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Blueschist (), also called glaucophane schist, is a metavolcanic rock that forms by the
metamorphism Metamorphism is the transformation of existing Rock (geology), rock (the protolith) to rock with a different mineral composition or Texture (geology), texture. Metamorphism takes place at temperatures in excess of , and often also at elevated ...
of
basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
and similar rocks at relatively low
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
s () but very high pressure corresponding to a depth of . The blue color of the rock comes from the presence of the predominant minerals glaucophane and lawsonite. This combination of low temperature occurring at significant depth can only be explained in the context of plate
subduction Subduction is a geological process in which the oceanic lithosphere and some continental lithosphere is recycled into the Earth's mantle at the convergent boundaries between tectonic plates. Where one tectonic plate converges with a second p ...
, followed by exhumation, which accounts for the rarity of this rock. Blueschists are
schist Schist ( ) is a medium-grained metamorphic rock generally derived from fine-grained sedimentary rock, like shale. It shows pronounced ''schistosity'' (named for the rock). This means that the rock is composed of mineral grains easily seen with a l ...
s typically found within orogenic belts as
terrane In geology, a terrane (; in full, a tectonostratigraphic terrane) is a crust fragment formed on a tectonic plate (or broken off from it) and accreted or " sutured" to crust lying on another plate. The crustal block or fragment preserves its d ...
s of
lithology The lithology of a rock unit is a description of its physical characteristics visible at outcrop, in hand or core samples, or with low magnification microscopy. Physical characteristics include colour, texture, grain size, and composition. Lit ...
in faulted contact with
greenschist Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as Chlorite ...
or rarely eclogite
facies In geology, a facies ( , ; same pronunciation and spelling in the plural) is a body of rock with distinctive characteristics. The characteristics can be any observable attribute of rocks (such as their overall appearance, composition, or con ...
rocks.


Petrology

Blueschist, as a rock type, is defined by the presence of the minerals glaucophane + ( lawsonite or
epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in ha ...
) +/- jadeite +/-
albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicat ...
or
chlorite The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
+/-
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...
+/-
muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavage y ...
in a rock of roughly basaltic composition.
Blueschist often has a lepidoblastic, nematoblastic or
schist Schist ( ) is a medium-grained metamorphic rock generally derived from fine-grained sedimentary rock, like shale. It shows pronounced ''schistosity'' (named for the rock). This means that the rock is composed of mineral grains easily seen with a l ...
ose
rock microstructure Rock most often refers to: * Rock (geology), a naturally occurring solid aggregate of minerals or mineraloids * Rock music, a genre of popular music Rock or Rocks may also refer to: Places United Kingdom * Rock, Caerphilly, a location in Wale ...
defined primarily by
chlorite The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
, phengitic white
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into fragile elastic plates. This characteristic is described as ''perfect basal cleavage''. Mica is co ...
, glaucophane, and other minerals with an elongate or platy shape. Grain size is rarely coarse, as mineral growth is retarded by the swiftness of the rock's metamorphic trajectory and perhaps more importantly, the low temperatures of metamorphism and in many cases the anhydrous state of the basalts. However,
porphyritic Porphyritic is an adjective used in geology to describe igneous rocks with a distinct difference in the size of mineral crystals, with the larger crystals known as phenocrysts. Both extrusive and intrusive rocks can be porphyritic, meaning ...
varieties do occur. Blueschists may appear blue, black, gray, or blue-green in outcrop.


Blueschist facies

Blueschist facies is determined by the particular temperature and pressure conditions required to metamorphose basalt to form blueschist.
Felsic In geology, felsic is a grammatical modifier, modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted ...
rocks and pelitic sediments which are subjected to blueschist facies conditions will form different mineral assemblages than metamorphosed basalt. Thereby, these rocks do not appear blue overall in color. Blueschist mineralogy varies by rock composition, but the classic equilibrium assemblages of blueschist facies are: * Basalts: ''glaucophane + lawsonite and/or epidote + albite + titanite +/- garnet +/- quartz'' ''jadeite + quartz'' - diagnostic of pressures ~> 10 kbar *
Ultramafic Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are usua ...
rocks: ''
serpentinite Serpentinite is a metamorphic rock composed predominantly of serpentine group minerals formed by serpentinization of mafic or ultramafic rocks. The ancient origin of the name is uncertain; it may be from the similarity of its texture or color ...
/ lizardite +/-
talc Talc, or talcum, is a clay mineral composed of hydrated magnesium silicate, with the chemical formula . Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant ...
+/- zoisite'' *
Pelite A pelite () or metapelite is a metamorphism, metamorphosed fine-grained sedimentary rock, i.e. mudstone or siltstone. The term was earlier used by geologists to describe a clay-rich, fine-grained clastic sediment or sedimentary rock, i.e. mud or ...
s: ''Fe-Mg-carpholite +/- chloritoid +/-
kyanite Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure Polymorphism (materials science), polymorph of andalusite and sillimanite, and the presence of kyani ...
+ zoisite +/-
pargasite Pargasite or ''pargasitic hornblende'' is a complex Silicate mineral, inosilicate mineral of the amphibole group with formula NaCa2(Mg4Al)(Si6Al2)O22(OH)2. It was first described for an occurrence in Pargas, Finland in 1814 and named for the loc ...
or phengite +/- albite +/- quartz +/- talc +/- garnet'' *
Granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...
s: ''
kyanite Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure Polymorphism (materials science), polymorph of andalusite and sillimanite, and the presence of kyani ...
+/- paragonite +/- chlorite +/- albite +/- quartz +/- pargasite or phengite'' * Calc-silicates: Various *
Limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...
s and
marble Marble is a metamorphic rock consisting of carbonate minerals (most commonly calcite (CaCO3) or Dolomite (mineral), dolomite (CaMg(CO3)2) that have recrystallized under the influence of heat and pressure. It has a crystalline texture, and is ty ...
:
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
transforms to
aragonite Aragonite is a carbonate mineral and one of the three most common naturally occurring crystal forms of calcium carbonate (), the others being calcite and vaterite. It is formed by biological and physical processes, including precipitation fr ...
at high pressure, but typically reverts to calcite when exhumed Blueschist facies generally is considered to form under pressures of >0.6 GPa, equivalent to depth of burial in excess of 15–18 km, and at temperatures of between 200 and 500 °C. This is a 'low temperature, high pressure' prograde metamorphic path and is also known as the ''Franciscan facies series'', after the west coast of the United States where these rocks are exposed. Well-exposed blueschists also occur in
Greece Greece, officially the Hellenic Republic, is a country in Southeast Europe. Located on the southern tip of the Balkan peninsula, it shares land borders with Albania to the northwest, North Macedonia and Bulgaria to the north, and Turkey to th ...
,
Turkey Turkey, officially the Republic of Türkiye, is a country mainly located in Anatolia in West Asia, with a relatively small part called East Thrace in Southeast Europe. It borders the Black Sea to the north; Georgia (country), Georgia, Armen ...
,
Japan Japan is an island country in East Asia. Located in the Pacific Ocean off the northeast coast of the Asia, Asian mainland, it is bordered on the west by the Sea of Japan and extends from the Sea of Okhotsk in the north to the East China Sea ...
,
New Zealand New Zealand () is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and List of islands of New Zealand, over 600 smaller islands. It is the List of isla ...
and
New Caledonia New Caledonia ( ; ) is a group of islands in the southwest Pacific Ocean, southwest of Vanuatu and east of Australia. Located from Metropolitan France, it forms a Overseas France#Sui generis collectivity, ''sui generis'' collectivity of t ...
. Continued
subduction Subduction is a geological process in which the oceanic lithosphere and some continental lithosphere is recycled into the Earth's mantle at the convergent boundaries between tectonic plates. Where one tectonic plate converges with a second p ...
of blueschist facies
oceanic crust Oceanic crust is the uppermost layer of the oceanic portion of the tectonic plates. It is composed of the upper oceanic crust, with pillow lavas and a dike complex, and the lower oceanic crust, composed of troctolite, gabbro and ultramaf ...
will produce eclogite facies assemblages in metamorphosed basalt (garnet + omphacitic clinopyroxene). Rocks which have been subjected to blueschist conditions during a prograde trajectory will gain heat by conduction with hotter lower crustal rocks if they remain at the 15–18 km depth. Blueschist which heats up to greater than 500 °C via this fashion will enter
greenschist Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as Chlorite ...
or eclogite facies temperature-pressure conditions, and the mineral assemblages will metamorphose to reflect the new facies conditions. Thus in order for blueschist facies assemblages to be seen at the Earth's surface, the rock must be exhumed swiftly enough to prevent total thermal equilibration of the rocks which are under blueschist facies conditions with the typical
geothermal gradient Geothermal gradient is the rate of change in temperature with respect to increasing depth in Earth's interior. As a general rule, the crust temperature rises with depth due to the heat flow from the much hotter mantle; away from tectonic plat ...
. Blueschists and other high-pressure subduction zone rocks are thought to be exhumed rapidly by flow and/or faulting in
accretionary wedge An accretionary wedge or accretionary prism forms from sediments accreted onto the non- subducting tectonic plate at a convergent plate boundary. Most of the material in the accretionary wedge consists of marine sediments scraped off from the ...
s or the upper parts of subducted crust, or may return to the Earth's surface in part owing to buoyancy if the metabasaltic rocks are associated with low-density continental crust (marble, metapelite, and other rocks of continental margins). It has been held that the absence of blueschist dating to before the Neoproterozoic Era indicates that currently exhumed rocks never reached blueschist facies at
subduction Subduction is a geological process in which the oceanic lithosphere and some continental lithosphere is recycled into the Earth's mantle at the convergent boundaries between tectonic plates. Where one tectonic plate converges with a second p ...
zones before 1,000 million years ago. This assertion is arguably wrong because the earliest
oceanic crust Oceanic crust is the uppermost layer of the oceanic portion of the tectonic plates. It is composed of the upper oceanic crust, with pillow lavas and a dike complex, and the lower oceanic crust, composed of troctolite, gabbro and ultramaf ...
would have contained more
magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
than today's crust and, therefore, would have formed greenschist-like rocks at blueschist facies.


History and etymology

In
Minoan Crete The Minoan civilization was a Bronze Age culture which was centered on the island of Crete. Known for its monumental architecture and energetic art, it is often regarded as the first civilization in Europe. The ruins of the Minoan palaces at K ...
blueschist and
greenschist Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically and 2–10 kilobars (). Greenschists commonly have an abundance of green minerals such as Chlorite ...
were used to pave streets and
courtyard A courtyard or court is a circumscribed area, often surrounded by a building or complex, that is open to the sky. Courtyards are common elements in both Western and Eastern building patterns and have been used by both ancient and contemporary a ...
s between 1650 and 1600 BC. These rocks were likely quarried in Agia Pelagia on the north coast of central Crete. In 1962, Edgar Bailey of the U.S. Geological Survey, introduced the concept of "blueschist" into the subject of metamorphic
geology Geology (). is a branch of natural science concerned with the Earth and other astronomical objects, the rocks of which they are composed, and the processes by which they change over time. Modern geology significantly overlaps all other Earth ...
. His carefully constructed definition established the pressure and temperature conditions which produce this type of metamorphism.


See also

*
List of minerals This is a list of minerals which have Wikipedia articles. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a mineral speci ...
* List of rock types *
Metamorphism Metamorphism is the transformation of existing Rock (geology), rock (the protolith) to rock with a different mineral composition or Texture (geology), texture. Metamorphism takes place at temperatures in excess of , and often also at elevated ...


References


External links


Blueschist facies - Rock Library Glossary, Imperial College London
{{Rock type Schist Metamorphic petrology Volcanic rocks he:צפחה#צפחות כחולות