Berlinite ( aluminium phosphate, chemical formula AlPO₄ or Al(PO₄)) is a rare high-temperature

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

metasomatic Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical com ...

phosphate mineral Phosphate minerals are minerals that contain the tetrahedrally coordinated phosphate () anion, sometimes with arsenate () and vanadate () substitutions, along with chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions, that also fit in ...

. It has the same crystal structure as

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

with a low temperature

polytype In crystallography, polymorphism is the phenomenon where a compound or element can crystallize into more than one crystal structure. The preceding definition has evolved over many years and is still under discussion today. Discussion of the defi ...

isostructural with α–quartz and a high temperature polytype isostructural with β–quartz. Berlinite can vary from colorless to greyish or pale pink and has translucent crystals. It was first described in 1868 for an occurrence in the Västanå iron mine,

Scania Scania ( ), also known by its native name of Skåne (), is the southernmost of the historical provinces of Sweden, provinces () of Sweden. Located in the south tip of the geographical region of Götaland, the province is roughly conterminous w ...

Sweden Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...

and named for Nils Johan Berlin (1812–1891) of

Lund University Lund University () is a Public university, public research university in Sweden and one of Northern Europe's oldest universities. The university is located in the city of Lund in the Swedish province of Scania. The university was officially foun ...

. It occurs as a rare mineral in high-temperature

deposits. Associated minerals include augelite, attakolite,

kyanite Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure Polymorphism (materials science), polymorph of andalusite and sillimanite, and the presence of kyani ...

, pyrophyllite, scorzalite, lazulite, gatumbaite, burangaite, amblygonite, phosphosiderite, purpurite,

apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...

muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavage y ...

hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...

granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...

pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...

s. It also occurs with

alunite Alunite is a hydroxylated aluminium potassium sulfate mineral, formula potassium, Kaluminium, Al3(sulfur, Soxygen, O4)2(Ohydrogen, H)6. It was first observed in the 15th century at Tolfa, near Rome, where it was mined for the manufacture of alum ...

aragonite Aragonite is a carbonate mineral and one of the three most common naturally occurring crystal forms of calcium carbonate (), the others being calcite and vaterite. It is formed by biological and physical processes, including precipitation fr ...

, collophane, crandallite, francoanellite,

gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...

huntite Huntite is a carbonate mineral with the chemical formula Mg3Ca(CO3)4. Huntite crystallizes in the trigonal system and typically occurs as platy crystals and powdery masses. For most of recorded history its main use was as a white pigment. Today ...

hydromagnesite Hydromagnesite is a hydrated magnesium carbonate mineral with the formula . It generally occurs associated with the weathering products of magnesium containing minerals such as serpentine group, serpentine or brucite. It occurs as incrustations a ...

, leucophosphite, nesquehonite,

niter Niter or nitre is the mineral form of potassium nitrate, KNO3. It is a soft, white, highly soluble mineral found primarily in arid climates or cave deposits. Potassium and other nitrates are of great importance for use in fertilizers and, hi ...

, and nitrocalcite in the Paddy's River copper mine in the Brindabella Mountains of

Australia Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...

References

Further reading