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physics Physics is the scientific study of matter, its Elementary particle, fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge whi ...
, complementarity is a conceptual aspect of
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
that
Niels Bohr Niels Henrik David Bohr (, ; ; 7 October 1885 – 18 November 1962) was a Danish theoretical physicist who made foundational contributions to understanding atomic structure and old quantum theory, quantum theory, for which he received the No ...
regarded as an essential feature of the theory. The complementarity principle holds that certain pairs of complementary properties cannot all be observed or measured simultaneously. For example, position and momentum, frequency and lifetime, or optical phase and photon number. In contemporary terms, complementarity encompasses both the
uncertainty principle The uncertainty principle, also known as Heisenberg's indeterminacy principle, is a fundamental concept in quantum mechanics. It states that there is a limit to the precision with which certain pairs of physical properties, such as position a ...
and wave-particle duality. Bohr considered one of the foundational truths of quantum mechanics to be the fact that setting up an experiment to measure one quantity of a pair, for instance the position of an
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary charge, elementary electric charge. It is a fundamental particle that comprises the ordinary matter that makes up the universe, along with up qua ...
, excludes the possibility of measuring the other, yet understanding both experiments is necessary to characterize the object under study. In Bohr's view, the behavior of atomic and subatomic objects cannot be separated from the measuring instruments that create the context in which the measured objects behave. Consequently, there is no "single picture" that unifies the results obtained in these different experimental contexts, and only the "totality of the phenomena" together can provide a completely informative description.


History


Background

Complementarity as a physical model derives from Niels Bohr's 1927 lecture during the Como Conference in Italy, at a scientific celebration of the work of
Alessandro Volta Alessandro Giuseppe Antonio Anastasio Volta (, ; ; 18 February 1745 – 5 March 1827) was an Italian chemist and physicist who was a pioneer of electricity and Power (physics), power, and is credited as the inventor of the electric battery a ...
100 years previous. Bohr's subject was complementarity, the idea that measurements of quantum events provide complementary information through seemingly contradictory results. While Bohr's presentation was not well received, it did crystallize the issues ultimately leading to the modern wave-particle duality concept. The contradictory results that triggered Bohr's ideas had been building up over the previous 20 years. This contradictory evidence came both from light and from electrons. The
wave theory of light In physics, physical optics, or wave optics, is the branch of optics that studies interference, diffraction, polarization, and other phenomena for which the ray approximation of geometric optics is not valid. This usage tends not to include effec ...
, broadly successful for over a hundred years, had been challenged by
Planck Max Karl Ernst Ludwig Planck (; ; 23 April 1858 – 4 October 1947) was a German theoretical physicist whose discovery of energy quanta won him the Nobel Prize in Physics in 1918. Planck made many substantial contributions to theoretical p ...
's 1901 model of
blackbody radiation Black-body radiation is the thermal electromagnetic radiation within, or surrounding, a body in thermodynamic equilibrium with its environment, emitted by a black body (an idealized opaque, non-reflective body). It has a specific continuous spectr ...
and
Einstein Albert Einstein (14 March 187918 April 1955) was a German-born theoretical physicist who is best known for developing the theory of relativity. Einstein also made important contributions to quantum mechanics. His mass–energy equivalence f ...
's 1905 interpretation of the
photoelectric effect The photoelectric effect is the emission of electrons from a material caused by electromagnetic radiation such as ultraviolet light. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physi ...
. These theoretical models use discrete energy, a
quantum In physics, a quantum (: quanta) is the minimum amount of any physical entity (physical property) involved in an interaction. The fundamental notion that a property can be "quantized" is referred to as "the hypothesis of quantization". This me ...
, to describe the interaction of light with matter. Despite confirmation by various experimental observations, the
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless particles that can ...
theory (as it came to be called later) remained controversial until
Arthur Compton Arthur Holly Compton (September 10, 1892 – March 15, 1962) was an American particle physicist who won the 1927 Nobel Prize in Physics for his discovery of the Compton effect, which demonstrated the particle nature of electromagnetic radiati ...
performed a series of experiments from 1922 to 1924 demonstrating the momentum of light. The experimental evidence of particle-like momentum seemingly contradicted other experiments demonstrating the wave-like interference of light. The contradictory evidence from electrons arrived in the opposite order. Many experiments by J. J. Thompson,
Robert Millikan Robert Andrews Millikan ( ; March 22, 1868 – December 19, 1953) was an American physicist who received the Nobel Prize in Physics in 1923 "for his work on the elementary charge of electricity and on the photoelectric effect". Millikan gradua ...
, and Charles Wilson, among others, had shown that free electrons had particle properties. However, in 1924,
Louis de Broglie Louis Victor Pierre Raymond, 7th Duc de Broglie (15 August 1892 – 19 March 1987) was a French theoretical physicist and aristocrat known for his contributions to quantum theory. In his 1924 PhD thesis, he postulated the wave nature of elec ...
proposed that electrons had an associated wave and Schrödinger demonstrated that wave equations accurately account for electron properties in atoms. Again some experiments showed particle properties and others wave properties. Bohr's resolution of these contradictions is to accept them. In his Como lecture he says: "our interpretation of the experimental material rests essentially upon the classical concepts." Direct observation being impossible, observations of quantum effects are necessarily classical. Whatever the nature of quantum events, our only information will arrive via classical results. If experiments sometimes produce wave results and sometimes particle results, that is the nature of light and of the ultimate constituents of matter.


Bohr's lectures

Niels Bohr apparently conceived of the principle of complementarity during a skiing vacation in Norway in February and March 1927, during which he received a letter from
Werner Heisenberg Werner Karl Heisenberg (; ; 5 December 1901 – 1 February 1976) was a German theoretical physicist, one of the main pioneers of the theory of quantum mechanics and a principal scientist in the German nuclear program during World War II. He pub ...
regarding an as-yet-unpublished result, a thought experiment about a microscope using gamma rays. This thought experiment implied a tradeoff between uncertainties that would later be formalized as the
uncertainty principle The uncertainty principle, also known as Heisenberg's indeterminacy principle, is a fundamental concept in quantum mechanics. It states that there is a limit to the precision with which certain pairs of physical properties, such as position a ...
. To Bohr, Heisenberg's paper did not make clear the distinction between a position measurement merely disturbing the momentum value that a particle carried and the more radical idea that momentum was meaningless or undefinable in a context where position was measured instead. Upon returning from his vacation, by which time Heisenberg had already submitted his paper for publication, Bohr convinced Heisenberg that the uncertainty tradeoff was a manifestation of the deeper concept of complementarity. Heisenberg duly appended a note to this effect to his paper, before its publication, stating:
Bohr has brought to my attention
hat A hat is a Headgear, head covering which is worn for various reasons, including protection against weather conditions, ceremonial reasons such as university graduation, religious reasons, safety, or as a fashion accessory. Hats which incorpor ...
the uncertainty in our observation does not arise exclusively from the occurrence of discontinuities, but is tied directly to the demand that we ascribe equal validity to the quite different experiments which show up in the articulatetheory on one hand, and in the wave theory on the other hand.
Bohr publicly introduced the principle of complementarity in a lecture he delivered on 16 September 1927 at the International Physics Congress held in
Como, Italy Como (, ; , or ; ) is a city and (municipality) in Lombardy, Italy. It is the administrative capital of the Province of Como. Nestled at the southwestern branch of the picturesque Lake Como, the city is a renowned tourist destination, ce ...
, attended by most of the leading physicists of the era, with the notable exceptions of
Einstein Albert Einstein (14 March 187918 April 1955) was a German-born theoretical physicist who is best known for developing the theory of relativity. Einstein also made important contributions to quantum mechanics. His mass–energy equivalence f ...
, Schrödinger, and Dirac. However, these three were in attendance one month later when Bohr again presented the principle at the Fifth Solvay Congress in
Brussels, Belgium Brussels, officially the Brussels-Capital Region, (All text and all but one graphic show the English name as Brussels-Capital Region.) is a Communities, regions and language areas of Belgium#Regions, region of Belgium comprising #Municipalit ...
. The lecture was published in the proceedings of both of these conferences, and was republished the following year in ''Naturwissenschaften'' (in German) and in ''Nature'' (in English). Available in the collection of Bohr's early writings, ''Atomic Theory and the Description of Nature'' (1934). In his original lecture on the topic, Bohr pointed out that just as the finitude of the speed of light implies the impossibility of a sharp separation between space and time (relativity), the finitude of the quantum of action implies the impossibility of a sharp separation between the behavior of a system and its interaction with the measuring instruments and leads to the well-known difficulties with the concept of 'state' in quantum theory; the notion of complementarity is intended to capture this new situation in epistemology created by quantum theory. Physicists F.A.M. Frescura and
Basil Hiley Basil James Hiley (15 November 1935 – 25 January 2025) was a British physicist and professor emeritus of the University of London. Long-time colleague of David Bohm, Hiley is known for his work with Bohm on implicate orders and for his work ...
have summarized the reasons for the introduction of the principle of complementarity in physics as follows:


Debate following the lectures

Complementarity was a central feature of Bohr's reply to the
EPR paradox EPR may refer to: Science and technology * EPR (nuclear reactor), European Pressurised-Water Reactor * EPR paradox (Einstein–Podolsky–Rosen paradox), in physics * Earth potential rise, in electrical engineering * East Pacific Rise, a mid-ocea ...
, an attempt by Albert Einstein, Boris Podolsky and
Nathan Rosen Nathan Rosen (; March 22, 1909 – December 18, 1995) was an American and Israeli physicist noted for his study on the structure of the hydrogen molecule and his collaboration with Albert Einstein and Boris Podolsky on entangled wave functions and ...
to argue that quantum particles must have position and momentum even without being measured and so quantum mechanics must be an incomplete theory. The
thought experiment A thought experiment is an imaginary scenario that is meant to elucidate or test an argument or theory. It is often an experiment that would be hard, impossible, or unethical to actually perform. It can also be an abstract hypothetical that is ...
proposed by Einstein, Podolsky and Rosen involved producing two particles and sending them far apart. The experimenter could choose to measure either the position or the momentum of one particle. Given that result, they could in principle make a precise prediction of what the corresponding measurement on the other, faraway particle would find. To Einstein, Podolsky and Rosen, this implied that the faraway particle must have precise values of both quantities whether or not that particle is measured in any way. Bohr argued in response that the deduction of a position value could not be transferred over to the situation where a momentum value is measured, and vice versa. Later expositions of complementarity by Bohr include a 1938 lecture in
Warsaw Warsaw, officially the Capital City of Warsaw, is the capital and List of cities and towns in Poland, largest city of Poland. The metropolis stands on the Vistula, River Vistula in east-central Poland. Its population is officially estimated at ...
and a 1949 article written for a
festschrift In academia, a ''Festschrift'' (; plural, ''Festschriften'' ) is a book honoring a respected person, especially an academic, and presented during their lifetime. It generally takes the form of an edited volume, containing contributions from the h ...
honoring Albert Einstein. It was also covered in a 1953 essay by Bohr's collaborator Léon Rosenfeld.


Mathematical formalism

For Bohr, complementarity was the "ultimate reason" behind the uncertainty principle. All attempts to grapple with atomic phenomena using classical physics were eventually frustrated, he wrote, leading to the recognition that those phenomena have "complementary aspects". But classical physics can be generalized to address this, and with "astounding simplicity", by describing physical quantities using non-commutative algebra. This mathematical expression of complementarity builds on the work of
Hermann Weyl Hermann Klaus Hugo Weyl (; ; 9 November 1885 – 8 December 1955) was a German mathematician, theoretical physicist, logician and philosopher. Although much of his working life was spent in Zürich, Switzerland, and then Princeton, New Jersey, ...
and
Julian Schwinger Julian Seymour Schwinger (; February 12, 1918 – July 16, 1994) was a Nobel Prize-winning American theoretical physicist. He is best known for his work on quantum electrodynamics (QED), in particular for developing a relativistically invariant ...
, starting with
Hilbert spaces In mathematics, a Hilbert space is a real number, real or complex number, complex inner product space that is also a complete metric space with respect to the metric induced by the inner product. It generalizes the notion of Euclidean space. The ...
and
unitary transformation In mathematics, a unitary transformation is a linear isomorphism that preserves the inner product: the inner product of two vectors before the transformation is equal to their inner product after the transformation. Formal definition More precise ...
, leading to the theorems of mutually unbiased bases. In the
mathematical formulation of quantum mechanics The mathematical formulations of quantum mechanics are those mathematical formalisms that permit a rigorous description of quantum mechanics. This mathematical formalism uses mainly a part of functional analysis, especially Hilbert spaces, whic ...
, physical quantities that classical mechanics had treated as real-valued variables become
self-adjoint operator In mathematics, a self-adjoint operator on a complex vector space ''V'' with inner product \langle\cdot,\cdot\rangle is a linear map ''A'' (from ''V'' to itself) that is its own adjoint. That is, \langle Ax,y \rangle = \langle x,Ay \rangle for al ...
s on a Hilbert space. These operators, called "
observables In physics, an observable is a physical property or physical quantity that can be measured. In classical mechanics, an observable is a real-valued "function" on the set of all possible system states, e.g., position and momentum. In quantum me ...
", can fail to commute, in which case they are called "incompatible":\left hat, \hat\right:= \hat\hat - \hat\hat \neq \hat. Incompatible observables cannot have a complete set of common eigenstates; there can be some simultaneous eigenstates of \hat and \hat, but not enough in number to constitute a complete basis. The
canonical commutation relation In quantum mechanics, the canonical commutation relation is the fundamental relation between canonical conjugate quantities (quantities which are related by definition such that one is the Fourier transform of another). For example, hat x,\hat p ...
\left hat, \hat\right= i\hbar implies that this applies to position and momentum. In a Bohrian view, this is a mathematical statement that position and momentum are complementary aspects. Likewise, an analogous relationship holds for any two of the
spin Spin or spinning most often refers to: * Spin (physics) or particle spin, a fundamental property of elementary particles * Spin quantum number, a number which defines the value of a particle's spin * Spinning (textiles), the creation of yarn or thr ...
observables defined by the
Pauli matrices In mathematical physics and mathematics, the Pauli matrices are a set of three complex matrices that are traceless, Hermitian, involutory and unitary. Usually indicated by the Greek letter sigma (), they are occasionally denoted by tau () ...
; measurements of spin along perpendicular axes are complementary. The Pauli spin observables are defined for a quantum system described by a two-dimensional Hilbert space; mutually unbiased bases generalize these observables to Hilbert spaces of arbitrary finite dimension. Two bases \ and \ for an N-dimensional Hilbert space are mutually unbiased when, \langle a_j, b_k \rangle, ^2 = \frac\ \text\ j, k = 1, ... N-1. Here the basis vector a_1, for example, has the same overlap with every b_k; there is equal transition probability between a state in one basis and any state in the other basis. Each basis corresponds to an observable, and the observables for two mutually unbiased bases are complementary to each other. This leads to a definition of 'Principle of Complementarity' as: The concept of complementarity has also been applied to quantum measurements described by positive-operator-valued measures (POVMs).


Continuous complementarity

While the concept of complementarity can be discussed via two experimental extremes, continuous tradeoff is also possible. In 1979 Wooters and Zurek introduced an information-theoretic treatment of the
double-slit experiment In modern physics, the double-slit experiment demonstrates that light and matter can exhibit behavior of both classical particles and classical waves. This type of experiment was first performed by Thomas Young in 1801, as a demonstration of ...
providing on approach to a quantiative model of complementarity. The wave-particle relation, introduced by Daniel Greenberger and Allaine Yasin in 1988, and since then refined by others, quantifies the trade-off between measuring particle path distinguishability, D, and wave interference fringe visibility, V: D^2 + V^2\ \le\ 1 The values of D and V can vary between 0 and 1 individually, but any experiment that combines particle and wave detection will limit one or the other, or both. The detailed definition of the two terms vary among applications, but the relation expresses the verified constraint that efforts to detect particle paths will result in less visible wave interference.


Modern role

While many of the early discussions of complementarity discussed hypothetical experiments, advances in technology have allowed advanced tests of this concept. Experiments like the quantum eraser verify the key ideas in complementarity; modern exploration of
quantum entanglement Quantum entanglement is the phenomenon where the quantum state of each Subatomic particle, particle in a group cannot be described independently of the state of the others, even when the particles are separated by a large distance. The topic o ...
builds directly on complementarity: In his Nobel lecture, physicist
Julian Schwinger Julian Seymour Schwinger (; February 12, 1918 – July 16, 1994) was a Nobel Prize-winning American theoretical physicist. He is best known for his work on quantum electrodynamics (QED), in particular for developing a relativistically invariant ...
linked complementarity to
quantum field theory In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines Field theory (physics), field theory and the principle of relativity with ideas behind quantum mechanics. QFT is used in particle physics to construct phy ...
: The Consistent histories
interpretation of quantum mechanics An interpretation of quantum mechanics is an attempt to explain how the mathematical theory of quantum mechanics might correspond to experienced reality. Quantum mechanics has held up to rigorous and extremely precise tests in an extraordinarily b ...
takes a generalized form of complementarity as a key defining postulate.


See also

*
Copenhagen interpretation The Copenhagen interpretation is a collection of views about the meaning of quantum mechanics, stemming from the work of Niels Bohr, Werner Heisenberg, Max Born, and others. While "Copenhagen" refers to the Danish city, the use as an "interpretat ...
*
Canonical coordinates In mathematics and classical mechanics, canonical coordinates are sets of coordinates on phase space which can be used to describe a physical system at any given point in time. Canonical coordinates are used in the Hamiltonian formulation of cla ...
*
Conjugate variables Conjugate variables are pairs of variables mathematically defined in such a way that they become Fourier transform duals, or more generally are related through Pontryagin duality. The duality relations lead naturally to an uncertainty relation— ...
*
Interpretations of quantum mechanics An interpretation of quantum mechanics is an attempt to explain how the mathematical theory of quantum mechanics might correspond to experienced reality. Quantum mechanics has held up to rigorous and extremely precise tests in an extraordinarily b ...
*
Wave–particle duality Wave–particle duality is the concept in quantum mechanics that fundamental entities of the universe, like photons and electrons, exhibit particle or wave (physics), wave properties according to the experimental circumstances. It expresses the in ...


References


Further reading

* Berthold-Georg Englert, Marlan O. Scully &
Herbert Walther Herbert Walther (January 19, 1935 in Ludwigshafen/Rhein, Germany – July 22, 2006 in Munich) was a leader in the fields of quantum optics and laser physics. He was a founding director of the Max Planck Institute of Quantum Optics (MPQ) in Garchin ...
, ''Quantum Optical Tests of Complementarity'', Nature, Vol 351, pp 111–116 (9 May 1991) and (same authors) ''The Duality in Matter and Light'' Scientific American, pg 56–61, (December 1994). *
Niels Bohr Niels Henrik David Bohr (, ; ; 7 October 1885 – 18 November 1962) was a Danish theoretical physicist who made foundational contributions to understanding atomic structure and old quantum theory, quantum theory, for which he received the No ...
, ''Causality and Complementarity: supplementary papers edited by Jan Faye and Henry J. Folse. The Philosophical Writings of Niels Bohr, Volume IV''. Ox Bow Press. 1998. *


External links


Discussions with Einstein on Epistemological Problems in Atomic Physics


{{Authority control Quantum mechanics Niels Bohr Dichotomies Scientific laws