Berkelium(III) fluoride is a binary
inorganic compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''.
Inorgan ...
of
berkelium
Berkelium is a synthetic chemical element; it has symbol Bk and atomic number 97. It is a member of the actinide and transuranium element series. It is named after the city of Berkeley, California, the location of the Lawrence Berkeley National ...
and
fluorine
Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
with the chemical formula .
Synthesis
The compound can be prepared by treating with a gaseous mixture of and HF at 600 °C.
Physical properties
Berkelium trifluoride forms a yellow-green solid with two structures. At low temperature, it is orthorhombic (
structure), with lattice parameters a = 670 pm, b = 709 pm, and c = 441 pm. At high temperature, it is trigonal (
structure), with lattice parameters a = 697 pm and c = 714 pm. The transition temperature of is between 350 and 600 °C.
Chemical properties
Berkelium trifluoride is reduced by
lithium
Lithium (from , , ) is a chemical element; it has chemical symbol, symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard temperature and pressure, standard conditions, it is the least dense metal and the ...
to obtain metallic berkelium:
::
References
{{Actinide halides
Fluorides
Berkelium compounds
Actinide halides