Bonnington facility was located on Newhaven Road in Bonnington (between Edinburgh and
Leith Leith (; ) is a port area in the north of Edinburgh, Scotland, founded at the mouth of the Water of Leith and is home to the Port of Leith. The earliest surviving historical references are in the royal charter authorising the construction of ...
) near the south bank of the
Water of Leith The Water of Leith (Scottish Gaelic: ''Uisge Lìte'') is the main river flowing through central Edinburgh, Scotland, that starts in the Pentlands Hills and flows into the port of Leith and then into the sea via the Firth of Forth. Name The ...
. George Dixon Longstaff recorded that the chemical works began in 1822 for the purpose of
distilling Distillation, also classical distillation, is the process of separating the component substances of a liquid mixture of two or more chemically discrete substances; the separation process is realized by way of the selective boiling of the mixt ...
coal tar to separate
naphtha Naphtha (, recorded as less common or nonstandard in all dictionaries: ) is a flammable liquid hydrocarbon mixture. Generally, it is a fraction of crude oil, but it can also be produced from natural-gas condensates, petroleum distillates, and ...
. This was supplied to
Charles Macintosh Charles Macintosh FRS (29 December 1766 – 25 July 1843) was a Scottish chemist and the inventor of the modern waterproof raincoat. The Mackintosh raincoat (the variant spelling is now standard) is named after him. Biography Macintosh was ...
for him to make waterproof fabrics, as epitomised by the
Mackintosh The Mackintosh raincoat (abbreviated as mac) is a form of waterproof raincoat, first sold in 1824, made of rubberised textile, fabric. The Mackintosh is named after its Scotland, Scottish inventor Charles Macintosh, although many writers adde ...
. Longstaff was at that time assistant to Dr John Wilson Anderson, who taught practical chemistry at the
University of Edinburgh The University of Edinburgh (, ; abbreviated as ''Edin.'' in Post-nominal letters, post-nominals) is a Public university, public research university based in Edinburgh, Scotland. Founded by the City of Edinburgh Council, town council under th ...
. When Anderson resigned from the university to concentrate on his growing chemical plant, Longstaff took his academic post. By 1830, the factory was making and selling naphtha, pitch oil (later called
creosote Creosote is a category of carbonaceous chemicals formed by the distillation of various tars and pyrolysis of plant-derived material, such as wood, or fossil fuel. They are typically used as preservatives or antiseptics. Some creosote types w ...
), pitch, and lampblack (
carbon black Carbon black (with subtypes acetylene black, channel black, furnace black, lamp black and thermal black) is a material produced by the incomplete combustion of coal tar, vegetable matter, or petroleum products, including fuel oil, fluid cataly ...
) from the coal tar, while the ammoniacal liquor was processed into sal ammoniac (
ammonium chloride Ammonium chloride is an inorganic chemical compound with the chemical formula , also written as . It is an ammonium salt of hydrogen chloride. It consists of ammonium cations and chloride anions . It is a white crystalline salt (chemistry), sal ...
). Anderson also made the
sulphuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formu ...
and
hydrochloric acid Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ...
he needed in processing and sold the associated products
magnesium carbonate Magnesium carbonate, (archaic name magnesia alba), is an inorganic salt that is a colourless or white solid. Several hydrated and Base (chemistry), basic forms of magnesium carbonate also exist as minerals. Forms The most common magnesium car ...
and sodium sulphate. Anderson believed he was the first in Britain to commence making black ash and soda ash (
sodium carbonate Sodium carbonate (also known as washing soda, soda ash, sal soda, and soda crystals) is the inorganic compound with the formula and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water ...
) using the
Leblanc process The Leblanc process was an early industrial process for making ''soda ash'' ( sodium carbonate) used throughout the 19th century, named after its inventor, Nicolas Leblanc. It involved two stages: making sodium sulfate from sodium chloride, fol ...
when the salt tax was repealed in 1823. For some years he also made
soap Soap is a salt (chemistry), salt of a fatty acid (sometimes other carboxylic acids) used for cleaning and lubricating products as well as other applications. In a domestic setting, soaps, specifically "toilet soaps", are surfactants usually u ...
. Macintosh remained a special customer until at least the late 1830s, and probably well beyond, receiving a significant discount on his large naphtha orders. When Anderson died in 1835, his brother-in-law Thomas Astley (son of chemical manufacturer Joseph Astley) took on the management of the plant and introduced the further products ammonium sulphate fertiliser and
asphalt Asphalt most often refers to: * Bitumen, also known as "liquid asphalt cement" or simply "asphalt", a viscous form of petroleum mainly used as a binder in asphalt concrete * Asphalt concrete, a mixture of bitumen with coarse and fine aggregates, u ...
road surfacing. In 1847, the works was taken over by John Tennant and John Tennent, who had both been close associates of Macintosh. Tennant was the eldest son of industrialist
Charles Tennant Charles Tennant (3 May 1768 – 1 October 1838) was a Scottish chemist and industrialist. He discovered Calcium hypochlorite, bleaching powder and founded an industrial dynasty. Biography Charles Tennant was born at Laigh Corton, Alloway, Ayrs ...
, and Tennent was of the Tennent family who ran Wellpark Brewery. The firm became one of the Tennant group of companies. They added to the product line sodium sulphite and sodium thiosulphate (which they sold as
antichlor An antichlor is a substance used to decompose residual hypochlorite or chlorine after chlorine-based bleaching, in order to prevent ongoing reactions with, and therefore damage to, the material that has been bleached. Antichlors include sodium bi ...
) and copper sulphide marine
anti-fouling paint Anti-fouling paint is a specialized category of coatings applied as the outer (outboard) layer to the hull of a ship or boat, to slow the growth of and facilitate detachment of subaquatic organisms that attach to the hull and can affect a ve ...
. The large scale of processing precipitated the construction of a
pipeline A pipeline is a system of Pipe (fluid conveyance), pipes for long-distance transportation of a liquid or gas, typically to a market area for consumption. The latest data from 2014 gives a total of slightly less than of pipeline in 120 countries ...
to pump the gasworks residues directly from Edinburgh to Bonnington over
Calton Hill Calton Hill (; ) is a hill in central Edinburgh, Scotland, situated beyond the east end of Princes Street and included in the city's United Nations Educational, Scientific and Cultural Organization, UNESCO World Heritage Site. Views of, and f ...
. Tennent's brother-in-law Dr
Edmund Ronalds Edmund Ronalds FCS FRSE (18 June 1819 – 9 September 1889) was an English academic and industrial chemist.  He was co-author of a seminal series of books on chemical technology that helped begin university teaching of chemical applications for ...
took over the management of the plant in 1856. He retained most of the existing products and conducted further distillations to make
benzene Benzene is an Organic compound, organic chemical compound with the Chemical formula#Molecular formula, molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar hexagonal Ring (chemistry), ring with one hyd ...
and also coke oil and coke. Products were shipped as far as Russia and America. He commissioned a new
acid An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis ...
plant in which sulphuric and hydrochloric acids and sulphurous acid gas were made and introduced
waste Waste are unwanted or unusable materials. Waste is any substance discarded after primary use, or is worthless, defective and of no use. A by-product, by contrast is a joint product of relatively minor Value (economics), economic value. A wast ...
gas capture equipment and a large new chimney to reduce emissions. The facility now occupied close to three acres. The plant was closed in 1878 after Ronalds had suffered chronic ill health for some years.


References

{{coord, 55.970903, -3.186236, type:landmark_region:GB, display=title Buildings and structures in Edinburgh Chemical plants of the United Kingdom 1822 establishments in Scotland