Beudandite is a secondary mineral occurring in the

oxidized Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...

zones of polymetallic deposits. It is a

lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...

iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...

arsenate The arsenate is an ion with the chemical formula . Bonding in arsenate consists of a central arsenic atom, with oxidation state +5, double bonded to one oxygen atom and single bonded to a further three oxygen atoms. The four oxygen atoms orien ...

sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...

with endmember formula: PbFe₃(OH)₆SO₄AsO₄. Beudantite is in a subgroup of the

alunite Alunite is a hydroxylated aluminium potassium sulfate mineral, formula potassium, Kaluminium, Al3(sulfur, Soxygen, O4)2(Ohydrogen, H)6. It was first observed in the 15th century at Tolfa, near Rome, where it was mined for the manufacture of alum ...

group. It is the arsenate analogue of the phosphate

corkite Corkite is a phosphate mineral in the beudantite subgroup of the alunite group. Corkite is the phosphate analogue of beudantite and with it, a complete solid solution range exists. Corkite will also form a solid solution with kintoreite. Corki ...

. Beudantite also forms a solid-solution with

segnitite } Segnitite is a lead iron(III) arsenate mineral. Segnitite was first found in the Broken Hill ore deposit in Broken Hill, New South Wales, Australia. In 1991, segnitite was approved as a new mineral. Segnitite has since been found worldwide near ...

and plumbojarosite. It crystallizes in the

trigonal In crystallography, the hexagonal crystal family is one of the six crystal family, crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the tr ...

crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices (an infinite array of discrete points). Space groups (symmetry groups ...

and shows a variety of

crystal habit In mineralogy, crystal habit is the characteristic external shape of an individual crystal or aggregate of crystals. The habit of a crystal is dependent on its crystallographic form and growth conditions, which generally creates irregularities d ...

s including tabular, acute rhombohedral, pseudo-cubic and pseudo-cuboctahedral. It occurs in association with carminite,

scorodite Scorodite is a common hydrated iron arsenate mineral, with the chemical formula FeAsO4·2H2O. It is found in hydrothermal deposits and as a secondary mineral in gossans worldwide. Scorodite weathers to limonite. Scorodite was discovered in Schw ...

mimetite Mimetite is a lead arsenate chloride mineral () which forms as a secondary mineral in lead deposits, usually by the Redox, oxidation of galena and arsenopyrite. The name derives from the Greek ''mimetes'', meaning "imitator" and refers to mimeti ...

, dussertite,

arseniosiderite Arseniosiderite is a rare arsenate mineral formed by the oxidation of other arsenic-containing minerals, such as scorodite or arsenopyrite Arsenopyrite ( IMA symbol: Apy) is an iron arsenic sulfide (FeAsS). It is a hard ( Mohs 5.5–6) metalli ...

pharmacosiderite Pharmacosiderite is a hydrated basic ferric arsenate, with the chemical formula K Fe4( As O4)3(O H)4·(6-7) H2O and a molecular weight of 873.38 g/mol. It consists of the elements arsenic, iron, hydrogen, potassium, sodium and oxygen. It has a ...

olivenite Olivenite is a copper arsenate mineral, formula Cu2 As O4O H. It crystallizes in the monoclinic system (pseudo-orthorhombic), and is sometimes found in small brilliant crystals of simple prismatic habit terminated by domal faces. More commonly ...

bayldonite Bayldonite (BAIL-done-ite) is a rare secondary mineral with the chemical formula PbCu3(AsO4)2(OH)2. Its provenance has been attributed to Penberthy Croft Mine, Cornwall, England, United Kingdom but there is no substantiating evidence for this and ...

, duftite,

anglesite Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and ...

cerussite Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate with the chemical formula PbCO3, and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was ...

and

azurite Azurite or '' Azure spar'Krivovichev V. G.'' Mineralogical glossary. Scientific editor A. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0. ''(in Russian)'' is a soft, deep-blue copp ...

Discovery

Beudantite was first described in 1826 for an occurrence in the Louise Mine, Wied Iron Spar District,

Westerwald The Westerwald (; literally 'Western forest') is a low mountain range on the right bank of the river Rhine in the States of Germany, German federal states of Rhineland-Palatinate, Hesse and North Rhine-Westphalia. It is a part of the Rhenish Ma ...

Rhineland-Palatinate Rhineland-Palatinate ( , ; ; ; ) is a western state of Germany. It covers and has about 4.05 million residents. It is the ninth largest and sixth most populous of the sixteen states. Mainz is the capital and largest city. Other cities are ...

Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen States of Germany, constituent states have a total popu ...

. It was named by Armand Lévy after his fellow

Frenchman French people () are a nation primarily located in Western Europe that share a common French culture, history, and language, identified with the country of France. The French people, especially the native speakers of langues d'oïl from nort ...

and mineralogist

François Sulpice Beudant François Sulpice Beudant (5 September 1787 – 10 December 1850) was a French mineralogist and geologist. The mineral beudantite was named after him. Life Born in Paris, he was educated at the Ecole Polytechnique and Ecole Normale, and in 1811 ...

(1787–1850).

References

{{reflist Sulfate minerals Arsenate minerals Iron minerals Lead minerals Trigonal minerals Minerals in space group 166 Beudantite group

Discovery

See also

References